Characteristics of SnOx-Coated Lithium Manganese Oxide Thin Film for MEMS Power System

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Abstract:

We prepared spinel-phase LiMn2O4 layer by using rf magnetron sputtering system. LiMn2O4 films were deposited at room temperature and then annealed at 750°C for crystallization to spinel type. In order to reduce the interface reaction such as Mn dissolution phenomenon during operation, we introduced SnOx (coating-layer) thin film. The SnOx films were deposited on LiMn2O4 films by rf magnetron sputtering system. A SnOx-coated LiMn2O4 film was more stable during the chargingdischarging reaction and maintained good cycle behavior at high temperature conditions of 55°C.

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Periodical:

Materials Science Forum (Volumes 486-487)

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562-565

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June 2005

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© 2005 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. H. Jung, B. H. Kim, D. E. Lee, S. Y. Lee, B. W. Moon, J. Joo, S. H. Chang and K. S. Ryu, J. Korean Phys. Soc. 37, 396 (2000).

Google Scholar

[2] Y. -I. Kim, H. -S. Ji, S. -H. Seong and J. -W. Park, J. Korean Phys. Soc. 39. S337 (2001).

Google Scholar

[3] F. K Shokoohi, J. M. Tarascon and B. J. Wilkens, Appl. Phys. Lett. 59, 1260 (1991).

Google Scholar

[4] J. M. Tarascon, E. Wang, F. K. Shokoohi, W. R. McKinnon and S. Colson, J. Electrochem. Soc. 138, 2859 (1991).

Google Scholar

[5] Y. Xia, Y. Zhou, M. Yoshio, J. Electrochem. Soc. 144 (1997) 2593.

Google Scholar

5 10 15 20 25 30 35 40 45 50.

Google Scholar

[5] [10] [15] [20] [25] [30] [35] [40] [45] [50] [55] Cycle Number Non-coated spinel film SnOx-1 min coated spinel film SnOx-2 min coated spinel film SnOx-5 min coated spinel film.

DOI: 10.37473/dac/10.1007/s10854-022-08219-4

Google Scholar

5 10 15 20 25 30 35 40 45 50.

Google Scholar

[5] [10] [15] [20] [25] [30] [35] [40] [45] [50] [55] Cycle Number Non-coated spinel film SnOx-1 min coated spinel film SnOx-2 min coated spinel film SnOx-5 min coated spinel film Fig 4. Cyclic behaviors of the non-coated LiMn2O4 and SnOx 1min, 2min and 5min coated LiMn2O4 at (a) room temperature and (b) 55℃℃℃℃ high temperature. (b)(b)(b)(b) (a)(a)(a)(a).

DOI: 10.1021/acsami.9b09901.s003

Google Scholar