Materials Science Forum Vol. 1021

Abstract: In this research, the actions of antibiotic trimethoprim alone and with metals combained. Then assayed through formation of base transition metal compounds as ligands have the chance to achieve an unusual arrangement and stability complexes of coordination. We show advancement in using transtional metal compounds medications for treamentt manyl human illnesses such as carcinomas, lymphomas, control of infections, anti-inflammatory disorders, diabetes, with neurological conditions. This combination with transition metal observed the interaction can be separated by derivative spectroscopic method and measure the characterization of compound by IR and UV spectroscopy.

Abstract: Pistachio shells (PS) are one of the agricultural wastes, that are considered as economic and wide available material. It has some features that encourage using it to produce lightweight concrete and cement mortar. The essential objective of the current investigation is to evaluate the possibility of incorporating PS as a fibre in the cement mortar and the effect on its properties. Four different fibre percentages (0%, 0.5%, 1% and 1.5% by volume of cement) were examined. After curing the samples for 7 and 28 days, the fundamental properties of the cement mortars, including splitting tensile and compressive strengths I addition to the density, were determined and compared. The results revealed that the optimum content of the pistachio shells fibre lies between 0.5% and 1% where the splitting tensile and compressive strengths increased and the mortar’s density reduced at age of 28 days.

Abstract: This study presents a step towards exploring the possibility of using silicon materials as a surrogate to produce a multi-material 3D printed soft silicone brain model to be used in the investigation of Traumatic Brain Injury (TBI) in paediatric populations. Silicone represents a popular choice of material due to its viscoelastic properties, 3D printability, and capability to be tuned to possess different properties. Dynamic oscillatory shear tests were carried out for seven types of silicon materials at three different speeds against a different range of frequencies. The mechanical parameters response has been ranked on, which is the most appropriate to try. It also agrees with the range of reported paediatric brain tissue imitating grey and white matter as a surrogate brain material. Utilising of silicone for 3D printing represents a new approach to fabricate surrogate models that closely mimic biofidelic features and advance the medical engineering discipline.

Abstract: There are many reasons neededfor continuous evolution in concrete technology; one of them concern on the greenhouse gas emission and depletion of natural resource as a results of high production of Portland cement. Many solutions are used to solve these problems; one of them is using cement replacement materials in concrete like metakaolin (in micro or Nano scale) which offered positive effect on the properties of cement concrete. Therefore, the main aim of this study is to evaluate and compare the effects of metakaolin (MK) and Nano-metakaolin (NMK) on some physical and mechanical properties of cement mortar. For this purpose, mortar mixes are prepared by substituting cement (by weight) with (10%) metakaolin or (1, 3, 5, and 7%) Nano - metakaolin. The amount of binder for mortar mixtures is 700 kg/m with a constant water / binder ratio of 0.33. Workability, apparent density, water absorption, compressive strength, and flexural strength of all mortar mixes are determined and compared with reference mix without any mineral admixture (0% MK or NMK). The results indicated that the performance of mortar mixes can be enhanced by metakaoline replacement. Furthermore, Nano-metakaolin has significantly positive impacts on the properties of mortar mixes which have found to be improved with increasing the Nano-metakaolin replacement, due to better pore refinement, micro filling action, and higher pozzolanic reaction. The optimum Nano-metakaolin substitution ratio (7%) causes increase in compressive and flexural strength reach to (82.6% and 59.5%), respectively compared with the reference mix, at age of 28 days.

Abstract: In the present work, corrosion inhibition of low carbon steel in a 1M H2SO4 solution by pectin nanoparticles extract was studied by potentiostatic and weight loss methods. Increasing the acid concentration leads to an increase in the corrosion rate of the electrode. The variable conditions of the pectin nanoparticles used in this investigation are (2 to 10g/l at 25oC). It was found that the concentrates acts as a compelling consumption inhibitor for gentle steel in an acidic medium. The hindrance process is credited to the adsorbed film development of the inhibitor on the metal surface of that protects the metal against corrosion. It was observed that the efficiency of the inhibition rose with increased inhibitor concentration up to the maximum level of 92% for 10 g/l at 25 oC. The results showed that the corrosion rate without the inhibitor was 2.263mpy while with the inhibitor 0.179 mpy, meaning that the rate of corrosion improved more than 90%. The results of the immersion time (1 h) at 25oC on the inhibition of the corrosion also indicated improved corrosion resistance. The results demonstrated that an extract of pectin nanoparticles could serve as an excellent eco-friendly, green corrosion inhibitor. Fourier- transform infrared spectroscopy (FTIR) results indicate that these nanoparticles contain various chemical bonds (C-C, CH2, C-O-C, and cellulose) with metal surfaces, lead to producing a barrier layer that protects the surface.

