Dynamic Adsorption of Cr (VI) Ions from Aqueous Solution by Canna Edulis Ker Residue in a Fixed-Bed Column

Article Preview

Abstract:

A continuous dynamic adsorption in a fixed-bed column was studied by canna edulis ker residue (CEKR) as an adsorbent for the removal of Cr (VI) ions from aqueous solution. The dynamic adsorption process was simulated by some mathematic models, to determine the characteristic parameters of the column. The results indicated that CEKR could effectively absorb Cr (VI) ions from aqueous solution. Breakthrough time reaching saturation increased significantly with the increase of the temperature, while the bed depth increased and the pH value decreased. In comparison, the initial metal concentration is able to slightly affect the adsorption. Some mathematical models could calculate the rate constants, correlation coefficients, the equilibrium adsorption and kinetic parameters, however, they were not suitable for the description the dynamic adsorption of Cr (VI) ions in the fixed-bed column.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 743-744)

Pages:

498-503

Citation:

Online since:

January 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] G. Crini, Non-conventional low-cost adsorbents for dye removal: a review, Bioresour. Technol. 97 (2006) 1061-1085.

DOI: 10.1016/j.biortech.2005.05.001

Google Scholar

[2] A. Mittal, A. Malviya, D. Kaur, et al., Studies on the adsorption kinetics and isotherms for the removal and recovery of Methyl Orange from wastewaters using waste materials, J. Hazard. Mater. 148 (2007) 229-240.

DOI: 10.1016/j.jhazmat.2007.02.028

Google Scholar

[3] S. Chen, J. Zhang, C. Zhang, et al., Equilibrium and kinetic studies of methyl orange and methyl violet adsorption on activated carbon derived from Phragmites austries, Desalination. 252 (2010) 149-156.

DOI: 10.1016/j.desal.2009.10.010

Google Scholar

[4] M. Rafatullah, O. Sulaiman, R. Hashim, et al., Adsorption of methylene blue on low-cost adsorbents: a review, J. Hazard. Mater. 177 (2010) 70-80.

DOI: 10.1016/j.jhazmat.2009.12.047

Google Scholar

[5] G.M. Walker, L.R. Weatherley, Adsorption of acid dyes onto granular activated carbon in fixed beds, Water Res. 31 (1997) 2093-2101.

DOI: 10.1016/s0043-1354(97)00039-0

Google Scholar

[6] F.A. Pavan, E.C. Lima, S.L.P. Dias, et al., Methylene blue biosorption from aqueous solutions by yellow passion fruit waste, J. Hazard. Mater. 150 (2008) 703-712.

DOI: 10.1016/j.jhazmat.2007.05.023

Google Scholar

[7] F.A. Pavan, A.C. Mazzocato, Y. Gushikem, Removal of methylene blue dye from aqueous solutions by adsorption using yellow passion fruit peel as adsorbent, Bioresour. Technol. 99 (2008) 3162-3165.

DOI: 10.1016/j.biortech.2007.05.067

Google Scholar

[8] R. Han, W. Zou, W. Yu, et al., Biosorption of methylene blue from aqueous solution by fallen phoenix tree's leaves, J. Hazard. Mater. 141 (2007) 156-162.

DOI: 10.1016/j.jhazmat.2006.06.107

Google Scholar

[9] Y. Bulut, H. Aydın, A kinetics and thermodynamics study of methylene blue adsorption on wheat shells, Desalination. 194 (2006) 259-267.

DOI: 10.1016/j.desal.2005.10.032

Google Scholar

[10] R. Gong, Y. Jin, J. Chen, et al., Removal of basic dyes from aqueous solution by sorption on phosphoric acid modified rice straw, Dyes Pigments. 73 (2007) 332-337.

DOI: 10.1016/j.dyepig.2006.01.037

Google Scholar

[11] Y.S. Ho, W.T. Chiu, C.C. Wang, Regression analysis for the sorption isotherms of basic dyes on sugarcane dust, Bioresour. Technol. 96 (2005) 1285-1291.

DOI: 10.1016/j.biortech.2004.10.021

Google Scholar

[12] F.D. Ardejani, Kh. Badii, N.Y. Limaee, et al., Adsorption of direct Red 80 dye fromaqueous solution onto almond shells: effect of pH, initial concentration and shell type, J. Hazard. Mater. 151 (2008) 730-737.

DOI: 10.1016/j.jhazmat.2007.06.048

Google Scholar

[13] R. Gong, X. Zhang, H. Liu, et al., Uptake of cationic dyes from aqueous solution by biosorption onto granular kohlrabi peel, Bioresour. Technol. 98 (2007) 1319-1323.

DOI: 10.1016/j.biortech.2006.04.034

Google Scholar

[14] R. Han, Y. Wang, W. Yu, et al., Biosorption of methylene blue from aqueous solution by rice husk in a fixed-bed column, J. Hazard. Mater. 141 (2007) 713-718.

DOI: 10.1016/j.jhazmat.2006.07.031

Google Scholar

[15] R. Han, Y. Wang, X. Zhao, et al., Adsorption of methylene blue by phoenix tree leaf powder in a fixed-bed column: experiments and prediction of breakthrough curves, Desalination. 245 (2009) 284-297.

DOI: 10.1016/j.desal.2008.07.013

Google Scholar

[16] Z. Aksu, F. Gonen, Biosorption of phenol by immobilized activated sludge in a continuous packed bed: prediction of breakthrough curves, Process Biochem. 39 (2004) 599-613.

DOI: 10.1016/s0032-9592(03)00132-8

Google Scholar

[17] V.C. Srivastava, I.D. Mall, I.M. Mishra, Adsorption thermodynamics and isosteric heat of adsorption of toxic metal ions onto bagasse fly ash (BFA) and rice husk ash (RHA), Chem. Eng. J. 132 (2007) 267-278.

DOI: 10.1016/j.cej.2007.01.007

Google Scholar

[18] Z. Zulfadhly, M.D. Mashitah, S. Bhatia, Heavy metals removal in fixed-bed column by the macro fungus Pycnoporus sanguineus, Environ. Pollut. 112 (2001) 463-470.

DOI: 10.1016/s0269-7491(00)00136-6

Google Scholar

[19] J. Goel, K. Kadirvelu, C. Rajagopal, et al., Removal of lead (II) by adsorption using treated granular activated carbon: Batch and column studies, J. Hazard. Mater. 125 (2005) 211-220.

DOI: 10.1016/j.jhazmat.2005.05.032

Google Scholar

[20] K. Mohanty, M. Jha, B.C. Meikap, Biosorption of Cr(VI) from aqueous solutions by Eichhornia crassipes, Chem. Eng. J. 117 (2006) 71-77.

DOI: 10.1016/j.cej.2005.11.018

Google Scholar

[21] Y. Bulut, Z. Tez, Removal of heavy metal ions by modified sawdust of walnut, Fresen. Environ. Bull. 12 (2003) 1499-1504.

Google Scholar