Paper Titles

Preface, Organizers and Supporters

Effect of Fe on the Precipitate Characteristics and Out-of-Pile Corrosion Behavior of Zr-1Nb-xFe Alloys
p.1

Synthesis and Electrochemical Performance of Graphite Oxide as Cathode Material for Rechargeable Batteries
p.8

Evaluation of Pulsed Laser Deposited Li₄Ti₅O₁₂ Thin Film Anodes by CV and EIS
p.13

Reactant Concentration and Carbonization to the Controllable Fabrication of Carbon Aerogels
p.20

Al-Si-Mg-Cu Heat Storage Alloys and their Heat Storage Properties
p.24

Preparation of Polymer Capsules for Solid Hydrogen Storage
p.29

Synthesis and Electrochemical Performances of Nanoparticle FePO₄ and Ce-Doped FePO₄ Cathode Materials for Lithium Ion Batteries by Microemulsion Method
p.35

First-Principles Studies on the Structures and Properties of Ti- and Zn-Substituted Mg₂Ni Hydrogen Storage Alloys and their Hydrides
p.44

HomeMaterials Science ForumMaterials Science Forum Vols. 743-744Evaluation of Pulsed Laser Deposited Li4Ti5O12 ...

Evaluation of Pulsed Laser Deposited Li₄Ti₅O₁₂ Thin Film Anodes by CV and EIS

Article Preview

Abstract:

Li₄Ti₅O₁₂ thin film anodes were prepared successfully using pulsed laser deposition technique. The thin films were characterized by X-ray diffraction and environmental scanning electron microscopy. The effects of thickness and scan rate on the electrochemical properties of Li₄Ti₅O₁₂ thin film electrodes were discussed in detail. The thin film anodes deliver favorable capacity and excellent cycling performance. The discharge capacity maintains at 141 mAhg^-1 after 20 cycles at 1C charge-discharge rate for the thin film anodes deposited for 20 minutes. The charge-transfer resistances were also investigated by electrochemical impedance spectroscopy.

You might also be interested in these eBooks

Energy and Environment Materials

Info:

Periodical:

Materials Science Forum (Volumes 743-744)

Pages:

13-19

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.743-744.13

Citation:

Cite this paper

Online since:

January 2013

Authors:

Jian Qiu Deng, Zhou Guang Lu, Chi Yuen Chung, Zhong Min Wang, Huai Ying Zhou

Keywords:

Cyclic Voltammetry (CV), Lithium Titanate, Rechargeable Lithium Ion Batteries, Thin Film Electrode

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] K. Ariyoshi, R. Yamato, T. Ohzuku, Zero-strain insertion mechanism of Li[Li1/3Ti5/3]O4 for advanced lithium-ion (shuttlecock) batteries, Electrochim. Acta. 51 (2005) 1125-1129.

DOI: 10.1016/j.electacta.2005.05.053

[2] E.M. Sorensen, S.J. Barry, H.K. Jung, J.R. Rondinelli, J.T. Vaughey, K.R. Poeppelmeier, Three dimensionally ordered macroporous Li4Ti5O12: effect of wall structure on electrochemical properties, Chem. Mater. 18 (2006) 482-489.

DOI: 10.1021/cm052203y

[3] C.H. Jiang, Y. Zhou, I. Honma, T. Kudo, H.S. Zhou, Preparation and rate capability of Li4Ti5O12 hollow-sphere anode material, J. Power Sources. 166 (2007) 514-518.

DOI: 10.1016/j.jpowsour.2007.01.065

[4] W. Lu, J. Liu, Y.K. Sun, K. Amine, Electrochemical performance of Li4/3Ti5/3O4/Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 cell for high power applications, J. Power Sources 167 (2007) 212-216.

DOI: 10.1016/j.jpowsour.2006.12.077

[5] K.S. Park, A. Benayad, D.J. Kang, S.G. Doo, Nitridation-driven conductive Li4Ti5O12 for lithium ion batteries, J. Am. Chem. Soc. 130 (2008) 14930-1.

DOI: 10.1021/ja806104n

[6] J.X. Ma, C.S. Wang, S. Wroblewski, Kinetic characteristics of mixed conductive electrodes for lithium ion batteries, J. Power Sources . 164 (2007) 849-856.

DOI: 10.1016/j.jpowsour.2006.11.024

[7] E. Ferg, R.J. Gummow, A. de Kock , M.M. Thackeray, Spinel anodes for lithium-ion batteries, J. Electrochem. Soc. 141 (1994) L147-L150.

DOI: 10.1149/1.2059324

[8] F. Ronci, P. Reale, B. Scrosati, P. Panero, V.R. Albertini, P. Perfetti, et al., High-resolution in-situ structural measurements of the Li4/3Ti5/3O4 Zero-Strain, insertion material, J. Phys. Chem. B. 106 (2002) 3082-3086.

