Effect of Withdrawal Rate on Defects of Upgraded Metallurgical Grade (UMG)-Silicon Prepared by Vacuum Directional Solidification

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The structural defects including dislocations and grain boundaries (GBs) in upgraded metallurgical grade silicon (UMG-Si) prepared by vacuum directional solidification were investigated. The results demonstrated that higher withdrawal rates increased the dislocation density. The state of melt growth changed from quasi-equilibrium to non-equilibrium, and the GB type was also highly related to the withdrawal rate, especially for ∑3 boundary. The change of total interfacial energy and increase of carbon concentration may be a possible driving mechanism for this phenomenon.

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316-319

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March 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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