Role of Multiwall Carbon Nanotubes (MWCNT) on Electrical Conductivity of Polymer Composite as Alternative Materials for Bipolar Plate Fuel Cell

Article Preview

Abstract:

Polypropylene can be improved an electrical conductivity by addition of carbon and multiwall carbon nanotube (MWCNT) as well as combination with copper (Cu) powder. Multiwall carbon nanotube used from 0.1 wt%, 0.5 wt% to 1 wt% while the addition of Cu powder into PP/C was various from 0.1 wt%, 0.2wt% to 0.5wt% respectively. This research focuses on material design of composite based on polymer and carbon to improve an electrical conductivity according to electrical conductivity requirement for bipolar plate. Bipolar plate is one of the components in PEMFC constituted a crucial component that collects and transfers electron from the anode to the cathode, therefore it should possess high electrical conductivity. The main discussion in this research is to analyze the role of multiwall carbon nano tube (MWCNT) and copper on electrical conductivity of polymer composites produced. Functional groups analysis using Fourier Transform Infrared Spectroscopy (FTIR) was also carried out to investigate whether carbon has been mixed perfectly within polypropylene. It is found that the effect of adding a small amount of MWCNT and Cu have improved their electrical conductivity of composites up to 15.62 S/cm.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

183-190

Citation:

Online since:

January 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] R.A. Antunes, M.C.L. de Oliveira, G. Ett, V. Ett., Carbon materials in composite bipolar plates for polymer electrolyte membrane fuel cells: A review of the main challenges to improve electrical performance. Journal of Power Sources 196 (2011) 2945–2961.

DOI: 10.1016/j.jpowsour.2010.12.041

Google Scholar

[2] S.R. Dhakate, S. Sharma, N. Chauhan, R.K. Seth, R.B. Mathur, Int. J. Hydrogen Energy 35 (2010) 4195–4200.

DOI: 10.1016/j.ijhydene.2010.02.072

Google Scholar

[3] S.-H. Liao, M.-C. Hsiao, C.-Y. Yen, C.-C.M. Ma, S.-J. Lee, A. Su, M.-C. Tsai, M.-Y. Yen, P.-L. Liu, Journal of Power Sources 195 (2010) 7808–7817.

DOI: 10.1016/j.jpowsour.2009.10.020

Google Scholar

[4] S.-H. Liao, C.-H. Hung, C.-C.M. Ma, C.-Y. Yen, Y.-F. Lin, C.-C. Weng, Journal of Power Sources 176 (2008) 175–182.

Google Scholar

[5] S.-H. Liao, C.-Y. Yen, C.-C. Weng, Y.-F. Lin, C.-C.M. Ma, C.-H. Yang, M.-C. Tsai, M.-Y. Yen, M.-C. Hsiao, S.-H. Lee, X.-F. Xie, Y.-H. Hsiao, Journal of Power Sources 185 (2008) 1225–1232.

DOI: 10.1016/j.jpowsour.2008.06.097

Google Scholar

[6] L.-G. Xia, A.-J. Li, W.-Q. Wang, Q. Yin, H. Lin, Y.-B. Zhao, Journal of Power Sources 178 (2008) 363–367.

Google Scholar

[7] C.-F. Kuan, H.-C. Kuan, C.-C.M. Ma, C.-H. Chen, J. Phys. Chem. Solids 69 (2008) 1395–1398.

Google Scholar

[8] C.F. Kuan, H.C. Kuan, C.C.M. Ma. Mechanical and electrical properties of multi-wall carbon nanotube/poly(lactic acid) composites. J. Phys. Chem. Solids 69 (2008) 1395-1398.

DOI: 10.1016/j.jpcs.2007.10.060

Google Scholar

[9] S.H. Liao, C.H. Hung, C.C.M. Ma, C.Y. Yen, Y.F. Lin, C.C. Weng. Preparation and properties of carbon nanotube-reinforced vinyl ester/nanocomposite bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources 176 (2008) 175–182.

DOI: 10.1016/j.jpowsour.2007.10.064

Google Scholar

[10] R.B. Mathur, S.R. Dhakate, D.K. Gupta, T.L. Dhami, R.K. Aggarwal, Journal Mater. Process. Technol. 203 (2008) 184–192.

Google Scholar

[11] J.H. Lee, Y.K. Jang, C.E. Hong, N.H. Kim, P. Li, H.K. Lee, J. Power Sources 193 (2009) 523–529.

Google Scholar

[12] B.D. Cunningham, D.G. Baird, Journal Power Sources 168 (2007) 418–425.

Google Scholar

[13] Y.Wang, Thesis Master of Applied Science, Chemical Engineering, University of Waterloo, Ontario Canada, (2006)

Google Scholar

[14] R.A. Antunes, M.C.L. de Oliveira, G. Ett, V. Ett.. Carbon materials in composite bipolar plates for polymer electrolyte membrane fuel cells: A review of the main challenges to improve electrical performance. Journal of Power Sources 196 (2011) 2945–2961.

DOI: 10.1016/j.jpowsour.2010.12.041

Google Scholar

[15] S.H. Liao, C.C. Weng, C.Y. Yen, M.C. Hsiao, C.C.M. Ma, M.C. Tsai, Ay Su, M.Y. Yen, Y.F. Lin, P.L. Liu. Preparation and properties of functionalized multiwalled carbon nanotubes/polypropylene nanocomposite bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources 195 (2010), 263-270.

DOI: 10.1016/j.jpowsour.2009.06.064

Google Scholar

[16] Sastrohamidjojo, Hardjono. Spektroskopi Infra Merah. Yogyakarta: Liberty (1994) 15-16.

Google Scholar