Synthesis by Stille Cross-Coupling Procedure and Electrochemical Characterization of Branched Polymers Based on Substituted 1,3,5-Triarylbenzenes
A series of various substituted 1,3,5-triarylbenzenes, 2,4,6-triaryl-1-phenoles, 1,3,5-triaryl-1-methoxybenzenes and 2,4,6-triaryl-1,3,5-trimethoxybenzenes were synthesized by a Stille cross-coupling procedure. Their structures were confirmed by 1H NMR, 13C NMR, and elemental analysis. Containing thienyl, furyl and EDOT groups polymers obtained in the process of electropolymerization could be carefully considered as a building material in a wide range of organic-electronic devices. We compare properties of monomers and related polymers depending on aryls moieties and their influence of hydroxyl and methoxyl groups attached to the central benzene core.
Yuan Ming Huang
K. R. Idzik et al., "Synthesis by Stille Cross-Coupling Procedure and Electrochemical Characterization of Branched Polymers Based on Substituted 1,3,5-Triarylbenzenes", Materials Science Forum, Vols. 663-665, pp. 876-879, 2011