The Formation and Morphology of PVA Ferrogel Nanofibre by the Electrospinning Process

Article Preview

Abstract:

Aqueous solutions of polyvinyl alcohol (PVA) with FeCl3 were homogenously mixed and subsequently electrospun; and its characteristics were studied as a function of voltage, tip-target distance and solution flow rate. Fiber mats of (PVA)/FeCl3 composite, in the diameter of 700–1100 nm were prepared by electrospinning. Lower concentrations of solution tended to facilitate the formation of fibres with beads. With increasing concentration, the morphology was improved with smooth and uniform fibres and the increased fibre diameters in the nano range. Spinning voltage also had an important influence on the diameters of the nano fibres, while the collection distance affected fibre diameters. Nano fibres of smaller diameter were formed when lower voltages are applied. The morphology of the electrospun from PVA/FeCl3 nano fibres and their magnetic power was observed and analyzed by scanning electron microscopy (SEM).The fibres produced in this way could potentially be applied to manufacture magnetic sensors, flexible magnets.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

361-366

Citation:

Online since:

May 2010

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2010 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Formhals, A.U.S. Patent No. 1975504, (1934).

Google Scholar

[2] DH, Reneker, I. Chun, Nanometer diameter fibres of polymer produced by electrospinning. Nanotechnology 1996, 7: 216-23.

DOI: 10.1088/0957-4484/7/3/009

Google Scholar

[3] ZM Huang, YZ Zhang, M Kotaki, S. A Ramakrishna, review on polymer nanofibres by electrospinning and their applications in nanocomposites, Compos Sci Technology 2003, 63: 223-53.

Google Scholar

[4] G. G, Chase, R. D Ramsier, Alessandro. M, Katta, P. Continous, electrospinning of aligned polymer nanofibres onto a wire drum collector. Nano letters, Vol. 4, No. 11 2215-2218, (2003).

DOI: 10.1021/nl0486158

Google Scholar

[5] J. Doshi, D.H. Reneker, J. Electrost. 1995, 35, 151.

Google Scholar

[6] M. M., Bershoef, G.J. Vancso, Adv. materials, 1999, 11. 1362.

Google Scholar

[7] W.M. Edwards, U.S. Patent No. 3415782, (1965).

Google Scholar

[8] R.S. Irwin, U.S. Patent No 3415782, (1968).

Google Scholar

[9] A. L Yarin, E Zussman, Theorn, S.A. Experimental investigation of the governing parametrs in the electrospinning of polymer solutions, European polymer journal, 45 (2004) 2017-(2030).

DOI: 10.1016/j.polymer.2004.01.024

Google Scholar

[10] Fong H, Chun I, reneker DH. Polymer 40 (1999) 4585-92.

Google Scholar

[11] YM Shin, MM Hohman, MP Brenner, GC Rutledge, polymer, 9955-67 (2001).

Google Scholar

[12] J Sheng, Y Han., L Wu., X Yuan., C Zhang., Study on morphology of electrospun poly (vinyl alcohol) mats, European polymer journal 41 (2005) 423-432.

DOI: 10.1016/j.eurpolymj.2004.10.027

Google Scholar

[13] W K. Sona, J H Youkb, T S Leec Matter. Letts 59 1571. (2005).

Google Scholar

[14] M. Krumova, D. Lopez, R. Benavente, C. Mijangos, J.M. Perena, Polymer 41 9265. (2000).

Google Scholar

[15] Shivkumar. S, Yim. K, Koski. A, Effect of molecular weight on fibrous PVA produced by electrospiing, Materials letters 58 (2004) 493-497.

DOI: 10.1016/s0167-577x(03)00532-9

Google Scholar

[16] L Yao, T W Haas, A G Elie, L Bowlin Gary, D G Simpson and G E Wnek, Chem. Mater. 15 1860 (2003).

Google Scholar

[17] A Koski, K Yim and S Shivkumar Mater. Lett. 58 p.4939 (2004).

Google Scholar

[18] X.H., Zong, K.S. Kim, D.F. Fang, S.F. Ran, B.S. Hsiao & B.J. Chu. Structure and process relationship of electrospun bioabsorbable nanofibre membranes, Polymer Volume 43, Issue 16, July Pages 4403-4412 (2002).

DOI: 10.1016/s0032-3861(02)00275-6

Google Scholar

[19] S.Y. GU, J Ren, G.J. Vancso, Eur, Polymer J, 41, 2559, ( 2005).

Google Scholar

[20] H Chun I Fong, DH. Reneker, Beaded nanofibers formed during electrospinning, Polymer 40 4585-4592. (1999).

DOI: 10.1016/s0032-3861(99)00068-3

Google Scholar

[21] L. Larrondo, R.S.J. Manley, Electrostatic fiber spinning from polymer melts; electrostatic deformation of pendent drop of polymer melt. Journal of polymer science, (19): p.933. ( 1981).

DOI: 10.1002/pol.1981.180190603

Google Scholar

[22] K. Baumgarten, Electrostatic spinning of acrylic micro fibers, J Colloid Interface Science, 36 (no. 1); 71-9 (1971).

Google Scholar

[23] S.H. Tan, R. Inai, M. Kotaki, S. Ramakrishna, Polymer, 46, 6128. (2005).

Google Scholar