Membrane Surface Morphology before and after the Reversible Hydrogen Doping of Diffusion Filters

Article Preview

Abstract:

Atomic force microscopy (АFМ) and high-precision scanning electron microscopy methods were used to study the surface of diffusion filter-membranes of alloy Pd93Y7. The formation of alterations in structure in one of membranes was established as a result from the homogenizing annealing at 900°C for 1 hours. It was found that the reversible doping of the membrane alloy with hydrogen caused the dispersion of the diffusion filter-membranes’ surface structure. Differences in changes by the surface structure are determined during the hydrogenation in directional and non-directional flow of hydrogen.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1037)

Pages:

626-631

Citation:

Online since:

July 2021

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] G.S. Burkhanov, N.B. Gorina, N.B. Kolchugina and N.R. Roshan, Palladium – Based Alloy Membranes for Separation of High Purity Hydrogen from Hydrogen – Containing Gas Mixtures, Platinum Metals Rev. 55 (2011) 3–12.

DOI: 10.1595/147106711x540346

Google Scholar

[2] G.J. Grashoff, C.E. Pilkington and C.W. Corti, The Purification of Hydrogen, Platinum Metals Rev. 27 (1983) 157-169.

Google Scholar

[3] N.A. Al-Mufachi, N.V. Rees and R. Steinberger-Wilkens, Hydrogen selective membranes: A review of palladium-based dense metal membranes, Renewable and Sustainable Energy Reviews. 47 (2015) 540-551.

DOI: 10.1016/j.rser.2015.03.026

Google Scholar

[4] J. J. Conde, M. Maroño and J. M. Sánchez-Hervás, Pd-Based Membranes for Hydrogen Separation: Review of Alloying Elements and Their Influence on Membrane Properties, Separation & Purification Rev. 46 (2017) 152–177.

DOI: 10.1080/15422119.2016.1212379

Google Scholar

[5] O. V. Akimova and A. A. Veligzhanin Effect of Annealing on the Structure of Metallic Diffusive Membrane Filters on the Base of Palladium, Physics of Metals and Metallography, 120 (2019) 962-968.

DOI: 10.1134/s0031918x19080027

Google Scholar

[6] O. V. Akimova, A. A. Veligzhanin and R. D. Svetogorov, Kinetics of the Structure Evolution Diffusion Membrane Filters of the Pd-Y System after Hydrogenation, Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques, 14 (2020) 867-874.

DOI: 10.1134/s102745102005002x

Google Scholar

[7] O.V. Akimova, A.A. Veligzhanin, R.D. Svetogorov, S.V. Gorbunov, N.R. Roshan and G.S. Burkhanov, Kinetics of Hydrogen Absorption from a Gas Phase by Diffusion Filtering Pd-Y Membranes, Physics of Metals and Metallography, 121 (2020) 157-163.

DOI: 10.1134/s0031918x20020027

Google Scholar

[8] O.V. Akimova, A.A. Veligzhanin, R.D. Svetogorov, S.V. Gorbunov, N.R. Roshan and G.S. Burkhanov, Defect structure evolution in the process of relaxation of the Pd-Y-H, Journal of Physics: Conference Series, SPb2020.

DOI: 10.1088/1742-6596/1697/1/012072

Google Scholar

[9] J.W. Martin, Micromechanisms in particle-hardened alloys, Cambridge University Press,(1980).

Google Scholar

[10] G.B. Olson and M. Cohen, A perspective on martensitic nucleation, Ann. Rev. Matter. 11 (1981) 1-30.

Google Scholar