Paper Titles

Macroscopic Fracture Behaviour of CrN Hard Coatings Evaluated by X-Ray Diffraction Coupled with Four-Point Bending
p.272

Characterisation of the Residual Stresses in HVOF WC-Co Coatings and Substrates
p.280

Study of Stresses in Texture Components Using Neutron Diffraction
p.289

Macroscopic and Microscopic Determinations of Residual Stresses in Thin Oxide Dispersion Strengthened Steel Tubes
p.296

Cementite Dissolution in Cold Drawn Pearlitic Steel Wires: Role of Dislocations
p.304

In Situ Structural Evolution of Steel-Based MMC by High Energy X-Ray Diffraction and Comparison with Micromechanical Approach
p.313

Inter-Granular Phase Formation during Reactive Diffusion of Gallium with Al Alloy
p.321

Evolution of Residual Micro Phase and Orientation Dependent Stresses during Cold Wire Drawing
p.327

Thermal Stress Estimation of Tungsten Fiber Reinforced Titanium Composite by In Situ X-Ray Diffraction Method
p.335

HomeMaterials Science ForumMaterials Science Forum Vols. 768-769Cementite Dissolution in Cold Drawn Pearlitic...

Cementite Dissolution in Cold Drawn Pearlitic Steel Wires: Role of Dislocations

Article Preview

Abstract:

Despite numerous investigations in the past, mechanism of cementite dissolution has still remained a matter of debate. The present work investigates cementite dissolution during cold wire drawing of pearlitic steel (~ 0.8wt% carbon) at medium drawing strain (up to true strain 1.4) and the role of dislocations in the ferrite matrix on the dissolution process. Quantitative phase analysis using x-ray diffraction (XRD) confirms more than 50% dissolution of cementite phase at drawing strain ~ 1.4. Detail analysis of the broadening of ferrite diffraction lines confirms presence of strain anisotropy in ferrite due to high density of dislocations (~ 1015m-2) at drawing strain 1.4. The results of the analysis shows that the screw dislocations near the ferrite-cementite interface are predominantly responsible for pulling the carbon atoms out of the cementite phase leading to its dissolution.

You might also be interested in these eBooks

International Conference on Residual Stresses 9 (ICRS 9)

Info:

Periodical:

Materials Science Forum (Volumes 768-769)

Pages:

304-312

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.768-769.304

Citation:

Cite this paper

Online since:

September 2013

Authors:

Jay Chakraborty, Tias Maity, Mainak Ghosh, Goutam Das, Sanjay Chandra

Keywords:

Cementite, Dislocation, Ferrite, Pearlitic Steel, X-Ray Diffraction (XRD)

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M.V. Belous, V.T. Cherepin, Phys. Met. Metall. 12 (1961) 685.

[2] V.N. Gridnev, V.G. Gavrilyuk, I.Y. Dekhtyar, Y.Y. Meshkov, P.S. Nizin, V.G. Prokopenko, Phys. Stat. Sol. (a) 14 (1972) 689.

DOI: 10.1002/pssa.2210140238

[3] V.N. Gridnev, V.V. Nemoshkalenko, Y.Y. Meshkov, V.G. Gavrilyuk, V.G. Prokopenko, O.N. Razumov, Phys. Stat. Sol. (a) 31 (1975) 201.

DOI: 10.1002/pssa.2210310122

[4] V.G. Gavrilyuk, V.G. Prokopenko, O.N. Razumov, Phys. Stat. Sol. (a) 53 (1979) 147.

[5] V.N. Gridnev, V.G. Gavrilyuk, Phys. Met. 4 (1982) 531.

[6] J. Languillaume, G. Kapelski, B. Baudelet, Acta Materialia 45 (1997) 1201.

DOI: 10.1016/s1359-6454(96)00216-9

[7] H.G. Read, W.T. Reynolds Jr., K. Hono, T. Tarui, Scripta Mater. 37 (1997) 1221.

