Nanostructured Co3O4 Oxide for Low Temperature Ethanol Oxidation

Jairo Alberto Gomez-Cuaspud; Martin Schmal

doi:10.4028/www.scientific.net/MSF.798-799.205

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HomeMaterials Science ForumMaterials Science Forum Vols. 798-799Nanostructured Co3O4 Oxide for Low Temperature...

Nanostructured Co₃O₄ Oxide for Low Temperature Ethanol Oxidation

Abstract:

We investigated the synthesis of nanosized Co₃O₄ oxide by the polymerization-combustion technique, with different concentrations (3, 12 and 25% w/w) in the ethanol oxidation reaction. Characterization was done by X-ray fluorescence analysis, X-ray diffraction, temperature programmed reduction, scanning and transmission electronic microscopy and CO and H₂ chemisorption. Principal results from physicochemical characterization show that the concentration of the metal oxide influence the product distribution and selectivity under isothermal conditions at 420 °C showed the formation of intermediate etoxi-species and preferential dehydrogenation reaction on stream of material. Specific concentrations result in high conversions and H₂ selectivity under present reaction conditions.

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Periodical:

Materials Science Forum (Volumes 798-799)

Pages:

205-210

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.798-799.205

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Online since:

June 2014

Authors:

Jairo Alberto Gomez-Cuaspud*, Martin Schmal

Keywords:

Ethanol, Monoliths, Partial Oxidation

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