Paper Titles

The early Stages of the Scale Growth on FeCrAl(+RE)-Type Alumina Formers
p.70

Thermodynamic Stability and Reaction Sequence for High Temperature Oxidation Processes in Steels
p.76

Modeling Internal Oxidation of Binary Ni Alloys
p.82

Calculation of Boundary Conditions between Internal and External Oxidation of Silicon or Chromium Containing Steels
p.88

Scale Surface and Scale/Alloy Interface for Alumina-Forming Alloys with Noble Metal and Yttrium
p.94

Failure Characteristics of Scales Formed on Si-Containing Low Carbon Steels during Cooling - Influences of Cooling Rate and Water Vapor
p.101

High Temperature Oxidation of Advanced High Strength Steel: HT-XRD Method for Quantitative Evaluation
p.107

High-Temperature Oxidation of Low-Carbon Steel Coated by Solution-Spraying with Cerium and Aluminum Ions
p.114

High Temperature Service Experience and Failure Analysis of some Heat Resistant Stainless Steels
p.120

HomeMaterials Science ForumMaterials Science Forum Vol. 696Scale Surface and Scale/Alloy Interface for...

Scale Surface and Scale/Alloy Interface for Alumina-Forming Alloys with Noble Metal and Yttrium

Article Preview

Abstract:

Scale surface and scale/alloy interface for alumina-forming (Fe-20Cr-4Al) alloys with noble metal (palladium, platinum) and yttrium were studied in oxidizing atmospheres (oxygen, oxygen-water vapor) for 18ks at 1473, 1573 and 1673K, by mass gain measurements, amount of spalled oxide, X-ray diffraction (XRD), scanning electron microscopy (SEM) and field emission-transmission electron microscopy/energy dispersive spectroscopy (FE-TEM/EDS). After oxidation at 1473K for 18ks in oxygen, the mass gains of the FeCrAl, FeCrAlPd and FeCrAlPt alloys showed almost the same values. Those of the FeCrAlY alloys decreased with increasing yttrium of up to 0.1% followed by an increase with the yttrium content. The mass gain of the FeCrAlPtY alloys with appropriate additions of platinum and yttrium were lower than that of the FeCrAlY alloy with 0.1mass% yttrium, and alumina/alloy interface of the alloy showed good coherency by TEM. The scale surface of the FeCrAl, FeCrAlPd and FeCrAlPt alloys were rough, however, those of the FeCrAlY and FeCrAlPtY alloys were smooth. After oxidation at 1673K for 18ks in water-vapor (47vol%), FeCrAlPt alloy with 0.5mass% platinum showed good oxide adherence. Platinum concentration was observed at alloy side of the alumina/alloy interface by FE TEM/EDS.

You might also be interested in these eBooks

High-Temperature Oxidation and Corrosion 2010

Info:

Periodical:

Materials Science Forum (Volume 696)

Pages:

94-100

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.696.94

Citation:

Cite this paper

Online since:

September 2011

Authors:

Tadaaki Amano

Keywords:

FeCrAl, Noble Metal, Oxidation, Scale Surface, Scale/Alloy Interface, Yttrium

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Y. Ikeda, K. Nii, C. Yoshihara, Trans. Japan Inst. Met. Suppl., 207(1983).

[2] A. W. Funkenbusch, J. G. Smeggil, N. S. Bornstein, Met. Trans., 16A, 1164(1985).

[3] C. Mennicke, E. Schumann, J. Le Coze, J. L. Smialek, G. H. Meier, M. Rule, in: S. B. Newcomb, J. A. Little, (Eds. ), Microscopy of Oxidation Vol. 3, 95(1997).

[4] H. Al-Baddairy,G. J. Tatlock, J. Le Coze, in: in: S. B. Newcomb, J. A. Little, (Eds. ), Microscopy of Oxidation Vol. 3, 105(1997).

[5] J. L. Smialek, in: S. B. Newcomb, J. A. Little, (Eds. ), Microscopy of Oxidation Vol. 3, 127(1997).

[6] P.Y. Hou, K. Wang, K. Prusner, K. B. Alexander, I. G. Brown, in: S. B. Newcomb, J. A. Little, (Eds. ), Microscopy of Oxidation Vol. 3, 140(1997).

[7] P.Y. Hou, Oxid. Met., 52, 337(1999).

