The Effect of Superheating and Cooling Rate on Primary Precipitation of Si in Hypereutectic Al-Si Alloys

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The effect of superheating and cooling rate on primary precipitation of Si was studied in hypereutectic Al-Si alloys. Alloys with compositions of 15, 18 and 20 wt% Si were solidified in unidirectional solidification equipment from different temperatures and drawing speeds. The fraction of primary silicon was measured over a certain distance of the sample in the steady state region. Results show a large variation in primary silicon fraction along the sample length and with varying cooling rate. The fraction of primary silicon and primary aluminium around silicon increases with increasing superheat. These fractions decrease with increasing cooling rate and the structure changes to a more refined dendritic-like primary silicon. Different morphologies of Si and their transformation during solidification can be seen over the sample length. An analysis of the quenched solidification front shows the possibility of strong convection ahead of the solidification front. The convection can be caused by density variation in the liquid due to the cluster structure of the melt which changes the microstructure.

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135-139

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July 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] M.G. Day, A. Hellawell, The microstructure and crystallography of aluminium-silicon eutectic alloys, Proc. Royal Soc. Lond. A. 305 (1968) 473.

DOI: 10.1098/rspa.1968.0128

Google Scholar

[2] Weimin Wang, Xiufang Bian, Jingyu Qin, S.I Syliusarenko, The atomic structure changes in Al-16 Pct Si alloy above the liquidus, Metall. Mater. Trans. A., 31A (2000) 2163.

DOI: 10.1007/s11661-000-0134-y

Google Scholar

[3] F. Yilmaz, R. Elliott, The microstructure and mechanical properties of unidirectionally solidified Al-Si alloys, J. Mater. Sci. 24 (1989) 2065-2070.

DOI: 10.1007/bf02385422

Google Scholar

[4] F. Yilmaz, Structure and properties of directionally solidified Al-Si hypereutectic alloys, Mater. Sci. Eng. A. 124 (1990) L1-L5.

DOI: 10.1016/0921-5093(90)90158-y

Google Scholar

[5] B. Korojy, H. Fredriksson, Trans. Ind. Inst. Metals, 62 (2009) 361-365.

Google Scholar

[6] H.A.H Steen, A. Hellawell, Structure and properties of aluminium-silicon eutectic alloys, Acta Metall. 20 (1972) 363-370.

DOI: 10.1016/0001-6160(72)90030-2

Google Scholar

[7] J. Fjellstedt, On the crystallization of Al-base alloys, PhD thesis, Royal Institute of Technology (KTH), Sweden (2001).

Google Scholar

[8] A. Formenti, A. Eliasson, H. Fredriksson, On the dendritic growth and microsegregation in Ni-base superalloys In718, In625 and In939, High Temp. Mater. Process. 24 (2005) 221–238.

DOI: 10.1515/htmp.2005.24.4.221

Google Scholar

[9] H. Fredriksson, Metall. Tans. 3 (1972) 2989-2997.

Google Scholar

[10] A.G. Prigunova, An effect of silicon, zinc and magnesium on density and structure of molten silumines, Met. Phys. Adv. Tech. 17 (1999) 1103-1107.

Google Scholar