Mitigation of Efflorescence and Alkali Leaching in Activated Slag Using Foundry Sand

Article Preview

Abstract:

This research aimed to examine the impact of foundry sand on alkali leaching and the formation of efflorescence in alkali-activated slag. The activation process involved the utilization of sodium hydroxide and sodium silicate solutions in activating ground-granulated blast furnace slag (GBFS) and sand samples. The leaching of alkali and the formation of efflorescence were observed to occur at a reduced rate in samples derived solely from 100% ground granulated blast furnace slag (GBFS). In contrast, higher rates were identified in samples containing chemically bonded foundry sand. The incorporation of chemically bonded foundry sand elevated the mobility of alkali, leading to an increased formation of efflorescence in alkali-activated slag. Following a three-day immersion of the specimens in deionized water, nearly all of the sodium was leached from the samples, highlighting the limited affinity of sodium within the gel structure.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

101-107

Citation:

Online since:

April 2024

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Flower, D.J. and Sanjayan, J.G., 2007. Greenhouse gas emissions due to concrete manufacture. The International Journal of Life Cycle Assessment, 12, pp.282-288.

DOI: 10.1007/s11367-007-0327-3

Google Scholar

[2] Cabeza, L.F., Barreneche, C., Miró, L., Morera, J.M., Bartolí, E. and Fernández, A.I., 2013. Low carbon and low embodied energy materials in buildings: A review. Renewable and Sustainable Energy Reviews, 23, pp.536-542.

DOI: 10.1016/j.rser.2013.03.017

Google Scholar

[3] Živica, V., 2007. Effects of type and dosage of alkaline activator and temperature on the properties of alkali-activated slag mixtures. Construction and Building Materials, 21(7), pp.1463-1469.

DOI: 10.1016/j.conbuildmat.2006.07.002

Google Scholar

[4] Fu-Sheng, W., Rui-Lian, S. and Ying-Jing, C., 2005. Study on modification of the high-strength slag cement material. Cement and concrete research, 35(7), pp.1344-1348.

DOI: 10.1016/j.cemconres.2004.10.017

Google Scholar

[5] Abhilash, P., Sasidhar, C. and Ramana Reddy, I.V., 2017. Evaluation of Performance of Geopolymer Concrete in Acid Environment". International Research of Engineering and Technology (IJRET), 4(7).

Google Scholar

[6] Rostami, M. and Behfarnia, K., 2017. The effect of silica fume on durability of alkali activated slag concrete. Construction and building materials, 134, pp.262-268.

DOI: 10.1016/j.conbuildmat.2016.12.072

Google Scholar

[7] Wang, S.D., Scrivener, K.L. and Pratt, P.L., 1994. Factors affecting the strength of alkali-activated slag. Cement and concrete research, 24(6), pp.1033-1043.

DOI: 10.1016/0008-8846(94)90026-4

Google Scholar

[8] Škvára, F., Šmilauer, V., Hlaváček, P.E.T.R., Kopecký, L.U.B.O.M.Í.R. and Cilova, Z., 2012. A weak alkali bond in (N, K)–A–S–H gels: evidence from leaching and modeling. Ceramics–Silikáty, 56(4), pp.374-382.

Google Scholar

[9] Sun, K., Peng, X., Wang, S., Zeng, L., Ran, P. and Ji, G., 2020. Effect of nano-SiO2 on the efflorescence of an alkali-activated metakaolin mortar. Construction and Building Materials, 253, p.118952.

DOI: 10.1016/j.conbuildmat.2020.118952

Google Scholar

[10] Wang, J., Zhou, T., Xu, D., Zhou, Z., Du, P., Xie, N., Cheng, X. and Liu, Y., 2018. Effect of nano-silica on the efflorescence of waste-based alkali-activated inorganic binder. Construction and Building Materials, 167,pp.381-390.

DOI: 10.1016/j.conbuildmat.2018.02.006

Google Scholar

[11] Saludung, A., Azeyanagi, T., Ogawa, Y. and Kawai, K., 2021. Effect of silica fume on efflorescence formation and alkali leaching of alkali-activated slag. Journal of Cleaner Production, 315, p.128210.

DOI: 10.1016/j.jclepro.2021.128210

Google Scholar

[12] Zhang, Z., Provis, J.L., Reid, A. and Wang, H., 2014. Fly ash-based geopolymers: The relationship between composition, pore structure and efflorescence. Cement and concrete

DOI: 10.1016/j.cemconres.2014.06.004

Google Scholar

[13] Scherer, G.W., 2004. Stress from crystallization of salt. Cement and concrete research, 34(9), pp.1613-1624.

DOI: 10.1016/j.cemconres.2003.12.034

Google Scholar

[14] Ye, H. and Radlińska, A., 2016. Shrinkage mechanisms of alkali-activated slag. Cement and Concrete Research, 88, pp.126-135.

DOI: 10.1016/j.cemconres.2016.07.001

Google Scholar

[15] Prud'homme, E., Michaud, P., Joussein, E., Peyratout, C., Smith, A., Arrii-Clacens, S., Clacens, J.M. and Rossignol, S., 2010. Silica fume as porogent agent in geo-materials at low temperature. Journal of the European Ceramic Society, 30(7), pp.1641-16

DOI: 10.1016/j.jeurceramsoc.2010.01.014

Google Scholar