Observation of Diatom Settling and Photocatalytic Antifouling on TiO2 Using ATR-IR Spectroscopy

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Abstract:

The settling of marine diatoms Amphora coffeaeformis onto a photocatalytic titanium dioxide surface was monitored by ATR-IR. Attachment of the diatoms via their mucilaginous secretions was monitored via observation of protein amide I and II linkages, carboxylate linkages from a uronic acid polysaccharide, and sulfate ester groups. Exposure to UV-A light resulted in the rapid removal of the groups attached to the photocatalyst surface, demonstrating the potential antifouling capability of a TiO2 anatase surface.

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227-230

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September 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] A.L. Linsebigler, G. Lu, and J.T. Yates Jr., Photocatalysis on TiO2 surfaces: Principles, mechanism and selected results, Chem. Rev, 95 (1995) 735-758.

DOI: 10.1021/cr00035a013

Google Scholar

[2] A.M. Smith, J.A. Callow, (Eds); Biological Adhesives, Springer, Berlin 2006.

Google Scholar

[3] B.A. Wustmann, M.R. Gretz, and K.D. Hoagland, Extracellular matrix assembly in diatoms (Bacillariophyceae) (I. A model of adhesives based on chemical characterization and localization of polysaccharides from the marine diatom achnanthes longipes and other diatoms), Plant Physiol. 113 (1997) 1059-1069.

DOI: 10.1104/pp.113.4.1059

Google Scholar

[4] A.J. McQuillan, Probing solid-solution interfacial chemistry with ATR-IR spectroscopy of particle films. Adv. Mater. 13 (2001) 1034-1038.

DOI: 10.1002/1521-4095(200107)13:12/13<1034::aid-adma1034>3.0.co;2-7

Google Scholar

[5] R. Asada, M. Okuno and K. Tazaki, Structural anisotropy of biogenic silica of pennate diatoms under Fourier transform polarized infrared microspectroscopy, J. Mineral. Petrolog. Sci. 97 (2002) 219-226.

DOI: 10.2465/jmps.97.219

Google Scholar