Pressed Magnesia Composites with Improved Weather Resistance Properties

Article Preview

Abstract:

The results of studies aimed at increasing the resistance to weathering of building products based on magnesia cement are presented. This goal was achieved by the use of mine burnt rock as a modifying additive and the use of molding sands compaction pressing method. The influence of the modifier on the compressive strength change of compressed composites in dried and water-saturated state, the softening and air resistance coefficients, as well as the linear deformations of the control samples after a specified number of alternating wetting and drying cycles, was investigated. The physical and mechanical characteristics of the control samples were determined according to the standard and generally accepted methods. The formation of a complex combined structure of modified magnesian composites, containing coagulation, condensation and crystallization phases with a clear predominance of the first, has been confirmed by the physicochemical analysis methods. It is shown that modification of magnesian cement with burnt rock purposefully changes the processes of structure formation and causes an increase in water and air resistance of pressed composites based on it. The proposed method for modifying pressed magnesia products prevents loosening of their structure under alternating stresses, reduces linear deformations and, as a result, slows down fatigue failure. The involvement of a secondary resource in the composition of molding sands as an active mineral additive leads to a decrease in the cost of products and allows the method of their production to be attributed to the best available technologies. The developed compositions of pressed magnesia composites are recommended for the production of small-piece products used in building envelopes, as well as for flooring in the rooms with more than 60% humidity.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1043)

Pages:

27-35

Citation:

Online since:

August 2021

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] А.Ya. Vayvad Magnesian binders, Zinatne, Riga, (1991).

Google Scholar

[2] G.I. Berdov, V.N. Zyryanova, L.V. Ilyina, N.I. Nikonenko, V.А. Suharenko, Interfacial interaction and mechanical strength of composite binders, Part 1. Magnesian binders, Technique and technology of silicates. 21(3) (2014) 8-14.

Google Scholar

[3] N.А. Mitina. V.А. Lotov, V.V. Kabanova, А.V. Sukhushina, Features of magnesia cement hydration, Fundamental research. 8 (2013) 676-680.

Google Scholar

[4] H. Chen, Preparation and Performance of Magnesia Cement Plate Modified by Some Modifiers, International Conference on Agricultural and Natural Resources Engineering Advances in Biomedical Engineering. 3(5) (2011) 261-265.

Google Scholar

[5] Т. Chernykh, Energy-saving magnesium oxychloride cement intensifier, SGEM International Multidisciplinary Scientific Conference on Social Sciences and Arts. (2015) 359-363.

DOI: 10.5593/sgemsocial2015/b41/s15.044

Google Scholar

[6] N.A. Mitina, V.A. Lotov, A.V. Sukhushina, Influence of Heat Treatment Mode of Various Magnesia Rocks on their Properties, Procedia Chemistry. 5 (2015) 213–218.

DOI: 10.1016/j.proche.2015.10.034

Google Scholar

[7] V.V. Zimich, L.Ya. Kramar, B.Ya. Trofimov, Influence of various types of sealants on the hygroscopicity of magnesian stone, SUFU Herald. Series Building and architecture. 6(12) (2008) 13-15.

Google Scholar

[8] V.V. Prokofyeva, Decorative and technical properties of building materials based on magnesia raw materials, Bulletin of civil engineers. 2 (2012) 169-173.

Google Scholar

[9] Y. Karimi, A. Monshi, Effect of magnesium chloride concentrations on the properties of magnesium oxychloride cement for nano SiC composite purposes, Ceramics International. 37 (2011) 2405-2410.

DOI: 10.1016/j.ceramint.2011.05.082

Google Scholar

[10] А.А. Orlov, Т.N. Chernykh, L.Ya. Kramar, Glass-magnesia sheets: production problems. applications and development prospects. Construction Materials. 3 (2014) 48-52.

Google Scholar

[11] G. Li, H. Yu, Influence of Fly Ash and Silica Fume on Water-resistant Property of Magnesium Oxychloride Cement, Journal of Wuhan University of Technology-Mater. Sci. Ed. 25(4) (2010) 721-724.

DOI: 10.1007/s11595-010-0079-y

Google Scholar

[12] A. Kaklyugin, N. Stupen, L. Kastornykh, V. Kovalenko, Pressed Composites Based on Gypsum and Magnesia Binders Modified with Secondary Resources, Materials Science Forum. 1011 (2020) 52-58.

DOI: 10.4028/www.scientific.net/msf.1011.52

Google Scholar

[13] А.V. Kaklyugin, N.S. Stupen, L.I. Kastornykh, V.V. Kovalenko, Dependence of the water resistance of pressed materials based on air binders on the value of open porosity, Proceedings of Universities. Investment. Construction. Real estate. 10(1) (2020) 68–75.

DOI: 10.4028/www.scientific.net/msf.1011.52

Google Scholar

[14] Y. Li, H. Yu, L. Zheng, J. Wen, C. Wu, Y. Tan, Compressive strength of fly ash magnesium oxychloride cement containing granite wastes, Construction and Building Materials. 38 (2013) 1-7.

DOI: 10.1016/j.conbuildmat.2012.06.016

Google Scholar

[15] А.V. Kaklyugin, L.I. Kastornykh, N.S. Stupen, V.V. Kovalenko, Extruded composites based on modified gypsum binder of increased air resistance, Construction Materials. 12 (2020) 40–46. DOI: https://doi.org/10.31659/0585-430X-2020-787-12-40-46.

DOI: 10.31659/0585-430x-2020-787-12-40-46

Google Scholar

[16] N.S. Stupen, А.V. Kaklyugin, L.I. Kastornykh, V.V. Kovalenko, Increasing the air resistance of pressed composites based on magnesia binder, Vestnik MGSU [Monthly Journal on Construction and Architecture]. 16(2) (2021) 176–185.

DOI: 10.22227/1997-0935.2021.2.176-185

Google Scholar

[17] Е.А. Gamaliy, S.P. Gorbunov, B.Ya. Trofimov, Research of pozzolanic activity of burnt rocks of mine waste heaps, Progressive materials and technologies in modern construction: international. Scientific works collection, Novosibirsk. (2007-2008) 110-114.

Google Scholar

[18] I.V. Trishchenko, А.V. Kaklyugin, On the assessment of the efficiency of investments in innovative directions of development of the building materials industry, Proceedings of Universities. Investment. Construction. Real estate. 8(2) (2018) 73-83.

Google Scholar