Resistance of Electrically Conductive Concrete to Sulphate Attack

Abstract:

It was defined that structural elements of a building made from electrically conductive concrete may reduce their performance characteristics due to the corrosion environment. The main reasons for that process are supplement corrosion factors such as a wide range of temperature, humidity as well as chemical agents in the environment. In this article results of different properties (mechanical, electrical) of electrically conductive concrete are discussed including their alterations due to sulphate attack. Also, microstructure as well as physical and chemical properties of modified concrete have been considered after being exposed to sulphate attack (Na₂SO₄) for 112 days. That component has been used for modeling the sulphate attack environment. Compressive strength, rate of the corrosion process, the volume of absorbed SO₄^2– ions from a water-based solution of Na₂SO₄ was defined in order to analyze the effect of sulphate attack. Scanning electron microscopic investigation, energy dispersive spectroscopy, differential thermal analyses were applied for observing morphology and properties changes of modified samples. To assess the influence of sulphate attack on mineral composite materials the approach was suggested and this method might be useful to foresee the durability of concrete while exposing it to the high corrosion environment. In addition to that, a possible method of protection for electrically conductive concrete from sulphate attack was also considered in the article.

• Periodical: Key Engineering Materials (Volume 932)
• Pages: 197-203
• DOI: https://doi.org/10.4028/p-z59pd9
• Online since: September 2022
• Authors: Irina Sergeevna Polyanskikh*, Aleksandr Nikolaevich Gumenyuk, Anastasiya Fedorovna Gordina, Igor Aleksandrovich Pudov, Grigory Ivanovich Yakovlev
• Keywords: Concrete Corrosion, Corrosion Protection, Electrically Conductive Concrete, Functional Modifiers, Modified Concrete, Morphology, Sulfate Attack

References

[1] Amr S. El-Dieba, Mahmoud A. El-Ghareeb, Mohamed A.H. Abdel-Rahman, El Sayed A. Nasr, Multifunctional electrically conductive concrete using different fillers, Journal of Building Engineering. 15 (2018) 61–69. https://doi.org/10.1016/j.jobe.2017.10.012.

DOI: 10.1016/j.jobe.2017.10.012

[2] W. Dong, Y. Huang, B. Lehane, F. Aslani, G. Mab, Mechanical and electrical properties of concrete incorporating an iron-particle contained nano-graphite by-product, Construction and Building Materials. 270 (2021) 121377. https://doi.org/10.1016/j.conbuildmat.2020.121377.

DOI: 10.1016/j.conbuildmat.2020.121377

[3] P. Rovnaník, I. Kusák, Bayer P., P. Schmid, L. Fiala, Electrical and self-sensing properties of alkali-activated slag composite with graphite filler, Materials. 12 (2019) 1616. https://doi.org/10.3390/ma12101616.

DOI: 10.3390/ma12101616

[4] B. Zukowski, Y. Mendonca, J. Souza, R. Filho Cement-based EMI shielding materials, Materials for potential EMI shielding applications. Processing, Properties and Current Trends. (2020) 333-340. https://doi.org/10.1016/B978-0-12-817590-3.00020-8.

DOI: 10.1016/b978-0-12-817590-3.00020-8

[5] F. Bernatskii, IU. N. Tselebrovskii, V.A. Chunchin Electrical properties of concrete, Energiya, Moscow, (1980).

[6] H. Dehghanpour, K. Yilmaz Heat behavior of electrically conductive concretes with and without rebar reinforcement, Materials science. 26 (2020) http://dx.doi.org/10.5755/j01.ms.26.4.23053.

DOI: 10.5755/j01.ms.26.4.23053

[7] K. Hornbostel, C.K. Larsen, M.R. Geiker, Relationship between concrete resistivity and corrosion rate—A literature review. Cem. Concr. Compos. 2013, 39, 60–72.

DOI: 10.1016/j.cemconcomp.2013.03.019

[8] G.Yakovlev, I. Polyanskikh, A. Gordina, I. Pudov, V. Černý, A. Gumenyuk, O. Smirnova, Influence of sulphate attack on properties of modified cement composites, Applied Sciences. 11 (2021) 8509. https://doi.org/10.3390/app11188509.

DOI: 10.3390/app11188509

[9] A.Sassani, H. Ceylan, S. Kim, K. Gopalakrishnan, A. Arabzadeh, P. C. Taylor Influence of mix design variables on engineering properties of carbon fiber-modified electrically conductive concrete, Construction and Building Materials. 152 (2017) 168–181 http://dx.doi.org/10.1016/j.conbuildmat.2017.06.172.

DOI: 10.1016/j.conbuildmat.2017.06.172

[10] J. Stark, B. Wicht Dauerhaftigkeit von Beton. Springer Verlag, (2013).

[11] A.Gumeniuk, R.Hela, I.Polyanskikh, A.Gordina, G. Yakovlev, Durability of concrete with man-made thermoplastic sulfur additive, IOP Conference Series: Materials Science and Engineering. 869 (2020) 032012.

DOI: 10.1088/1757-899x/869/3/032012

[12] S. V. Fedosov, S. M. Bazanov Sulfate corrosion of concrete, Moscow, Publisher ASV, (2003).