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Synthesis by Stille Cross-Coupling Procedure and Electrochemical Characterization of Branched Polymers Based on Substituted 1,3,5-Triarylbenzenes

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Abstract:

A series of various substituted 1,3,5-triarylbenzenes, 2,4,6-triaryl-1-phenoles, 1,3,5-triaryl-1-methoxybenzenes and 2,4,6-triaryl-1,3,5-trimethoxybenzenes were synthesized by a Stille cross-coupling procedure. Their structures were confirmed by 1H NMR, 13C NMR, and elemental analysis. Containing thienyl, furyl and EDOT groups polymers obtained in the process of electropolymerization could be carefully considered as a building material in a wide range of organic-electronic devices. We compare properties of monomers and related polymers depending on aryls moieties and their influence of hydroxyl and methoxyl groups attached to the central benzene core.

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Periodical:

Materials Science Forum (Volumes 663-665)

Pages:

876-879

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.663-665.876

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Online since:

November 2010

Authors:

Krzysztof R. Idzik, Rainer Beckert, Eric Tauscher, Przemyslaw Ledwon, Sylwia Golba, Mieczyslaw Lapkowski, Peter Rapta, Lothar Dunsch, Jaroslaw Frydel

Keywords:

Cyclic Voltammetry (CV), Electrochemical Polymerization, Hyperbranched Polymer, Stille Coupling Procedure

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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