Paper Titles
Influence of Dual Soaking Durations and Variable Tool Feed Rates on Tensile Behavior of Friction Stir Welded Aluminum 2219
p.15
Nanoindentation and Simulation Analysis of Deformation Behavior in Bulk Metallic Glass Alloy
p.27
A Numerical and Experimental Model for P-TIG Welded CpTi/V/Inconel 718 Joint Incorporating Represented Volume Elements (RVEs) and Nanoindentation
p.37
Mechanical Characterization of Used Steel for Green Construction Practices
p.47
Biosynthesis of Moringa oleifera (Malunggay) Silver Nanoparticles as a Corrosion Inhibitor for A36 Mild Steel
p.59
Properties of Epoxy Coatings Electrodeposited from Cationic Epoxy Suspensions Prepared by Different Secondary Amine's Volumes
p.75
Development of Recycling of Alloyed Industrial Waste by Carbothermic Reduction with the Determination of Structural and Phase Composition of the Obtained Materials
p.87
The Effect of Additives to the Primary Material of a Current-Carrying Conductor on the Heating Temperature of an Electrical Wire
p.99
Modeling of the Efficiency of Using Sorption Metal Hydride Technologies for the Purification of Gaseous Hydrogen from Accompanying Impurities during its Production, Storage and Transportation
p.109

Biosynthesis of Moringa oleifera (Malunggay) Silver Nanoparticles as a Corrosion Inhibitor for A36 Mild Steel

Article Preview

Abstract:

In this study, researchers investigated the effectiveness of silver nanoparticles (AgNPs) combined with powder extracts from Moringa oleifera (Malunggay) for inhibiting corrosion on A36 mild steel, a common material used in the oil and gas industry. The synthesis process involved mixing AgNPs with Moringa oleifera extracts at different concentrations in acidic conditions and varying temperatures. Characterization techniques such as UV-Vis Spectroscopy, FT-IR, and TEM were used to analyze the structural and functional properties of the resulting Moringa-AgNPs. The study aimed to evaluate how these nanoparticles affected the corrosion resistance of A36 steel under different conditions, including temperature and inhibitor concentration, by assessing parameters like weight loss and corrosion rate. SEM/EDS analysis provided further insights. Overall, the research suggests that incorporating Moringa-AgNPs could be a promising strategy to reduce corrosion rates in the oil and gas industry.

You might also be interested in these eBooks
Steel, Alloys, Corrosion Protection and Materials Technologies View Preview

Info:

Periodical:

Materials Science Forum (Volume 1164)

Pages:

59-74

DOI:

https://doi.org/10.4028/p-01fMDK

Citation:

Cite this paper

Online since:

November 2025

Authors:

Trixccia Ann R. Gallamos, Danielle F. Fajardo, Marco C. Gidayawan, Emmanuel B. Carpio, Edrian E. Terciano, Jayson D. Binay*, Rugi Vicente C. Rubi

Keywords:

Corrosion, Inhibition Efficiency, Mild Steel, Moringa oleifera, Petroleum Industry

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2025 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

References

[1] Angst, U. M., "Challenges and opportunities in corrosion of steel in concrete." Materials and Structures, vol. 51, no.4. Jan. 2018.

Google Scholar

[2] W. Zhao et al., "Research Progress of Organic Corrosion Inhibitors in Metal Corrosion Protection," Crystals, vol. 13, no. 9, Art. no. 9, Sep. 2023.

Google Scholar

[3] C. Verma, E. E. Ebenso, M. A. Quraishi, and C. M. Hussain, "Recent developments in sustainable corrosion inhibitors: design, performance and industrial scale applications," Mater. Adv., vol. 2, no. 12, p.3806–3850, Jun. 2021.

DOI: 10.1039/d0ma00681e

Google Scholar

[4] M.P. Gutte, S. R. Gaur, and S. B. Hiwale, "Synthesis Of Silver Nanoparticles By Biological and Chemical Methods," vol. 8, no. 12, 2021.

Google Scholar

[5] N. Padole, N. Majgavali, M. Meshram, and N. Padole, "Synthesis And Characterization Of Silver Nanoparticles By Chemical Route For Potential Applications: A Review," vol. 31, p.2022, Apr. 2022.

Google Scholar

[6] M. Fahim, A. Shahzaib, N. Nishat, A. Jahan, T. A. Bhat, and A. Inam, "Green synthesis of silver nanoparticles: A comprehensive review of methods, influencing factors, and applications," JCIS Open, vol. 16, p.100125, Dec. 2024.

