Ag Doping and rGO Coupling of TiO2 within Polysiloxane Matrix for the Ecofriendly Development of High-Performance Cotton Fabric

Article Preview

Abstract:

In this work, TiO2 was applied to cotton fabric by a sol–gel-hydrothermal process. A combination of 3-(trihydroxysilyl) propyl methylphosphonate monosodium salt solution (TPMP) and (3-aminopropyl)triethoxysilane (APTES) was used as a matrix to enhance the interfacial interaction between TiO2 and surface of the cotton fibres. During the hydrothermal treatment, silver nitrate (AgNO3) or reduced graphene oxide (rGO) were added to produce Ag-doped TiO2- or rGO-coupled TiO2-coated textiles. The successful application of all investigated components on cotton fabric was confirmed by the analysis of SEM and EDS. The results of UPF determination and self-cleaning activity showed excellent performance of both studied nanocomposite coatings, whereas the use of rGO proved to be better than Ag.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1117)

Pages:

9-15

Citation:

Online since:

March 2024

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Rashid, M. M. et al. (2021). Recent advances in TiO2-functionalized textile surfaces. Surfaces and Interfaces, 22, 100890.

DOI: 10.1016/j.surfin.2020.100890

Google Scholar

[2] Nasikhudin, et al. (2018). Study on Photocatalytic Properties of TiO2 Nanoparticle in various pH condition Journal of Physics: Conference Series, 1011, 12069.

Google Scholar

[3] Vahl, A. et al. (2019). Pathways to tailor photocatalytic performance of TiO2 thin films deposited by reactive magnetron sputtering. Materials, 12, 2840.

DOI: 10.3390/ma12172840

Google Scholar

[4] Tian, J., et al. (2016). Ru nanoparticles decorated TiO2 nanobelts: A heterostructure towards enhanced photocatalytic activity and gas-phase selective oxidation of benzyl alcohol. Cheramics International, 42, 1611–1617.

DOI: 10.1016/j.ceramint.2015.09.112

Google Scholar

[5] Abbas. W. A., et al. (2019). Recent advances in the use of TiO2 nanotube powder in biological, environmental, and energy applications. Nanoscale Advances, 1, 2801–2816.

Google Scholar

[6] Etacheri, V., et al. (2015). Visible-light activation of TiO2 photocatalysts: Advances in theory and experiments. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 25, 1–29.

DOI: 10.1016/j.jphotochemrev.2015.08.003

Google Scholar

[7] Rahimi, N. et al. (2016). Review of functional titanium oxides. I: TiO2 and its modifications. Progress in Solid State Chemistry, 44, 86–105.

DOI: 10.1016/j.progsolidstchem.2016.07.002

Google Scholar

[8] Kumar, S. G., Rao, K. S. R. (2017). Comparison of modification strategies towards enhanced charge carrier separation and photocatalytic degradation activity of metal oxide semiconductors (TiO2, WO3 and ZnO). Applied Surface Science, 391, 124–148.

DOI: 10.1016/j.apsusc.2016.07.081

Google Scholar

[9] Nam, Y., et al. (2019). Photocatalytic activity of TiO2 nanoparticles: a theoretical aspect. Journal of Materials Chemistry A, 7, 13833.

Google Scholar

[10] Shen, R., et al. (2019). Surface and interface engineering of hierarchical photocatalysts. Applied Surface Science, 471, 43–87.

Google Scholar

[11] Sirivallop, A., et al. (2020). Enhanced visible light photocatalytic activity of N and Ag doped and co-doped TiO2 synthesized by using an in-situ solvothermal method for gas phase ammonia removal. Catalysts, 10, 251.

DOI: 10.3390/catal10020251

Google Scholar

[12] Demirci, S., et al. (2016). Synthesis and characterization of Ag doped TiO2 heterojunction films and their photocatalytic performances. Applied Surface Science, 390, 591–601.

DOI: 10.1016/j.apsusc.2016.08.145

Google Scholar

[13] Santos, L. M., et al. (2015). Structural characterization of Ag-doped TiO2 with enhanced photocatalytic activity. RSC Advances, 5, 103752.

Google Scholar

[14] Jaksik.J., et al. (2018). Advanced cotton fibers exhibit efficient photocatalytic self-cleaning and antimicrobial activity. Journal of Photochemistry & Photobiology A: Chemistry, 365,77–85.

DOI: 10.1016/j.jphotochem.2018.07.037

Google Scholar

[15] Elshahawy, M. F., et al. (2020). Fabrication of TiO2 reduced graphene oxide based nanocomposites for efective of photocatalytic decolorization of dye efuent. Journal of Inorganic and Organometallic Polymers and Materials, 30, 2720–2735.

DOI: 10.1007/s10904-020-01463-3

Google Scholar

[16] Wang, F., Zhang, K. (2011). Reduced graphene oxide–TiO2 nanocomposite with high photocatalystic activity for the degradation of rhodamine B. Journal of Molecular Catalysis A: Chemical, 345, 101–107.

DOI: 10.1016/j.molcata.2011.05.026

Google Scholar

[17] Gu, Y., et al. (2014). Synthesis and photocatalytic activity of graphene based doped TiO2 nanocomposites, Applied Surface Science, 319, 8–15.

DOI: 10.1016/j.apsusc.2014.04.182

Google Scholar

[18] Ul-Islam, S. (Ed.), Butola, B. S. (Ed.) (2019). Advanced functional textiles and polymers (1st ed.). John Wiley & Sons, Inc. (Hoboken, NJ) and Scrivener Publishing LLC (Beverly, MA).

Google Scholar

[19] Shabbir, M. (Ed.), Ahmed, S. (Ed.), Sheikh, J. N. (Ed.) (2020). Frontiers of textile materials. Polymers, Nanomaterials, Enzymes, and Advanced modification techniques (1st ed.). John Wiley & Sons, Inc. (Hoboken, NJ) and Scrivener Publishing LLC (Beverly, MA).

DOI: 10.1002/9781119620396

Google Scholar

[20] Kim, Y.-K., Min, D.-H. (2013). UV protection of reduced graphene oxide films by TiO2 nanoparticle incorporation. Nanoscale, 5, 3638–3642.

DOI: 10.1039/c3nr00321c

Google Scholar

[21] Tayebi, M., et al. (2019). Reduced graphene oxide (RGO) on TiO2 for an improved photoelectrochemical (PEC) and photocatalytic activity. Solar Energy, 190, 185–194.

DOI: 10.1016/j.solener.2019.08.020

Google Scholar