[8] P.Y. Hou, J. L. Smialek, Mat. at High Temp., 17, 79(2000).

[9] T. Amano, T. Watanabe, K. Michiyama, J. Japan Inst. Met., 61, 1077(1997).

[10] T. Amano, T. Watanabe, K. Michiyama, Oxid. Met., 53, 451(2000).

[11] T. Amano, A. Hara, N. Sakai, K. Sasaki, Mat. at High Temp., 17, 117(2000).

[12] T. Amano, T. Watanabe, A. Hara, N. Sakai, I, Isobe, K. Sasaki, T. Shishido, ISIJ Int., 44, 145(2004).

DOI: 10.2355/isijinternational.44.145

[13] T. Amano, S. Yajima, Y. Saito, Trans. Japan Inst. Met. Suppl., 247(1983).

[14] H. Okabe, J. Japan Inst. Met., 49, 891(1985).

[15] H. Okabe, J. Japan Inst. Met., 50, 500(1986).

[16] T. Amano, K. Michiyama, K. Okazaki, in: L. Maldonado, M. Pech (Eds. ), Proc. 1st Mexican Symp. Met., Corros., , 119, 258(1994).

[17] A. S. Khanna, H. Jonas, W. J. Quadakkers, Werkstoffe and Korrosion, 40, 552(1989).

[18] B. A. Pint, Oxid. Met., 45, 1(1996).

[19] T. Amano, I. Isobe, N. Sakai, T. Shishido, J. Alloys and Comp., 344, 394(2002).

[20] K. Fukuda, K. Takao, T. Hoshi, Y. Usui, O. Furuki, Mat. at High Temp., 20, 319(2003).

[21] S. Chevalier, J. P. Larpin, P. Dufour, G. Strehl, G. Borchardt, K. Przybylski, S. Wwber, H. Scherrer, Mat. at High Temp., 20, 365(2003).

DOI: 10.1179/mht.2003.043

[22] B. A. Pint, K. L. More, I. G. Wright, Mat. at High Temp., , 20, 375(2003).

[23] T. Amano, H. Isobe, K. Yamada, T. Shishido, Mat. at High Temp., 20, 387(2003).

[24] V. Kochubey, H. Al-Badairy, G. Tatlock, J. Le-Coze, D. Naumenko, W. J. Quadakkers, Materials and Corrosion, 56, 848(2005).

DOI: 10.1002/maco.200503915

[25] F. J. Felten, Oxid. Met., 10, 23(1976).

[26] F. J. Felten, F. S. Pettit, Oxid. Met., 10, 189(1976).

[27] I. M. Allam, H. C. Akuezue, D. P. Whittle, Oxid. Met., 14, 517(1980).

[28] G. Gleeson, W. Wang, S. Hayashi, D. Sordelet, Materials Science Forum, 461-464, 213(2004).

[29] B. A. Pint, Surface & Coatings Technology, 188-189, 71(2004).

[30] T. Amano, M. Okazaki, K. Takeuchi, T. Shishido, Mat. at High Temp., 22, 473 (2005).

[31] T. Amano, A. Shiino, T. Shishido, presented at EUROCORR'2007, Freiburg, Germany, September 9-13, pp.1-7(2007).

[32] T. Amano, Y. Takezawa, A. Shiino, T. Shishido, J. Alloys and Comp., 452, 16(2008).

[33] T. Amano, Proc. 17th International Corrosion Congress, Paper No. 2314(2008).

[34] R. Kartono, D. J. Young, Materials and Corrosion, 59, 455(2008).

[35] R. Janakiraman, G. H. Meier, F. S. Pettit, Proc. 1997 Tri-Service Conference on Corrosion, Wrightsville Beach, NC, Office of Naval Research, pp.39-62(1977).

[36] K. Onal, M.C. Maris-Sida, G. H. Meier, F. S. Pettit, Mat. at High Temp., 20, 327(2003).

[37] E. J. Opila, The 6th International Symposium on High Temperature Corrosion and Protection of Materials, Les Embiez, France, pp.1-9(2004).

[38] J. L. Smialek, Materials Science Forum, vol. 595-598, Trans Tech Publications, Switzerland, pp.191-198(2008).

[39] L. Horn, Z. Metallkde, 40, 73(1949).