Effect of Zn Content on the Microstructure and Corrosion Behaviour of Mg-7Y-0.6Zr Alloy

Article Preview

Abstract:

Mg-7Y-0.6Zr-xZn (x = 0, 0.5, 1.0, 1.5, 2.0, 2.5, wt.%) alloys were prepared by the metal mould casting method. Effect of Zn content on the microstructures and corrosion behaviour were investigated. Results showed that microstructures were refined and volume fraction of secondary phase Mg24(YZn)5 was increased with increasing addition of Zn element. Results of electrochemical tests demonstrated that the corrosion potential of Mg-7Y-0.6Zr alloy was about -1.77 V, and, with addition of 0.5~2.0 wt.% Zn element, corrosion potential moved to more positive values than that of Mg-7Y-0.6Zr alloy. Mg-7Y-0.6Zr-0.5Zn alloy possessed the most positive corrosion potential of -1.53 V. The results of immersion test with different time also indicated that corrosion rate could be decreased by addition of 0.5~2.0 wt.% Zn, and Mg-7Y-0.6Zr-0.5Zn alloy exhibited the lowest corrosion rate.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

612-617

Citation:

Online since:

July 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] O. Lunder, T.Kr. Aune, K. Nisancioglu, Effect of manganese additions on the corrosion behaviour of mould-cast magnesium ASTM AZ91, Corrosion 43 (1987) 291-295.

DOI: 10.5006/1.3583151

Google Scholar

[2] J.H. Nordlien, S. Ono, N. Masuko, K. Nisancioglu, A TEM investigation of naturally formed oxide films on pure magnesium, Corros. Sci. 39 (1997) 1397-1414.

DOI: 10.1016/s0010-938x(97)00037-1

Google Scholar

[3] J.E. Gray, B. Luan, Protective coatings on magnesium and its alloys-a critical review, J. Alloys Compd. 336 (2002) 88-113.

DOI: 10.1016/s0925-8388(01)01899-0

Google Scholar

[4] R. Ambat, N.N. Aung, W. Zhou, Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy, Corros. Sci. 42 (2000) 1433-55.

DOI: 10.1016/s0010-938x(99)00143-2

Google Scholar

[5] G.L. Makar, J. Kruger, Corrosion of magnesium, Int. Mater. Rev. 38 (1993) 138-153.

Google Scholar

[6] G. Song, A. Atrens, Corrosion mechanisms of magnesium alloys, Adv. Eng. Mater. 1 (1999) 11-33.

Google Scholar

[7] F. Rosalbino, E. Angelini, S.D. Negri, A. Saccone, S. Delfino, Effect of erbium addition on the corrosion behaviour of Mg-Al alloys, Intermetallics 13 (2005) 55-60.

DOI: 10.1016/j.intermet.2004.05.007

Google Scholar

[8] Y. Gao, Q.D. Wang, J.H. Gu, Y. Zhao, Y. Tong, D.D. Yin, Comparison of microstructure in Mg–10Y–5Gd–0.5Zr and Mg–10Y–5Gd–2Zn–0.5Zr alloys by conventional casting, J. Alloys Compd. 477 (2009) 374-378.

DOI: 10.1016/j.jallcom.2008.10.003

Google Scholar

[9] M. Qian, D.H. StJohn, M.T. Frost, Characteristic zirconium-rich coring structures in Mg–Zr alloys, Scripta Mater. 46 (2002) 649-654.

DOI: 10.1016/s1359-6462(02)00046-5

Google Scholar

[10] P.J. Li, B. Tang, E.G. Kandalova, Microstructure and properties of AZ91D alloy with Ca additions, Mater. Letts. 59 (2005) 671-675.

DOI: 10.1016/j.matlet.2004.11.006

Google Scholar

[11] S.S Li, B. Tang, D.B. Zeng, Effects and mechanism of Ca on refinement of AZ91D alloy, J. Alloys Compd. 437(2007) 317-321.

DOI: 10.1016/j.jallcom.2006.07.117

Google Scholar

[12] H.M Liu, Y.G. Chen, Y.B. Tang, D.M. Huang, G. Niu, The microstructure and mechanical properties of permanent-mould cast Mg–5wt%Sn–(0–2.6)wt%Di alloys, Mat. Sci. Eng. A 437 (2006) 348-355.

DOI: 10.1016/j.msea.2006.07.149

Google Scholar

[13] Y. Liu, W.P. Chen, W.W. Zhang, D.T. Zhang, Y.Y Li, Effects of RE on Microstructures and Mechanical Properties of Hot-Extruded AZ31 Magnesium Alloy, J. Rare Earths 4 (2004) 527-532.

Google Scholar

[14] X.Y. Fang, D.Q. Yi, B. Wang, W.H. Luo, W. Gu, Effect of yttrium on microstructures and mechanical properties of hot rolled AZ61 wrought magnesium alloy, Trans. Nonferrous Met. Soc. China 16 (2006) 1053-1058.

DOI: 10.1016/s1003-6326(06)60376-2

Google Scholar

[15] H.H. Zou, X.Q. Xiao, C.Q. Zhai, W.J. Ding, The effects of yttrium element on microstructure and mechanical properties of Mg–5wt.% Zn–2wt.% Al alloy, Mat. Sci. Eng. A 402 (2005) 142-148.

DOI: 10.1016/j.msea.2005.04.011

Google Scholar

[16] Y.C. Lee, A.K. Dahle, D.H. Stjohn, The role of solute in grain refinement of magnsium, Metall. Mater. Trans. A 31 (2000) 2895-2906.

DOI: 10.1007/bf02830349

Google Scholar

[17] Z.L. Zhang, Z.J. Liu, F.Z Li, Study on burning point and the corrosion resistance & the mechanical property of magnesium alloy, Light Alloy Fabrication 31 (2003) 31-33.

Google Scholar

[18] Y. Fan, G.H. Wu, H.T. Gao, C.Q. Zhai, Current state and development of research on the corrosion of magnesium alloy, Foundry Technol. 25 (2004) 941-942.

Google Scholar

[19] G.Q. Li, G.H. Wu, Y. Fan, W.J. Ding, Effect of the main alloying elements on microstructure and corrosion resistance of magnesium alloys, Foundry Technol. 27 (2006) 79-83.

Google Scholar