Sensitivity and Selectivity Detection Studies of Fe (III) Using Cu(I) Complex of Schiff Base Material

Abstract:

The liver, bones, kidneys, teeth, and central nervous system sustain serious damage as a result of heavy metal ions entering the human food chain. In order to improve public health, new techniques must be developed for the rapid, easy, simple, reliable, low-cost, and reliable identification of toxic metal ions.Naked eye detection of hazardous metal ions with Cu (I) fluorescent properties of Cu(I) Complex of with 2, 2′-bipyridine and trans cinnamic acid were investigated. The structure of the fluorescent Cu (I) complex was characterized by conductivity measurement, elemental analysis, UV-Visible and FT-IR. The Cu (I) complex was soluble in dimethylsulfoxide, distilled water, methanol and insoluble in tetrahydrofuran. In the applications, firstly the color of the Cu(I) complex was compared with/without metal ions, and then the measurements were made in the UV-Vis spectrophotometer to exhibit selective and sensitive to Fe³⁺ ions in DMSO (dimethylsulfoxide) / H₂O (water) (v/v, 1:1). Cu(I) complex exhibited absorbance band at 323 nm in dimethylsulfoxide. The absorbance intensity was decreased by Fe (III) and behaves as a turn-off sensor. The sensor showed high selectively and sensitivity toward Fe (III) over the other cations in dimethlsulfoxide solution. The equilibrium binding constant of Cu (I) complex with Fe (III) was 1.9x10 ⁴ M ^-1 as calculated using stern –volmer equation. The limit of detection was also determined and calculated as 0.219 μM. Based on facts obtained from this study, the author suggests the Copper (I) complex response to Fe (III) rapidly and a large number of consecutive ions showed almost no obvious absorbance change during detection. Copper (I) complex could act as cost effective, selective, specific and sensor for detection of Fe (III) ions over other metal ions.

• Periodical: Materials Science Forum (Volume 1119)
• Pages: 31-45
• DOI: https://doi.org/10.4028/p-O8mOcg
• Online since: March 2024
• Authors: Omod Ojulu, G. Kanthimathi*, Raji Feyisa Bogale, Ponnusamy Thillai Arasu
• Keywords: Cu (I) Complex, Fluorescence Properties, Schiff Base, Sensitivity and Detection of Fe (III)

References

[1] Cahit Demetgul, Muruvvetkarakaplan, Selahattunserin and Metindigrak "Synthesis, Characterization, and biological properties of Ni(II), Co(II), and Cu(II) complexes of Schiff bases derived from 4-aminobenzylamine", J. Coord. Chem,62(1), (2009) 3544-3551.

DOI: 10.1080/00958970903082192

[2] Mahmoud WH, Deghadi RG, Mohamed GG. "Novel Schiff base ligand and its metal complexes with some transition elements.Synthesis, spectroscopic, thermal analysis, antimicrobial and in vitro anticancer activity", Appl. Organomet. Chem. 30(4),(2016) 221–230.

DOI: 10.1002/aoc.3420

[3] Majumder A, Rosair GM, Mallick A, Chattopadhyay N, Mitra S Synthesis, structures and fluorescence of nickel, zinc and cadmium complexes with the N, N, and O-tridentate Schiff base N-2-pyridylmethylidene-2-hydroxy-phenylamine. Polyhedron 25(8), (2006) 1753–1762.

DOI: 10.1016/j.poly.2005.11.029

[4] Basak S, Sen S, Marschner C, Baumgartner J, Batten SR, Turner DR, Mitra S ." Synthesis, crystal structures and fluorescence properties of two new di-and polynuclear Cd (II) complexes with N2O donor set of a tridentate Schiff base ligand", Polyhedron 27(4), (2008) 1193–1200.

DOI: 10.1016/j.poly.2007.12.005

[5] Qian S-S, Zhang M, Wang Y-N, Tian F-Y, Liu L, You Z-L, Zhu H-L ," Synthesis, crystal structures, and fluorescent properties of zinc and cadmium (II) complexes with tridentate Schiff bases" J. Coord. Chem, 66(6), (2013) 1006–1015.

