Evaluation of Wagner Interaction Parameter in Fe-Mn-Si-Nb-Ti-V-C System

Article Preview

Abstract:

The dilute solution model is quite widely used because the chemical potential is more easily defined than that in the sub-lattice model. In the present study, the thermodynamic model for the Fe-Mn-Si-Nb-Ti-V-C system was conducted by evaluating Wagner interaction parameters. The data used in this work was collected and modified by means of TCFE 2000-database in Thermo-Calc and up-to date references. The relationship of interaction parameters(L) in the sub-lattice model and Wagner interaction parameters in the dilute solution model was derived. The composition dependency of reference state and the higher order interaction parameters of the excess Gibbs energy were considered to evaluate Wagner interaction parameters. The equilibrium compositions of austenite and fractions of phases and the dissolution temperature of precipitates(NbC, VC, and TiC) were evaluated by the dilute solution model and compared with the results by the sub-lattice model.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 475-479)

Pages:

3327-3330

Citation:

Online since:

January 2005

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2005 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] C. Wagner: Thermodynamics of Alloys, Addison-Wesley Press, Cambridge, Mass. (1952).

Google Scholar

[2] L. S. Darken: TMS-AIME Vol. 239 (1967), p.80.

Google Scholar

[3] M. Hillert: Metall. Trans. Vol. 17A (1986), p.1878.

Google Scholar

[4] A. D. Pelton and C. W. Bale: Metall. Trans. Vol. 17A (1986), p.1211.

Google Scholar

[5] W. J. Liu, J. J. Jonas and E. B. Hawbolt: International Sysmposium On Mathmatical Modelling of Hot Rolling of Steel (1990), p.457.

Google Scholar

[6] M. Hillert and L. -I. Staffanson: Acta Chem. Scand. Vol. 24 (1970), p.3618.

Google Scholar

[7] K. Balasubramanian, A. Kroupa and J. S. Kirkaldy: Metall. Trans. Vol. 23A (1992), p.709.

Google Scholar

[8] K. Balasubramanian, A. Kroupa and J. S. Kirkaldy: Metall. Trans. Vol. 23A (1992), p.729.

Google Scholar

[9] B. Sundman: Thermo-Calc, Ver. N, Royal Institute of Technology, Stockholm.

Google Scholar