Fabrication of Ge30Te 70-xSbx Glasses Alloys and Studying the Effect of Partial Substitution on D.C Electrical Energy Parameters

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The non-linear components has been emphasized for its multiple applications in rewritable recording and data storage devices. Chalcogenide glasses materials are promising due to their high refractive index. In this paper, alloys for Ge30Te 70-xSbx glasses semiconductor (where x =0.0, 5, 10, 15 and 20) will be fabricated by melt quenching method. The effect of partial substitution on DC electric power parameters, and its knowledge of electrical conduction mechanisms, were investigated to determine the effect of Antimony on the density of extended states, local states, and in Fermi energy states. The electrical measurements revealed the existence of three conduction mechanisms depend on the temperature: at high temperature the conduction will be in the extended state. The local states are responsible at medium temperature, and at low temperature it will related to the Fermi level. The effect of partial substitution had produced change in all electrical conductivity parameters including the (extended, localized, and Fermi) density of states, the activation energy, tail width (ΔE), hoping transition distance (R), and interatomic distances a.

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[1] M.H. Cohen, H. Fritzsche, S.P. Ovshlnsky, Simple Band Model for Amorphous Semiconducting Alloys, Phy. Rev Latter, 22 (1969): 1065.

DOI: 10.1103/physrevlett.22.1065

Google Scholar

[2] Bahjat B. Kadhim, Ridha H. Risan, Auday H. Shaban, Kareem A. Jasim, Electrical characteristics of nickel/ epoxy - Unsaturated polyester blend nanocomposites, AIP Conf. Proc. 1968 (2019):020062-(1-5).

DOI: 10.1063/1.5116989

Google Scholar

[3] Haider M.J. Haider, Kareem A. Jasim, Effect of Composition and Dielectric Properties for (YBCO) Superconductor Compound in Different Preparation Methods, Ibn Al-Haitham Jour. for Pure & Appl. Sci. 33(1) (2020): 17-30.

DOI: 10.30526/33.1.2372

Google Scholar

[4] Mott, N. F.; Davis, E. A. Electronic Processes in Non-Crystalline Materials. Clarednon Press. Oxford (1979): 591.

Google Scholar

[5] Kareem A. Jasim, Rihab Nassr Fadhil, Auday H. Shaban, Harith I. Jaafar, Bushra K.H. Maiyaly, Suad H. Aleabi, Ebtisam M-T. Salman, The effects of copper additives on the glass transition temperature and hardness for epoxy resin, PIE, Progress in Industrial Ecology – An International Journal, 13(2) (2019): 163-172.

DOI: 10.1504/pie.2019.099357

Google Scholar

[6] A.S. Khomane. (Crystallographic and microscopic properties of ternary CdS0.5Se0.5 thin filmsR), 124(16), (2013): 2432-2435.

DOI: 10.1016/j.ijleo.2012.07.024

Google Scholar

[7] A.S. Hassanien, Alaa A. Ak, (Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films), Superlattices and Microstructures V.89. (2016): 153-169.

DOI: 10.1016/j.spmi.2015.10.044

Google Scholar

[8] M. Kastner, D. Adler and H. Frizsche, Valence-Alternation Model for Localized Gap States in Lone-Pair Semiconductors, Phys. Rev. letter, 37 (1976): (1905).

DOI: 10.1103/physrevlett.37.1504

Google Scholar

[9] Ovshinsky, S.R., Structure and Excitation of Amorphous Solids, edited by G. Lucovsky and F.L. Galeener (New York: AIP), pp (1976): 31.

Google Scholar

[10] M.A. Paesler, Compositional dependence of the electronic properties of amorphous Te-Tl, phys. Rev. B 13 (1976): 5578.

DOI: 10.1103/physrevb.13.5578

Google Scholar

[11] M. A. Alvi1 and Zishan H Khan, Synthesis and characterization of nanoparticle thin films of a-(PbSe) 100−xCdx lead chalcogenides, Nanoscale Research Letters 8, 148 (2013): 1-10. https://doi.org/10.1186/1556-276X-8-148.

DOI: 10.1186/1556-276x-8-148

Google Scholar

[12] Khan ZH, Salah N, Habib S, Electrical transport of a-Se87Te13 nanorods, J Experimental Nanoscience, 6 (2011):337.

