Kinetics of Copper Ion Leaching from Cement-Solidified Body of Blast Furnace Slag Adsorbing Copper Ion

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Blast furnace slag has good adsorption performance and can be used to adsorb heavy metal ions in waste liquid. It’s worth studying whether the blast furnace slag absorbing heavy metal ions will pose a potential threat to the environment during the process when used in cement-based materials.This paper has studied the leaching amount of copper ions in the blast furnace slag-cement system was analyzed, and analyzed the leaching kinetics of copper ions. The results showed that the leaching amount of copper ions in the blast furnace slag-cement system that adsorbed copper ions basically met the national standard, and the solidified body age was 28 days,blast furnace slag content 30% is the smallest condition for the amount of copper ion leaching.The leaching model of copper ions in the blast furnace slag-cement system is the Elovich equation, which is a heterogeneous diffusion process. The longer the curing age is the slower the leaching process is completed and do not cause environmental pollution during long-term use.

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Materials Science Forum (Volume 1035)

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1036-1042

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June 2021

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© 2021 Trans Tech Publications Ltd. All Rights Reserved

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[1] She Wenwen. Research on the influence of slag composition on the fluidity of primary and final slag[D]. Anhui University of Technology, (2019).

Google Scholar

[2] Ni Shiyue. Current Situation and Development Trend of Blast Furnace Slag Utilization [J]. Modern Metallurgy, 2014, 42(06): 1-4.

Google Scholar

[3] Liu Jinliang. Research on the adsorption performance of blast furnace slag adsorbent for heavy metal ions[D]. Inner Mongolia University of Science and Technology, (2015).

Google Scholar

[4] Li Li, Cao Jun. Study on Adsorption Properties of Cu~(2) from Blast Furnace Slag in Wastewater Applied Chemical Industry, 2016, 45(07): 1299-1303 1307.

Google Scholar

[5] Zhou Xiazhi. Study on modification of blast furnace slag and its adsorption performance of La~(3+)Ce~(3+)[D]. Jiangsu University of Science and Technology, (2019).

Google Scholar

[6] Lu D, Cao Q, Li X, et al. Kinetics and equilibrium of Cu( II) adsorption onto chemically modified orange peel cel-lulose biosorbents[J]. Hydrometallurgy, 2009, 95 (1 /2): 145-152.

DOI: 10.1016/j.hydromet.2008.05.008

Google Scholar

[7] Tian Mengying. Research on the release mechanism of heavy metals in sintered bricks [D]. Northwest A&F University, (2014).

Google Scholar

[8] Huang Yi. Study on the release of cadmium from soil and the solid-liquid balance in Chengdu urban area under acid rain[D]. Chengdu University of Technology, (2007).

Google Scholar

[9] Su Huawei, Zhang Ping, Wei Yongjie, Zhang Shuhui, Shi Huadong. Effect of fly ash on heavy metal leaching in cement hydration with waste incineration [J]. Study Fly ash. 29(01): 7-9.

Google Scholar

[10] Li Xueyuan, editor in chief. Soil Chemistry [M]. 2001 280-281.

Google Scholar

[11] Wang Xiyin. Research on the leaching method of heavy metals in building materials produced from solid waste[D]. Chongqing Jiaotong University, (2018).

Google Scholar

[12] Guo Ling, Wang Yanjiao, Zhang Ying, Ma Wei, Yuan Li. The effect of snow melting agent on the adsorption law and kinetics of Cd in soil[J]. Soil Science, 2019, 7(3): 226-232. D.

Google Scholar

[13] Tu Cong. Chemical kinetic equations in soil systems and their applications[J]. Tropical and Subtropical Soil Science, 1994, 3(3): 175-182.

Google Scholar

[14] Roy D M. Cement Research Progress[M]. American, Florida: American Ceramic Society, 1988, 261-262.

Google Scholar

[15] GB/T 7023-2011 Standard leaching test method standard for solidified low and medium level radioactive waste [S].

Google Scholar

[16] Shen Xiaodong, Yan Sheng, Wu Xuequan, Tang Mingshu. The leaching behavior of cesium from cement solidified body[J]. Nuclear Science and Engineering, 1994 (02): 134-140.

Google Scholar