Investigation Some Characteristics of Biocomposites Coating for Biomedical Implants

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The surface has a vital function in the tissue's response to the presence of foreign material in the field of body implants. Surface modification with coatings can be adjusted to provide the highest service performance at the lowest cost. Coatings can increase corrosion resistance by reducing metal ion and corrosion product migration in the body. We fabricated polymer based bio-composite coatings by blending chitosan (Chi), alginate (Alg) and nanoparticles ((TiO2, Nb2O5) by dip coating onto a 316L stainless steel substrate. The coatings’ surface morphology and phases were studied using FESEM and FTIR analysis. The wettability behavior of the coated samples was also studied by investigating their contact wetting attributes. The antibacterial activity of the functionalized coatings was determined too. The FTIR results showed that the blending of Chi-Alg and nanoparticles was excellent, and no obvious differences in the spectra or any changes in the structures of the polymer matrices were observed. The SEM results demonstrated that the coating layers were uniform, homogeneous, and crack-free on the 316L Stianless steel substrate when using TiO2-Nb2O5 nano particles. The contact angle results showed the highly hydrophilic properties of the pure chitosan-alginate blend. As well, coatings containing nano particles showed the same antibacterial effect of chitosan-alginate blend coating.

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3-11

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December 2022

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© 2022 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. R. Zuriadi, A. Fadli, and A. Amri, Pelapisan permukaan stainless Steel 316L menggunakan hidroksiapatit dengan metode deposisi, J. Online Mhs. Fak. Tek. Univ. Riau, 20, 2, (2015) 1–7.

Google Scholar

[2] S. A. Abdulrahmana, Q. A. Hamad, and J. K. Oleiwi, Investigation of some properties for laminated composite used for prosthetic socket, Engineering and Technology Journal,.39, 11, (2021) 1625-1631.

DOI: 10.30684/etj.v39i11.2050

Google Scholar

[3] J. A. Helsen, Metals as biomaterials, John Wiley & Sons, New York, (1998), 153.

Google Scholar

[4] J. Liu et al., Effect of low-temperature plasma carbonitriding on the fretting behaviour of 316LVM medical grade austenitic stainless steels, Wear, 271, 9–10, (2011) 1490–1496.

DOI: 10.1016/j.wear.2010.12.017

Google Scholar

[5] K. P. Ananth, J. Sun, and J. Bai, Superior corrosion protection and in vitro biocompatibility of Na-HAp/CS composite coating on PoPD-coated 316L SS, Materials Today Chemistry, 10, (2018) 153-166.

DOI: 10.1016/j.mtchem.2018.08.001

Google Scholar

[6] M. Cheng, W. Cao, Y. Gao, Y. Gong, N. Zhao, and X. Zhang, Studies on nerve cell affinity of biodegradable modified chitosan films, J Biomater Sci Polym Ed, 14, 10, (2003) 1155–1167.

DOI: 10.1163/156856203769231628

Google Scholar

[7] D. Wei, W. Sun, W. Qian, Y. Ye, and X. Mac, The synthesis of chitosan-based silver nanoparticles and their antibacterial activity, Carbohydrate Research, 344, 17, (2009) 2375-2382.

DOI: 10.1016/j.carres.2009.09.001

Google Scholar

[8] M. Ø. Dalheim, J. Vanacker, M. A. Najmi, F. L. Aachmann, B. L. Strand, and B. E. Christensen, Efficient functionalization of alginate biomaterials, Biomaterials, 80, (2016) 146-156.

DOI: 10.1016/j.biomaterials.2015.11.043

Google Scholar

[9] S. M. Gupta and M. Tripathi, A review of TiO2 nanoparticles, Chinese Science Bulletin, 56, 16, (2011) 1639–1657.

DOI: 10.1007/s11434-011-4476-1

Google Scholar

[10] J. K. Savaiano and T. J. Webster, Altered responses of chondrocytes to nanophase PLGA/nanophase titania composites, Biomaterials, 25, 7-8, (2004) 1205–1213.

DOI: 10.1016/j.biomaterials.2003.08.012

Google Scholar

[11] D. B. Haddow, S. Kothari, P. F. James, R. D. Short, P. V. Hatton and R.V. Noort, Synthetic implant surfaces. 1. The formation and characterization of sol-gel titania films, Biomaterials, 17, 5, (1996) 501-507.

DOI: 10.1016/0142-9612(96)82724-4

Google Scholar

[12] M. Kulkarni, A. Mazare, P. Schmuki, and A. Iglič, Biomaterial surface modification of titanium and titanium alloys for medical applications, Nanomedicine, 111, 615, (2014) 111.

Google Scholar

[13] H. M. Algailani, A.l K. Mahmoud, and H. A. Al-Kaisy, Fabrication of Ni-ZrO2 Nanocomposite Coating by Electroless Deposition Technique, Engineering and Technology Journal, 38, 5, (2020) 649-655.

DOI: 10.30684/etj.v38i5a.491

Google Scholar

[14] R. A. Isaa., M. N. Al-Shroofy. and H. A. Al-Kaisy, Al2O3-TiO2-PMMA Bio-Composite Coating via Electrostatic Spray Technique, Engineering and Technology Journal, 39, 3A, (2021) 504-511.

DOI: 10.30684/etj.v39i3a.1894

Google Scholar

[15] J. Scheirs, Compositional and failure analysis of polymers: a practical approach, John Wiley & Sons, (2000) 600.

Google Scholar

[16] M. L. Duarte, M. C. Ferreira, M. R. Marvao, and J. Rocha, an Optimised method to determine the degree of acetylation of chitin and chitosan by FTIR spectroscopy, Int J Biol Macromol, 31, 1-3, (2020) 1–8.

DOI: 10.1016/s0141-8130(02)00039-9

Google Scholar

[17] X. Wang, J. Wang, and H. Wang, Synthesis, characterization and ceramization of a novel vinyl-rich liquid precursor for Si(O)C ceramic, Ceramics Int, 39, 9, (2013) 9033–9039.

DOI: 10.1016/j.ceramint.2013.04.106

Google Scholar

[18] Q. A. Hamad, J. K. Oleiwi, and N. N. Kadhim, f Influence of pistachio shell powder reinforcement on FTIR and DSC behavior of PMMA acrylic resin, Iraqi J. Mech. Mater. Eng., 20, 1, (2020) 63–76.

DOI: 10.32852/iqjfmme.v20i1.462

Google Scholar

[19] J. K. Oleiwi, Q. A. Hamad, and S. A. Abdulrahman, Comparative study of polymeric laminated composites reinforced by different fibers of prosthetic socket by DSC and FTIR, Key Engineering Materials, 911, (2022) 3-8.

DOI: 10.4028/p-ju39wm

Google Scholar

[20] Q. A. Hamad, J. K. Oleiwi, and S. A. Abdulrahman, Tensile properties of laminated composite prosthetic socket reinforced by different fibers, Materials Today: Proceedings, (2021).

DOI: 10.1016/j.matpr.2021.06.348

Google Scholar

[21] N. An, X. Rausch-fan, M. Wieland, M. Mateika, O. Andrukhov, and A. Schedle, Initial attachment, subsequent cell proliferation/viability and gene expression of epithelial cells related to attachment and wound healing in response to different titanium surfaces, Dent Mater, 28, 12, (2012) 1207–1214.

DOI: 10.1016/j.dental.2012.08.007

Google Scholar