Google Scholar

[13] Indra Sen Ram, Sunil Kumar, Rajesh Kumar Singh, Prabhakar Singh, and Kedar Singh, Electrical conduction mechanism in Se90-xTe5Sn5Inx (x = 0, 3, 6 and 9) multi-component glassy alloys, AIP Advances 5, (2015): 087164-(1-7).

DOI: 10.1063/1.4929577

Google Scholar

[14] Haider M. J. Haider, Kassim M. Wadi, Hind A. Mahdi, Kareem A. Jasim, Auday H. Shaban, Studying the partial substitution of barium with cadmium oxide and its effect on the electrical and structural properties of HgBa2Ca2Cu3O8+δ superconducting compound, AIP Conf. Proc., 1968 (2019): 020033-(1-7).

DOI: 10.1063/1.5116960

Google Scholar

[15] Harith I. Jaafar, Seenaa I. Hussein, Huda M. jaafar, Study of Thermal Conductivity and Solution Absorption for Epoxy –Talc Composites, Iraqi journal of science, 58(4B) (2017): 2107-2111.

DOI: 10.24996/ijs.2017.58.4b.14

Google Scholar

[16] Mohd. Nasir, M. Zulfequar, DC Conductivity and Dielectric Behaviour of Glassy Se100–xZnx Alloy, Open Journal of Inorganic Non-metallic Materials, 2, (2012): 11-17.

DOI: 10.4236/ojinm.2012.22002

Google Scholar

[17] Y.K. Liu, J.A. Zapien, Y.Y. Shan, C.Y. Geng, C.S. Lee, S.T. Lee, Wavelength‐Controlled Lasing in ZnxCd1–xS Single‐Crystal Nanoribbons, Adv. Mater. 17(11) (2005): 1372-1377. https://doi.org/10.1002/adma.200401606.

DOI: 10.1002/adma.200401606

Google Scholar

[18] T.D. Rani, K. Tamilarasan, E. Elangovan, S. Leela, K. Ramamurthi, K. Thangaraj, C. Himcinschi, I. Trenkmann, S. SchuIze, M. Hietschold, A. Liebig, G. Salvan, D.R.T. Zahn, Structural and optical studies on Nd doped ZnO thin films, Superlattices and Microstructures, 77 (2015): 325-332.

DOI: 10.1016/j.spmi.2014.10.001

Google Scholar

[19] S. K. Tripathi, R. Arora and A. Kumar, Effect of In Impurity on the Electrical Properties of Amorphous Se80Te20, Jap. J. Appl. Phys. 29(I)(2) (1990): 226. https://doi.org/10.1143/JJAP.29.226.

Google Scholar

[20] Kareem Ali Jasim, Effect of Composition and Hydrogenated of the Density of State of Amorphous Chalcogide Semiconductor, MSc. Thesis college of Science, University of Baghdad, Iraq, (1992).

Google Scholar

[21] Aqeel N. Abdulateef, Ahlam Alsudani, Riyadh Kamil Chillab, Kareem A. Jasim, Auday H. Shaban, Calculating the Mechanisms of Electrical Conductivity and Energy Density of States for Se85Te10Sn5-xInx Glasses Materials, Journal of Green Engineering (JGE), 10(9), (2020): 5487–5503.

Google Scholar

[22] A.R. Jabur‏, B2223 High Temperature Superconductor wires in silver sheath, Filament diameter effect on critical temperature and current density‏, Energy Procedia 18, (2012): 254-264.

DOI: 10.1016/j.egypro.2012.05.037

Google Scholar

[23] Nyaga, P.K. Optoelectrical and stability characterization of. SnxSey/ZnO:Sn solar cell prepared by resistive evaporation. MSc Thesis, Department of Physics. Kenyatta University, Kenya, (2014).

Google Scholar

[24] Phillips, J. C., Phys. Rev. B. Constraint theory and carrier-type reversal in Bi-Ge chalcogenide alloy glasses, Physical Review B (Condensed Matter), 36(8) (1987): 4265-4270. 10.1103/PhysRevB.36.4265.

DOI: 10.1103/physrevb.36.4265

Google Scholar

[25] Juejun Hu, Xiaochen Sun, Anuradha M. Agarwal,a Jean-Francois Viens, and Lionel C. Kimerling, Studies on structural, electrical, and optical properties of Cu doped As–Se–Te chalcogenide glasses, Journal of Applied Physics 101 (2007): 063520-(1-9).

DOI: 10.1063/1.2712162

Google Scholar