Effect of Mo and Mo+Nb Additions on the Phase Transformation and Microstructure of a Developed Low-Carbon CrNiMnB Ultrahigh-Strength Steels with a Preceding Hot Deformation

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Abstract:

The influence of molybdenum, and molybdenum with niobium addition on the phase transformation behaviour of a developed low-carbon CrNiMnB ultrahigh-strength steels, was investigated. Gleeble 3800 thermomechanical simulator was employed to simulate the hot-rolling process and to get the dilatation curves. After austenitization at 1250 °C for the complete dissolution of carbides, specimens received 0.6 total strain (i.e., 0.2 at 1100 °C and 2 x 0.2 at 900 °C) followed by cooling at various cooling rates (CRs) in the range of 2-60 °C/s. The final microstructures were investigated using laser scanning confocal microscopy, field emission scanning electron microscopy, and hardness measurements. Then the continuous cooling transformation diagrams were constructed based on the dilatation curves, microstructure, and hardness values. The electrolytic extraction method was used to assess the elements' distribution and the composition of the forming precipitates. The addition of Mo increased the hardenability, decreased the transformation temperatures, and promoted the formation of low-temperature transformation products i.e., martensite and bainite ferrite, at different CRs and inhibit the formation of polygonal ferrite. The formation of coarse precipitates neglected the effect of Mo+Nb addition, decreased the hardenability and expanded the region of BF formation to high CRs. The variation in the hardness with microstructural changes was discussed.

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Materials Science Forum (Volume 1105)

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19-27

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November 2023

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© 2023 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. Takahashi, K. Ishikawa, K. Kawakami, M. Fujioka, N. Kubota, Atomic-scale study on segregation behavior at austenite grain boundaries in boron- and molybdenum-added steels, Acta Mater. 133 (2017) 41–54.

DOI: 10.1016/j.actamat.2017.05.021

Google Scholar

[2] M. Ali, O. Seppälä, T. Fabritius, J. Kömi, Microstructure evolution and static recrystallization kinetics in hot-deformed austenite of coarse-grained Mo-free and Mo containing low-carbon CrNiMnB ultrahigh-strength steels, Mater. Today Commun. 33 (2022) 104676.

DOI: 10.1016/j.mtcomm.2022.104676

Google Scholar

[3] M. Ali, T. Nyo, A. Kaijalainen, V. Javaheri, H. Tervo, J. Hannula, M. Somani, J. Kömi, Incompatible effects of B and B + Nb additions and inclusions' characteristics on the microstructures and mechanical properties of low-carbon steels, Mater. Sci. Eng. A. 819 (2021) 141453.

DOI: 10.1016/j.msea.2021.141453

Google Scholar

[4] M.G. Akben, I. Weiss, J.J. Jonas, Dynamic precipitation and solute hardening in A V microalloyed steel and two Nb steels containing high levels of Mn, Acta Metall. 29 (1981) 111–121.

DOI: 10.1016/0001-6160(81)90092-4

Google Scholar

[5] Y. Chen, D. Zhang, Y. Liu, H. Li, D. Xu, Effect of dissolution and precipitation of Nb on the formation of acicular ferrite/bainite ferrite in low-carbon HSLA steels, Mater. Charact. 84 (2013) 232–239.

DOI: 10.1016/j.matchar.2013.08.005

Google Scholar

[6] M. Perez, E. Courtois, D. Acevedo Reyes, T. Epicier, P. Maugis, Precipitation of Niobium Carbonitrides: Chemical Composition Measurements and Modeling, Mater. Sci. Forum. 539–543 (2007) 4196–4201.

DOI: 10.4028/www.scientific.net/msf.539-543.4196

Google Scholar

[7] G.-Y. Qiao, Y.-B. Cao, B. Liao, F.-R. Xiao, Effect of hot deformation and Nb precipitation on continuous cooling transformation of a high-Nb steel, Ironmak. Steelmak. 44 (2017) 359–367.

DOI: 10.1080/03019233.2016.1210935

Google Scholar

[8] C. Fossaert, G. Rees, T. Maurickx, H.K.D.H. Bhadeshia, The effect of niobium on the hardenability of microalloyed austenite, Metall. Mater. Trans. A. 26 (1995) 21–30.

DOI: 10.1007/BF02669791

Google Scholar

[9] A.J. Deardo, Niobium in modern steels, Int. Mater. Rev. 48 (2003) 371–402.

Google Scholar

[10] J. Hannula, A. Kaijalainen, D.A. Porter, M.C. Somani, J. Kömi, Evaluation of Mechanical Properties and Microstructures of Direct‐Quenched and Direct‐Quenched and Tempered Microalloyed Ultrahigh‐Strength Steels, Steel Res. Int. 92 (2021) 2000451.

DOI: 10.1002/srin.202000451

Google Scholar

[11] T. Sipola, T. Alatarvas, E.-P. Heikkinen, T. Fabritius, Determination of Alloying Elements Ti, Nb, Mn, Ni, and Cr in Double-Stabilized Ferritic Stainless Steel Process Sample Using an Electrolytic Extraction Method and Separate Analysis of Inclusions, Metall. Mater. Trans. B. 46 (2015) 1775–1781.

DOI: 10.1007/s11663-015-0364-4

Google Scholar

[12] M. Ali, D. Porter, J. Kömi, M. Eissa, H. El Faramawy, T. Mattar, Characterization of the Microstructure and Precipitates Formed During the Thermomechanical Processing of a CrNiMoWMnV Ultrahigh‐Strength Steel, Steel Res. Int. 91 (2020) 1900580.

DOI: 10.1002/srin.201900580

Google Scholar

[13] J. Hannula, D.A. Porter, A. Kaijalainen, J. Kömi, Evaluation of Mechanical Properties and Microstructures of Molybdenum and Niobium Microalloyed Thermomechanically Rolled High-Strength Press Hardening Steel, JOM. 71 (2019) 2405–2412.

DOI: 10.1007/s11837-019-03478-9

Google Scholar

[14] K. Carpenter, C. Killmore, The Effect of Nb on the Continuous Cooling Transformation Curves of Ultra-Thin Strip CASTRIP© Steels, Metals. 5 (2015) 1857–1877.

DOI: 10.3390/met5041857

Google Scholar