[8] F. Danoix, D. Julien, X. Sauvage, J. Copreaux, Mater. Sci. Eng. A 250 (1998) 8.

[9] M.H. Hong, W.T. Reynolds Jr., T. Tarui, K. Hono. Met. Trans. A 30A (1999) 717.

[10] W.J. Nam, C.M. Bae, S.J. Oh, S. -J. Kwon, Scripta Mater. 42 (2000) 457.

[11] X. Sauvage, J. Copreauxf, F. Danoix, D. Blavette, Phil. Mag. A 80 (2000) 781.

[12] K. Hono, M. Ohnuma, M. Murayama, S. Nishida, A. Yoshie, T. Takahashi, Scripta Mater. 44 (2001) 977.

DOI: 10.1016/s1359-6462(00)00690-4

[13] V.G. Gavrilyuk, Scripta Mater. 45 (2001) 1469.

[14] V.G. Gavrilyuk, Scripta Mater. 46 (2002) 175.

[15] V.G. Gavrilyuk , Mater. Sci. Eng. A 345 (2003) 81.

[16] N. Maruyama, T. Tarui, H. Tashiro, Scripta Mater. 46 (2002) 599.

[17] Y.J. Li, P. Choi, C. Borchers, S. Westerkamp, S. Goto, D. Raabe, R. Kirchheim, Acta Mater. 59 (2011) 3965.

DOI: 10.1016/j.actamat.2011.03.022

[18] J.D. Embury, R.M. Fisher, Acta Metall. 14 (1966)147.

[19] Y.S. Yang, J.G. Bae, C.G. Park, Mater. Sci. Eng. A 508 (2009) 148.

[20] Y.J. Li, P. Choi, S. Goto, C. Borchers, D. Raabe, R. Kirchheim, Acta Mater. 60 (2012) 4005.

[21] J.R. Carvajal, Full PROF 2000, Rietveld refinement and pattern matching analysis program, Laboratoire Leon Brillouin (CEA-CNRS), France.

[22] G.K. Williamson, W.H. Hall, Acta Metall. 1 (1953) 22.

[23] T. Ungar, A. Borbely, Appl. Phys. Lett. 69 (1996) 3173.

[24] M. Wilkens, Phys. Stat. Sol. (a) 2 (1970) 359.

[25] T. Ungár, I. Dragomir, A. Révész, A. Borbély, J. Appl. Cryst. 32 (1999) 992.

[26] G. Ribárik, PhD Thesis, Eötvös Löránd University, Hungary, (2003).

[27] I.G. Wood, L. VocÏadlo, K.S. Knight, D.P. Dobson, W.G. Marshall, G.D. Price, J. Brodholt, J. Appl. Cryst. 37 (2004) 82.

[28] L. Darken, R. Curry, Physical Chemistry of Metals, Chap. 16, McGraw-Hill Publ. Co., 1953 (p.4).

[29] G.A. Beresnev, V.I. Sarrak, N.A. Shilov, Problems of Metal Science and Physics of Metals, Vol. 8, Moscow 1964 (p.157).

[30] A. Revesz, T. Ungar, A. Borbely, J. Lendvai, Nanostr. Mater. 7 (1996) 779.

[31] A. Borbely, J. Dragomir-Cernatescu, G. Ribarik, T. Ungar, J. Appl. Cryst. 36 (2003) 160.

[32] T. Ungar, Adv. Eng. Mater. 5 (2003) 323.

[33] Smithells metals reference book, 7th Ed., E.A. Brandes & G.B. Brook.

[34] M. Maalekian, E. Kozeschnik, Comp. Coupl. Phase Diagr. Thermochem. 32 (2008) 650.

[35] A.H. Cottrell, B.A. Bilby, Proc. Phys. Soc. A62 (1949) 49.

[36] A.W. Cochardt, G. Schoek, H. Wiedersich, Acta Metall. 3 (1955) 533.