Effect of Heat Treatment on Microstructure and Properties of Cu-3Ti-1Al Alloy

Article Preview

Abstract:

The effect of heat treatment on the microstructure and properties of Cu-3Ti-1Al alloy was investigated. The microstructure was characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM), and the hardness and electrical conductivity were tested as well. The results showed that the hardness and electrical conductivity of Cu-3Ti-1Al alloy increased significantly after solid solution and ageing treatment. The strengthening effect of Cu-3Ti-1Al alloy was attributed to the formation of intermetallic phase such as Ti3Al and fine precipitates of coherent β-Cu4Ti. With increase of the aging time and the temperature, the precipitates became coarse and incoherent with Cu matrix, and the discontinuous precipitate β started to grow from grain boundaries toward grain interior, which decreased hardness. As the formation of Ti3Al, β-Cu3Ti and β-Cu4Ti phase can efficiently reduce Ti concentration in Cu matrix. The electrical conductivity of Cu-3Ti-1Al alloy increases. In the range of experiments, the optimal heat treatment process for Cu-3Ti-1Al alloy is solid solution at 850°C for 4h and ageing 500°C for 2h, and the hardness and electrical conductivity are 227HV and 12.3%IACS, respectively.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

282-286

Citation:

Online since:

March 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] W.A. Soffa, D.E. Laughlin, High-strength age hardening copper-titanium alloys, Prog. Mater Sci. 49(3-4) (2004) 347-366.

DOI: 10.1016/s0079-6425(03)00029-x

Google Scholar

[2] S. Nagarjuna, M. Srinvivas, K. Balasubraman, D.S. Sarma, On the variation of mechanical properties with solute content in Cu-Ti alloys, Mater. Sci. Eng. A 259(1) (1999) 34-42.

DOI: 10.1016/s0921-5093(98)00882-x

Google Scholar

[3] A. Datta, W.A. Soffa, Structure and properties of age hardened Cu-Ti alloys, Acta Metall. 24(11) (1976) 987-1001.

DOI: 10.1016/0001-6160(76)90129-2

Google Scholar

[4] S. Nagararjuna, K. Balasubramanian, D.S. Sarma, Effect of Ti additions on the electrical resistivity of copper, Mater. Sci. Eng., A 225(1-2) (1997) 118-124.

Google Scholar

[5] S. Suzuki, K. Hirabayashi, H. Shibata, K. Mimura, M. Isshiki, Y. Waseda, Electrical and thermal conductivities in quenched and aged high-purity Cu-Ti alloys, Scripta Mater. 48(4) (2003) 431-435.

DOI: 10.1016/s1359-6462(02)00441-4

Google Scholar

[6] V. Lebreton, D. Pachoutinski, Y. Bienvenu, An investigation of microstructure and mechanical properties in Cu-Ti-Sn alloy, Mater. Sci. Eng. A 508(1-2) (2009) 83-92.

DOI: 10.1016/j.msea.2009.01.050

Google Scholar

[7] S. Nagarjuna, D.S. Sarma, Effect of cobalt additions on the age hardening of Cu-4. 5Ti alloy, J. Mater. Sci. 37(10) (2002) 1929-(1940).

Google Scholar

[8] D. Bozic, O. Dimcic, B.I. Cvijovic, V. Rajkovic, The combination of precipitation and dispersion hardening in powder metallurgy produced Cu-Ti-Si alloy, Mater. Charact. 59(8) (2008) 1122-1126.

DOI: 10.1016/j.matchar.2007.09.005

Google Scholar

[9] I.S. Batra, A. Laik, G.B. Kale, G.K. Dey, U.D. Kulkarni, Microstructure and properties of a Cu-Ti-Co alloy, Mater. Sci. Eng. A 402(1-2) (2005) 118-125.

DOI: 10.1016/j.msea.2005.04.015

Google Scholar

[10] R. Markandeya, S. Nagarjuna, D.S. Sarma, Influence of prior cold work on age hardening of Cu-Ti-Zr alloys, Mater. Sci. Technol. 21(10) (2005) 1171-1180.

DOI: 10.1179/174328405x58922

Google Scholar

[11] V. Lebreton, D. Pachoutinski, Y. Bienvenu, An investigation of microstructure and mechanical properties in Cu-Ti-Sn alloys rich in copper, Mater. Sci. Eng. A 508(1-2) (2009) 83-92.

DOI: 10.1016/j.msea.2009.01.050

Google Scholar

[12] D.J. Wang, W.F. Zhou, D.F. Wang, Study on aging hardening of new-type aeronautic wear-resisting Cu-Ti-Co alloy, Hot Working Tech. 37(10) (2008) 41-43.

Google Scholar

[13] R. Markandeya, S. Nagarjuna, D.S. Sarma, Effect of prior cold work on age hardening of Cu-4Ti-1Cr alloy, Mater. Sci. Eng. A 404(1-2) (2005) 305-313.

DOI: 10.1016/j.msea.2005.05.072

Google Scholar

[14] R. Markandeya, S. Nagarjuna, D.S. Sarma, Precipitation hardening of Cu-Ti-Cr alloys, Mater. Sci. Eng. A 371(1-2) (2004) 291-305.

DOI: 10.1016/j.msea.2003.12.002

Google Scholar

[15] R. Markandeya, S. Nagarjuna, D.V.V. Satyanarayana, Correlation of structure and flow behaviour of Cu–Ti–Cd alloys, Mater. Charact. 428(4-5) (2006) 233-243.

DOI: 10.1016/j.msea.2006.05.034

Google Scholar

[16] S. Nagarjuna, M. Srinivas, Grain refinement during high temperature tensile testing of prior cold worked and peak aged Cu-Ti alloys: Evidence of superplasticity, Mater. Sci. Eng. A 498(1-2) (2008) 468-474.

DOI: 10.1016/j.msea.2008.08.029

Google Scholar

[17] J.Q. Deng, Study on severe plastic deformation processed Cu-Cr-Zr in-situ composites, PhD thesis, East China University of Science and Technology, (2010).

Google Scholar