Abstract: Novel extracted natural stabilizer for the polymer was investigated in this study. The natural anti-aging was extracted from plants and it is demonstrated that this type of stabilizers are suitable for biodegradable polymers. Gynostemma pentaphyllum (0.01–0.03 wt%) were extracted and added to the poly(vinyl chloride) blend. The achieved polymeric films were exposed to an accelerated UV light aging process for 300 hours at ambient temperature. The efficiency of tested natural stabilizer was linked to blank PVC films. FTIR spectroscopy, weight loss, electronic microscope and scanning electron microscopy were performed. Using small amount of natural stabilizer is significantly beneficial because it does not influence the PVC properties.

Abstract: Nd-YAG lasers have been successfully used in recent years as reliable heat source to surface modification of engineering materials such as laser surface re-melting. In the present study, X12 tool steel was surface modified by using pulse Nd-YAG laser technique. Laser parameters are selected of 12 J pulse energy, 15 Hz frequency, 20 mm defocus length, 6 ms pulse duration, and 5.6 mm /s mm scanning speed. These parameters were chosen after undertaking trials to give suitable parameters in this process. Optical microscopy and backscattered scanning electron microscopy (SEM) with EDS and X-ray diffraction techniques were used to analyse the microstructure changes of the surface of tool steel. Wear resistance test was achieved by using a pin on disk method. The reason for this work is to improve the wear resistance for surface layer of tool steel after changes the morphology of the structure by rapid solidification during laser re-melting. In general, the structure consists of the dendrite and cellular structures with δ ferrite formed under conditions of rapid solidification without the primary coarse carbides. After laser melting, the results of the structure at the surface layers show an increase in wear resistance.

Abstract: Polylactic acid (PLA) nanocomposite samples with different properties like mechanical, thermal, barrier and antibacterial properties are good candidates as packaging biomaterials. Unique PLA/TiO₂ and PLA/HNTs-TiO₂ nanocomposite samples were fabricated by solution casting method. The mechanical and antibacterial properties of PLA/TiO₂ and PLA/HNTs-TiO₂ samples were investigated with comparing to the pristine PLA film as a control sample. PLA nanocomposite samples with TiO₂ nanofillers showed poorer mechanical properties while PLA films with PLA/HNTs-TiO₂ showed unique developments, which tensile strength improved by 46% with the incorporation of 5 wt%. The PLA nanocomposites showed a high efficiency to both Gram positive and Gram negative bacteria, significant antibacterial effect being proved after first week elapsed time by comparing to the control sample (presenting no antibacterial effect). By considering the multifunctional characteristics of PLA/TiO₂ and PLA/HNTs-TiO₂ nanocomposites, the samples produced by solution casting can be considered a favourable alternative as environmental-friendly packaging materials.

Abstract: In this study, PLA/TiO₂ and PLA/HNTs-TiO₂ nanocomposites films were fabricated via solution casting method. By testing the film density, solubility, water contact angle and water vapor permeability, the PLA nanocomposite films, the comprehensive performances of the nanocomposites were analysed. The outcomes demonstrated that maximum film density of PLA/TiO₂ and PLA/HNTs-TiO₂ nanocomposites films increased gradually with the increasing of nanofiller loadings. Moreover, the incorporation of TiO₂ and HNTs-TiO₂ significantly decreased the water vapor transmittance rate of the nanocomposite films with a slight priority to the addition of HNTs-TiO₂, the water solubility was significantly improved with the addition of both nanofillers. Furthermore, the barrier properties were developed with the addition of both TiO₂ and HNTs-TiO₂ especially after the addition of low nanofiller loadings. Overall, the performance of the PLA/HNTs-TiO₂ nanocomposite films was better than that PLA/TiO₂ film. Nevertheless, both of the PLA nanocomposite samples achieved the requests of food packaging applications.

Abstract: The effect of different content of steric acid (3, 6 and 9 wt.%) on the mechanical properies (tensile, flexural and impact properties) and morphology of linear low-density polyethylene / date seeds (LLDPE/DS) composites were evaulated in this research. The composites were produced by using extrusion followed by injuction molding process. Results presented that the addition of steric acid at 3 wt.% to the composite has shown highest tensile strength and elongation at break as compared to other treated samples. This is due to the improvement on the fiber surface in presence of SA. However, the tensile strength and elongation at break decreased thereafter treatment with 6% and 9% of SA. Furthermore, the flexural and impact properties have shown the same trend of the tensile properties, this was consistent with the results shown on SEM micrographs.