Zea Mays Surfactant as Corrosion Inhibition of Copper and its Electrochemical Assessment in Hot Acidic Solution for Chemo-Mechanical Application

Abstract:

This study examines the corrosion propagation of copper at temperature of 298 K, 313 K and 323 K with the help of potentiodynamic polarization route and scanning electron microscopy analyses in 0.5 M HCl. The effect of zea mays surfactant at 0%, 5%, 10%, 15,%. 20% was considered and varied to estimate the inhibitive efficiency. From the results, increase in concentration of zea mays surfactant, practically reduce the corrosion rate and provides compact heteroatom thin film layer. Interestingly, metastable pitting evolution was absent until 313 K at 20 mL concentration, but at 323 K, passivation behavior tendency was absent and pits formation was seen. Undoubtedly, addition of surfactant up to 20mL into 50 mL 0.5M HCl acid shows a reduction in copper degradation which might have caused steel corrosion reaction to endothermic. The morphology study established that pit formation occur more at higher temperature of 323 K as against the 298 K. The inhibitor exhibited a physical type adsorption mechanism with inhibitive efficiency close to 90% at 20 mL admixed.

• Periodical: Materials Science Forum (Volume 1050)
• Pages: 81-91
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.1050.81
• Online since: January 2022
• Authors: Olayemi Abosede Odunlami, Ojo Sunday Issac Fayomi*, Ifeanyichukwu Okereke Elendu, Jeremiah Oludele Ojediran
• Keywords: Copper, Corrosion, Efficiency, Inhibition, Zea Mays

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