Characterization and Performance Analysis of TiO2 Coated UHMWPE for Biomedical Applications

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Abstract:

Ultra-high Molecular Weight Polyethylene (UHMWPE) is a highly versatile polymer known for its exceptional mechanical properties, however, its limited life as an implant material for Total Joint Replacement (TJR) necessitates surface modification to extend its lifespan. This study aims to enhance the surface properties of UHMWPE through application of ceramic coatings. Magnetron sputtering method was used to deposit thin film of white Titania (TiO2) on the material’s surface. To evaluate the surface characteristics, such as surface roughness, uniformity and structure, coated and uncoated samples were analyzed through Atomic Force Microscopy (AFM), Scanning Electron Microscopy (SEM) and X-ray Diffraction Analysis (XRD). The material performance in relation to biological context was investigated through Contact Angle measurement. A comparative analysis of coated and uncoated samples was then performed. The coated samples showed better wettability compared to uncoated sample. This fact highlights the hydrophilic nature of film. The results of the coated UHMWPE suggest that this surface modification technique could significantly extend the lifespan of UHMWPE implants in TJR, potentially addressing the current limitations associated with their longevity.

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61-66

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October 2024

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© 2024 Trans Tech Publications Ltd. All Rights Reserved

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[1] M.C. Sobieraj, C.M. Rimnac, Ultra high molecular weight polyethylene: mechanics, morphology, and clinical behavior, Journal of the Mechanical Behavior of Biomedical Materials, 2 5 (2009) 433-443.

DOI: 10.1016/j.jmbbm.2008.12.006

Google Scholar

[2] G. Helbig, Curbell Plastics Inc., New York Patent 86622509 (2016).

Google Scholar

[3] Technavio, Global Ultra-High Molecular Ployethylene Market 2017-2021, Technavio, London, (2017)

Google Scholar

[4] J. R. Foran, S. J. Fischer, Surgical Management of Osteoarthritis of the Knee - Clinical Practice Guideline (CPG), American Academy of Orthopaedic Surgeons (aaos.org) (2020).

Google Scholar

[5] A. Kumar, W.C. Tcai, T.S. Tai, P.T. Kug, L.T. Chiu, M.C Ku, Temporal trends in primary and revision total knee and hip replacement in Taiwan, Journal of the Chinese Medical Association, 78 9 (2015) 538-544.

DOI: 10.1016/j.jcma.2015.06.005

Google Scholar

[6] C.-J. Chung, P.-Y. Hsieh, C.-H. Hsiao, H.-I. Lin, A. Leyland, A. Matthews, J.-L. He, Mutifunctional arc ion plated TiO2 photocatalytic coatings with improved wear and corrosion protection, Surface and Coatings Technology (2009) 1689-1693.

DOI: 10.1016/j.surfcoat.2009.01.005

Google Scholar

[7] V.K. Matharu, G.S. Matharu, Metal-on-metal hip replacements: implications for general practice, British Journal of General Practice, 67 665 (2017) 544-545

DOI: 10.3399/bjgp17x693557

Google Scholar

[8] E. Ora, O. K. Muratoglu, Radiation cross-linking in ultra-high molecular weight polyethylene for orthopaedic applications, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 265 1 (2007) 18-22.

DOI: 10.1016/j.nimb.2007.08.022

Google Scholar

[9] V. Martínez-Nogués, F. J. Medel, M. D. Mariscal, J. L. Endrino, J. Krzanowski, F. Yubero, J. A. Puértolas, Tribological performance of DLC coatings on UHMWPE, Journal of Physics: Conference Series, 252 (2010) 120-126

DOI: 10.1088/1742-6596/252/1/012006

Google Scholar

[10] S. B. Amor, G. Baud, M. Benmalek, H. Dunlop, R. Frier, M. Jacquet, Titania Coatings on Polyethylene Terephthalate: Adhesion and XPS Studies, The Journal of Adhesion, 65 4 (1998) 307-329.

DOI: 10.1080/00218469808012251

Google Scholar

[11] H. Okada, J. Ida, T. Yoshikawa, T. Matsuyama, H. Yamamoto, Use of the Sol—Gel Method for Titania Coating and the Effect of Support Silica Particle Size, Advanced Powder Technology, 9 1 (2008) 39-48.

DOI: 10.1163/156855208x291710

Google Scholar

[12] A. Gordienko, A. B. Kaye, Unique Pulsed-Laser Deposition Production of Anatase and Rutile TiO2, Crystal Structure Theory and Applications, 07 02 (2018) 19-31.

DOI: 10.4236/csta.2018.72002

Google Scholar

[13] K. Elghniji, E. Elaloui, Y. Moussaoui, Coating of anatase titania on clinoptilolite by metal organic chemical vapor deposition method: enhanced mesoporosity and photocatalytic activity, Chemical Papers, 72 5 (2018) 1159-1168.

DOI: 10.1007/s11696-017-0350-1

Google Scholar

[14] H. K. Jang, S. W. Whangbo, H. B. Kim, K. Y. Im, Y. S. Lee, Titanium oxide films on Si(100) deposited by electron-beam evaporation at 250 °C, Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 18 3 (2000) 917-921.

DOI: 10.1116/1.582275

Google Scholar

[15] O. Oladijo, M. Sanjay, L. Collieus, S. Siengchin, L. Moloisane, S. Oladijo, Effects of deposition time and RF power on the film characteristics of magnetron sputtered silicon carbide thin films, Materials Today: Proceedings, 52 (2022) 2432-2438.

DOI: 10.1016/j.matpr.2021.10.423

Google Scholar

[16] P. Salunkhe, A. A. Muhammed, D. Kekuda, Structural, spectroscopic and electrical properties of dc magnetron sputtered NiO thin films and an insight into different defect states, Applied Physics A, 127 5 (2021) 390-397.

DOI: 10.1007/s00339-021-04501-0

Google Scholar

[17] O. Oladijo, M. Sanjay, L. Collieus, S. Siengchin, L. Moloisane, S. Oladijo, Effects of deposition time and RF power on the film characteristics of magnetron sputtered silicon carbide thin films, Materials Today: Proceedings, 52 (2022) 2432-2438.

DOI: 10.1016/j.matpr.2021.10.423

Google Scholar

[18] M. Peltzer, J. R. Wagner, A. Jiménez, Thermal characterization of UHMWPE stabilized with natural antioxidants, Journal of Thermal Analysis and Calorimetry, 87 2 (2007) 493-497.

DOI: 10.1007/s10973-006-7453-1

Google Scholar