DOI: 10.1016/j.jciso.2024.100125

Google Scholar

[7] R. S. Prakasham, S. K. Buddana, S. K. Yannam, and G. S. Guntuku, "Characterization of Silver Nanoparticles Synthesized by Using Marine Isolate Streptomyces albidoflavus," vol. 22, no. 5, p.614–621, May 2012.

DOI: 10.4014/jmb.1107.07013

Google Scholar

[8] Z. Haris and I. Ahmad, "Green synthesis of silver nanoparticles using Moringa oleifera and its efficacy against gram-negative bacteria targeting quorum sensing and biofilms," J.Umm Al-Qura Univ. Appll. Sci., vol. 10, no. 1, p.156–167, Mar. 2024.

DOI: 10.1007/s43994-023-00089-8

Google Scholar

[9] Klangmanee, K., & Athipornchai, A. (n.d.). An instrument-free classification of phenolic compounds using ferric chloride reagent to improve organic chemistry teaching and learning. Tci-thaijo.org. Retrieved March 27, 2025, from https://ph02.tci-thaijo.org/index.php/scihcu/article/download/243719/165309

Google Scholar

[10] Kancherla, N., Dhakshinamoothi, A., Chitra, K., & Komaram, R. B. (2019). Preliminary analysis of phytoconstituents and evaluation of anthelminthic property of Cayratia auriculata (in vitro). Maedica, 14(4), 350–356

DOI: 10.26574/maedica.2019.14.4.350

Google Scholar

[11] Lestari, M. S., Himawan, T., Abadi, A., & Retnowati, R. (2015). Toxicity and phytochemistry test of methanol extract of several plants from papua using Brine Shrimp Lethality Test (BSLT). https://www.jocpr.com/articles/toxicity-and-phytochemistry-test-of-methanol-extract-of-several-plants-from-papua-using-brine-shrimp-lethality-test-bslt.pdf

DOI: 10.33084/jsm.v11i2.10527

Google Scholar

[12] Pérez, M., Dominguez-López, I., & Lamuela-Raventós, R. M. (2023). The chemistry behind the Folin-Ciocalteu method for the estimation of (poly)phenol content in food: Total phenolic intake in a Mediterranean dietary pattern. Journal of Agricultural and Food Chemistry, 71(46), 17543–17553

DOI: 10.1021/acs.jafc.3c04022

Google Scholar

[13] Velásquez, P., Giordano, A., Valenzuela, L. M., & Montenegro, G. (2022). Combined antioxidant capacity of Chilean bee hive products using mixture design methodology. Lebensmittel-Wissenschaft Und Technologie [Food Science and Technology], 155(112982), 112982

DOI: 10.1016/j.lwt.2021.112982

Google Scholar

[14] Gulcin, İ., & Alwasel, S. H. (2023). DPPH radical scavenging assay. Processes (Basel, Switzerland), 11(8), 2248. July 2023.

DOI: 10.3390/pr11082248

Google Scholar

[15] Asif, Muhammad et al. "Green Synthesis of Silver Nanoparticles (AgNPs), Structural Characterization, and their Antibacterial Potential." Dose-Response, vol. 20, no. 2. Apr. 2022.

DOI: 10.1177/15593258221088709

Google Scholar

[16] Cui, Yanyu, Qin, Yongxiang, Dilimulati, Dilinuer, Wang, Yujun, The Effect of Chlorine Ion on Metal Corrosion Behavior under the Scratch Defect of Coating, International Journal of Corrosion, 2019, 7982893, 11 pages, 2019

DOI: 10.1155/2019/7982893

Google Scholar

[17] Živica, V. (2002). Significance and influence of the ambient temperature as a rate factor of steel reinforcement corrosion. Bulletin of Materials Science (India), 25(5), 375–379

DOI: 10.1007/bf02708013

Google Scholar

[18] E. T. Ayoade, O. A. Akinyemi, and F. S. Oyelere, "Phytochemical profile of different morphological organs of Moringa oleifera plant," J Phytopharmacol, vol. 8, no. 6, p.295–298, Dec. 2019.