DOI: 10.1021/jp013240p

[9] H.M. Wu, I. Belharouak, H. Deng, A. Abouimrane, Y.K. Sun, K. Amine, Development of LiNi0. 5Mn1. 5O4/Li4Ti5O12 system with long cycle life, J. Electrochem. Soc. 156 (2009) A 1047-A1050.

[10] A. Rougier, K.A. Striebel, S.J. Wen, E.J. Cairns. Cyclic voltammetry of pulsed laser deposited LixMn2O4 thin films, J. Electrochem. Soc. 145 (1998) 2975-2980.

DOI: 10.1149/1.1838750

[11] M.V. Reddy, B. Pecquenard, P. Vinatier, A. Levasseur, Cyclic voltammetry and galvanostatic cycling characteristics of LiNiVO4 thin films during lithium insertion and re/de-insertion, Electrochem. Comm. 9 (2007) 409-415.

DOI: 10.1016/j.elecom.2006.10.011

[12] G. Leftheriotis, S. Papaefthimiou, P. Yianoulis, Dependence of the estimated diffusion coefficient of LixWO3 films on the scan rate of cyclic voltammetry experiments, Solid State Ionics. 178 (2007) 259-263.

DOI: 10.1016/j.ssi.2006.12.019

[13] D.Y.W. Yu, C. Fietzek, W. Weydanz, K. Donoue, T. Inoue, H. Kurokawa, et al., Study of LiFePO4 by cyclic voltammetry, J. Electrochem. Soc. 154 (2007) A253-A257.

DOI: 10.1149/1.2434687

[14] Y.H. Rho, K. Kanamura, Preparation of Li4/3Ti5/3O4 thin film electrodes by a PVP sol-gel coating method and their electrochemical properties, J. Electrochem. Soc. 151 (2004) A106-A110.

DOI: 10.1002/chin.200416018

[15] Y. Yu, J.L. Shui, C.H. Chen, Electrostatic spray deposition of spinel Li4Ti5O12 thin films for rechargeable lithium batteries, Solid State Commun. 135 (2005) 485-489.

DOI: 10.1016/j.ssc.2005.05.045

[16] C.L. Wang, Y.C. Liao, F.C. Hsu, N.H. Tai, M.K. Wu, Preparation and characterization of thin film Li4Ti5O12 electrodes by magnetron sputtering, J. Electrochem. Soc. 152 (2005) A653-A657.

DOI: 10.1149/1.1861193

[17] J. Xie, N. Imanishi, A. Hirano, M. Matsumura, Y. Takeda, O. Yamamoto, Kinetics investigation of a preferential (104) plane oriented LiCoO2 thin film prepared by RF magnetron sputtering, Solid State Ionics. 178 (2007) 1218-1224.

DOI: 10.1016/j.ssi.2007.06.007

[18] M.D. Levi, G. Salitra, B. Markovsky, H. Teller, D. Aurbach, U. Heider, et al., Solid-state electrochemical kinetics of Li-ion intercalation into Li1-xCoO2: Simultaneous application of electroanalytical techniques SSCV, PITT, and EIS, J. Electrochem. Soc. 146 (1999).

DOI: 10.1002/chin.199928014

[19] J. Li, E. Murphy, J. Winnick, P.A. Kohl, The effects of pulse charging on cycling characteristics of commercial lithium-ion batteries, J. Power Sources. 102 (2001) 302-309.

DOI: 10.1016/s0378-7753(01)00820-5

[20] J.P. Christophersen, G.L. Hunt, C.D. Ho, D. Howell, Pulse resistance effects due to charging or discharging of high-power lithium-ion cells: A path dependence study, J. Power Sources. 173 (2007) 998-1005.

DOI: 10.1016/j.jpowsour.2007.08.025

[21] W. Lu, I. Belharouak, J. Liu, K. Amine, Electrochemical and Thermal Investigation of Li4/3Ti5/3O4 spinel, J. Electrochem Soc. 154A (2007) 114-118.

DOI: 10.1016/j.jpowsour.2007.06.199

[22] X.L. Yao, S. Xie, H.Q. Nian, C.H. Chen, Spinel Li4Ti5O12 as a reversible anode material down to 0 V, J. Alloys Compd. 465 (2008) 375-379.

DOI: 10.1016/j.jallcom.2007.10.113

[23] N. Takami, H. Inagaki, T. Kishi, Y. Harada, Y. Fujita, K. Hoshina, Electrochemical kinetics and safety of 2-volt class Li-ion battery system using lithium titanium oxide anode, J. Electrochem. Soc. 156A (2009) 128-132.

DOI: 10.1149/1.3043441