Ga-Modified Nanostructured ZnO: Characterization and Application in Dye-Sensitized Solar Cells

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Abstract:

ZnO has received great attention in many applications due to its electronic and optical properties. We report on the preparation of ZnO and gallium-containing ZnO (ZnO:Ga) nanoparticles by the precipitation method. The nanoparticles have the wurtzite structure and a high crystallinity. Gallium ions are present as Ga3+, as evidenced by the binding energies through XPS. Porosity and surface area of the powder increased under increasing gallium level, explained by the smaller particle size of ZnO:Ga samples compared with ZnO. The estimated optical band gap of ZnO was 3.2 eV, comparable to ZnO:Ga.

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Periodical:

Materials Science Forum (Volumes 591-593)

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13-17

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Online since:

August 2008

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© 2008 Trans Tech Publications Ltd. All Rights Reserved

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