DOI: 10.1080/00958972.2013.773980

[6] Armaroli, G. Accorsi, F. Cardinali, A. Listorti, Photochemistry and photophysics of coordination compounds: copper, in: V. Balzani, S. Campagna (Eds.), " Photochemistry and Photophysics of Coordination Compounds I", Springer, Berlin/Heidelberg, 69e115,(2007).

DOI: 10.1007/128_2007_128

[7] Grybauskaite-Kaminskiene, K. Ivaniuk, G. Bagdziunas, P. Turyk,P. Stakhira, G. Baryshnikov, D. Volyniuk, V. Cherpak, B. Minaev, Z. Hotra,H. Ågren, J.V. Grazulevicius, "Contribution of TADF and exciplex emission for efficient "warm-white" OLEDs ".J. Mater. Chem. 6, (2018), 1543-1550.

DOI: 10.1039/c7tc05392d

[8] Hu, M.Y. Gao, T. Wen, Y. Kang, S. Chen,( Inorganic Chemistry 56.6507e6511,(2017).

[9] Chacko, H. Boshoff, V. Singh, D.M. Ferraris, D.R. Gollapalli, M. J Zhang, A. P Lawson, M. J Pepi, A. Joachimiak, M. Rizzi, V. Mizrahi, G. D Cuny, L. Hedstrom," Targeting Genome Integrity in Mycobacterium Tuberculosis: From Nucleotide Synthesis to DNA Replication and Repair ",Molecules, 25(5), (2020) 1205.

DOI: 10.3390/molecules25051205

[10] Nishikawa, K. Nomoto, S. Kume, K. Inoue, M. Sakai, M. Fuji, H.J. Nishihara, "Dual emission caused by ring inversion isomerization of a 4-methyl-2-pyridyl-pyrimidine copper (I) complex", Am. Chem. Soc. 132, (2010), 28, 9579–9581

DOI: 10.1021/ja103718e

[11] Smita Ghosh,Vithal A Kawade, Avinash V Sapre and Avinash S Kumbhar.,"ulse Radiolytic Studies On Ci S-Dichlorobis(1,10-Phenanthroline-,6-Dione)Cobalt(III) Complex", Journal Chemical Science, 22, (2), (2010) 225–232.

DOI: 10.1007/s12039-010-0026-7

[12] Tsuboyama,A.,et al."HomolepticCyclometalated Iridium Complexes with Highly Efficient Red Phosphorescence and Application to Organic Light-Emitting Diode. Journal of the American Chemical Society", 125(42), (2007), 12971-12979.

DOI: 10.1021/ja034732d

[13] Akine, T. Taniguchi, W. Dong, S. Masubuchi, T. Nabeshima., "Helical Metallohost−Guest Complexes via Site-Selective Transmetalation of Homotrinuclear Complexes", J. Am. Chem. Soc. 128, 49, (2006),15765–15774

DOI: 10.1021/ja0646702

[14] Alizadeh, K.; Parooi, R.; Hashemi, P.; Rezaei, B.; Ganjali, M.R. (2011). A new Schiff's base ligand immobilized agarose membrane optical sensor for selective monitoring of mercury ion. Journal Hazard Mater. 186, (2011), 1794–1800.

DOI: 10.1016/j.jhazmat.2010.12.067

[15] Jeong, U.; Kim, Y "Colorimetric detection of heavy metal ions using aminosilane". Joural of Indian English Chemistry. 31, (2015) ,393–396..

DOI: 10.1016/j.jiec.2015.07.014

[16] Silverstein,D. and Webster, M., "Spectrometric Identification of Organic Compounds" 7th Edition. John Wiley & Sons, Inc., (2005) USA.

[17] Hu F L, Yin X H, Mi Y, Zhang S S, Luo W Q., "Synthesis, characterization and luminescence properties of Eu(III) and Tb(III) complexes with novel pyrazole derivatives and 1,10-phenanthroline" Spectrochem. Acta, Part A,75(2), (2010) 825.

DOI: 10.1016/j.saa.2009.12.006