DOI: 10.31254/phyto.2019.8605

Google Scholar

[19] J. Senguttuvan, S. Paulsamy, and K. Karthika, "Phytochemical analysis and evaluation of leaf and root parts of the medicinal herb, Hypochaeris radicata L. for in vitro antioxidant activities," Asian Pacific Journal of Tropical Biomedicine, vol. 4, no. Suppl 1, p. S359, May 2014.

DOI: 10.12980/apjtb.4.2014c1030

Google Scholar

[20] Z. Nizioł-Łukaszewska, D. Furman-Toczek, T. Bujak, T. Wasilewski, and Z. Hordyjewicz-Baran, "Moringa oleifera L. Extracts as Bioactive Ingredients That Increase Safety of Body Wash Cosmetics," Dermatology Research and Practice, vol. 2020, p.8197902, Jul. 2020.

DOI: 10.1155/2020/8197902

Google Scholar

[21] S. H. Hassanpour and A. Doroudi, "Review of the antioxidant potential of flavonoids as a subgroup of polyphenols and partial substitute for synthetic antioxidants," Avicenna Journal of Phytomedicine, vol. 13, no. 4, p.354, Aug. 2023.

Google Scholar

[22] N. Younis, M. I. Khan, T. Zahoor, and M. N. Faisal, "Phytochemical and antioxidant screening of Moringa oleifera for its utilization in the management of hepatic injury," Frontiers in Nutrition, vol. 9, p.1078896, Dec. 2022.

DOI: 10.3389/fnut.2022.1078896

Google Scholar

[23] S. Jaast and A. Grewal, "Green synthesis of silver nanoparticles, characterization, and evaluation of their photocatalytic dye degradation activity," Current Research in Green and Sustainable Chemistry, vol. 4, Oct. 2021, Article 100195.

DOI: 10.1016/j.crgsc.2021.100195

Google Scholar

[24] F. Y. Alzoubi, A. A. Ahmad, I. A. Aljarrah, A. B. Migdadi, and Q. M. Al-Bataineh, "Localize surface plasmon resonance of silver nanoparticles using Mie theory," J Mater Sci: Mater Electron, vol. 34, no. 32, p.2128, Nov. 2023.

DOI: 10.1007/s10854-023-11304-x

Google Scholar

[25] S. K. Ghosh and T. Pal, "Interparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles:  From Theory to Applications," Chem. Rev., vol. 107, no. 11, p.4797–4862, Nov. 2007.

DOI: 10.1021/cr0680282

Google Scholar

[26] Eguico, C. S.-A., Abanto, M. M., Cendaña, H. T., Perez Famero, D. A., Pediongco, K. B., Cruz Evangelista, A. D., & Del Castillo Rubi, R. V., "Sonophotopythochemical Functionalization of Graphene Oxide - Al - Zn Bimetal Nanocomposite for Corrosion Inhibition." Appl. Sci. Eng., vol 18, no.2., 2024.

DOI: 10.14416/j.asep.2024.10.004

Google Scholar

[27] M. O. Oloyede, "Green synthesis of silver nanoparticles using Moringa oleifera leaf extract and their characterization," Materials Today: Proceedings, vol. 37, pp.1869-1872, 2021.

Google Scholar

[28] N. Liaqat, N. Jahan, Khalil-ur-Rahman, T. Anwar, and H. Qureshi, "Green synthesized silver nanoparticles: Optimization, characterization, antimicrobial activity, and cytotoxicity study by hemolysis assay," Frontiers in Chemistry, vol. 10, p.952006, Aug. 2022.

DOI: 10.3389/fchem.2022.952006

Google Scholar

[29] Z. Shang and J. Zhu, "Overview on plant extracts as green corrosion inhibitors in the oil and gas fields," Journal of Materials Research and Technology, vol. 15, p.5078–5094, Nov. 2021.

DOI: 10.1016/j.jmrt.2021.10.095

Google Scholar

[30] "CH103 - Chapter 7: Chemical Reactions in Biological Systems," Chemistry. Accessed: Oct. 23, 2024. [Online]. Available: https://wou.edu/chemistry/courses/online-chemistry-textbooks/ch103-allied-health-chemistry/ch103-chapter-6-introduction-to-organic-chemistry-and-biological-molecules/

Google Scholar

[31] Latiza, R. J. P., Olay, J., Eguico, C., Yan, R. J., & Rubi, R. V. (2025a). Environmental applications of carbon dots: Addressing microplastics, air and water pollution. Journal of Hazardous Materials Advances, 17(100591), 100591

DOI: 10.1016/j.hazadv.2025.100591

Google Scholar

[32] M. Akter et al., "A systematic review on silver nanoparticles-induced cytotoxicity: Physicochemical properties and perspectives," Journal of Advanced Research, vol. 9, p.1–16, Jan. 2018.

