The Effects of Phosphotungstic Heteropoly Acid on Degradation Behaviour of Hardened Epoxide Polymers in Near-Critical Water

Article Preview

Abstract:

This paper aims to study the catalytic effects of phosphotungstic acid on the degradation behaviour of E-51/DDM and E-51/MeTHPA epoxy resins. The results show that phosphotungstic acid promotes the decomposition of E-51/DDM and E-51/MeTHPA in different degree. The decomposition rate of E-51/MeTHPA is relatively higher. According to the GC-MS results, the composition of products when phosphotungstic acid is used as the catalyst is complicated, indicating that the decomposition mechanism is complicated.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

515-519

Citation:

Online since:

July 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] T. Damstra: Clin. Toxicol. Vol. 40 (2002), p.457

Google Scholar

[2] A. Yasuhara, O. Nakasugi: J. Environ. Chem. Vol. 2 (1992), p.25

Google Scholar

[3] R. C. Thompson, Y. Olsen and R. P. Mitchell: Scinence Vol. 304 (2004), p.838

Google Scholar

[4] C.E. Kouparitsas, C.N. Kartalis, P.C. Vareilidis, C.J. Tsenoglou and C.D. Papaspyrides: Polym. Compos. Vol. 23 (2002), p.682

DOI: 10.1002/pc.10468

Google Scholar

[5] S.J. Pickering: Composites Part A Vol.37 (2006), p.1206

Google Scholar

[6] T. Iwaya, S. Tokuno, M. Sasaki, M. Goto and K. Shibata: J. Mater. Sci. Vol. 43 (2008), p.2452

Google Scholar

[7] N. Grassie: Polym. Degrad. Stab. Vol.14 (1989), p.99

Google Scholar

[8] T. Yoshioka, T. Sato and A. Okuwaki: J. Appl. Sci. Vol. 52 (1994), p.1353

Google Scholar

[9] M. Goto: Supercrit. Fluids Vol. 47 (2009), p.500

Google Scholar

[10] C. Fromonteil, P. Bardelle and F. Cansell: Ind. Eng. Chem. Res. Vol. 39 (2000), p.922

Google Scholar