Google Scholar

[33] Latiza, R. J. P., Olay, J., Eguico, C., Yan, R. J., & Rubi, R. V. (2025). Surface matters: passivation in carbon dot synthesis—a critical review. Journal of Materials Science

DOI: 10.1007/s10853-025-10764-2

Google Scholar

[34] S. Yadav et al., "Green nanoparticles for advanced corrosion protection: Current perspectives and future prospects," Applied Surface Science Advances, vol. 21, p.100605, Jun. 2024.

DOI: 10.1016/j.apsadv.2024.100605

Google Scholar

[35] M. T. Alhaffar, S. A. Umoren, I. B. Obot, and S. A. Ali, "Isoxazolidine derivatives as corrosion inhibitors for low carbon steel in HCl solution: experimental, theoretical and effect of KI studies," RSC Adv., vol. 8, no. 4, p.1764–1777, Jan. 2018.

DOI: 10.1039/c7ra11549k

Google Scholar

[36] A. O. Okewale and O. A. Adesina, "Kinetics and thermodynamic study of corrosion inhibition of mild steel in 1.5m HCl medium using cocoa leaf extract as inhibitor," Journal of Applied Sciences and Environmental Management, vol. 24, no. 1, Art. no. 1, Feb. 2020.

DOI: 10.4314/jasem.v24i1.6

Google Scholar

[37] K. Bijapur, V. Molahalli, A. Shetty, A. Toghan, P. De Padova, and G. Hegde, "Recent Trends and Progress in Corrosion Inhibitors and Electrochemical Evaluation," Applied Sciences, vol. 13, no. 18, Art. no. 18, Jan. 2023.

DOI: 10.3390/app131810107

Google Scholar

[38] Ebadi, M., Basirun, W. J., Khaledi, H., & Ali, H. M. (2012). Corrosion inhibition properties of pyrazolylindolenine compounds on copper surface in acidic media. Chemistry Central Journal, 6(1), 163

DOI: 10.1186/1752-153X-6-163

Google Scholar

[39] Circular economy integration in 1G+2G sugarcane bioethanol production: Application of carbon capture, utilization and storage, closed-loop systems, and waste valorization for sustainability. (n.d.). Kmutnb.Ac.Th. Retrieved April 5, 2025, from https://ojs.kmutnb.ac.th/index.php/ijst/article/view/7448

DOI: 10.14416/j.asep.2024.07.005

Google Scholar

[40] S. Km, B. M. Praveen, and B. K. Devendra, "A review on corrosion inhibitors: Types, mechanisms, electrochemical analysis, corrosion rate and efficiency of corrosion inhibitors on mild steel in an acidic environment," Results in Surfaces and Interfaces, vol. 16, p.100258, Aug. 2024.

DOI: 10.1016/j.rsurfi.2024.100258

Google Scholar

[41] Soto Puelles, J., Ghorbani, M., Yunis, R., Machuca, L. L., Terryn, H., Forsyth, M., & Somers, A. E. (2021). Electrochemical and surface characterization study on the corrosion inhibition of mild steel 1030 by the cationic surfactant cetrimonium trans-4-hydroxy-cinnamate. ACS Omega, 6(3), 1941–1952

DOI: 10.1021/acsomega.0c04733

Google Scholar

[42] Hossain, N., Asaduzzaman Chowdhury, M., & Kchaou, M. (2021). An overview of green corrosion inhibitors for sustainable and environment friendly industrial development. Journal of Adhesion Science and Technology, 35(7), 673–690

DOI: 10.1080/01694243.2020.1816793

Google Scholar

[43] E. Ituen, A. Singh, Y. Li, and O. Akaranta, "Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid," Phytochemical Bulletin, vol. 3, May 2021.

DOI: 10.1016/j.clet.2021.100119

Google Scholar

[44] Scimeca, M., Bischetti, S., Lamsira, H. K., Bonfiglio, R., & Bonanno, E. (2018). Energy Dispersive X-ray (EDX) microanalysis: A powerful tool in biomedical research and diagnosis. European Journal of Histochemistry: EJH, 62(1), 2841

DOI: 10.4081/ejh.2018.2841

Google Scholar