Porous Poly(1-naphthylamine) Synthesized by Interfacial Polymerization

Abstract:

Porous poly (1-naphthylamine) were synthesized by interfacial polymerization method. The effects of several reaction conditions including oxidant/monomer molar ratio, polymerization temperature and reaction time on the polymerization yield have been investigated. The highest yield of poly (1-naphthylamine) was up to 73% at oxidant/monomer molar ratio of 3 and polymerization temperature of 25 °C for over 20h. Using FT-IR and XRD to analyze the structure of the obtained polymer, the results show that the main mode of connection for 1-naphthylamine units was linking N to para-C and it formed amorphous polymer with some ordered strutures. The micro-morphology of the polymer observed by SEM was found to have irregular porous structure with pore size less than 5μm, which may be related to the “self-emulsion effect” during polymerization.

• Periodical: Materials Science Forum (Volumes 809-810)
• Pages: 319-322
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.809-810.319
• Online since: December 2014
• Authors: Zhen Zhong Hou, Qing Hao Yang*
• Keywords: Interfacial Polymerization, Poly(1-naphthylamine), Porous Material

References

[1] Y.J. Xu, Q.J. Xie and M.Q. Hu: Journal of Electroanalytical Chemistry, Vol. 389 (1995), p.85.

[2] S.M. Ashraf, S. Ahmad and U. Riaz: Polymer International, Vol. 56 (2007), p.1173.

[3] G.D. Liu, S.S. Huang and B.F. Li: Journal of Hunan University(Natural Sciences Edition), Vol 26 (1999), p.38. (In Chinese).

[4] S.S. Huang, F. Chen, B.F. Li, H.J. Liu and R.Q. Yu: Journal of Instrumental Analysis, Vol 15 (1996), p.31. (In Chinese).

[5] C.Y. Chung, T.C. Wen and A. Gopalan: Spectrochimica Acta, Part A, Vol 60 (2004), p.585.

[6] X.Y. Zhang, C.Y.K. Roch, A. Jose and S.K. Manohar: Synthetic Metals, Vol 145 (2004), p.23.

[7] S.X. Xing, H.W. Zheng and G.K. Zhao: Synthetic Metals, Vol 158 (2008), p.59.

[8] S. An, T. Abdiryim, Y. Ding and I. Nurulla: Materials Letters, Vol 62 (2008), p.935.

[9] Y.Q. Luo, W.C. Liu, K. Tan, Y.L. Hou, Y. Li, J. Gong and L.Y. Qu: Journal of Northeast Normal University(Natural Science Edition), Vol 39 (2007), p.55. (In Chinese).

[10] J.M. Du, J.L. Zhang, B.X. Han, Z.M. Liu and M.X. Wan: Synthetic Metals, Vol 155 (2005), p.523.

[11] B.T. Su, Y.C. Tong, J. Bai, N. Dong, S.X. Min and S.X. She: Journal of Northwest Normal University(Natural Science Edition), Vol 42 (2006), p.68. (In Chinese).

[12] X.G. Li, Q.F. Lü and M.R. Huang: Small, Vol 4 (2008), p.1201.

[13] X.G. Li, H. Li and M.R. Huang: Chemistry-A European Journal, Vol 13 (2007), p.8884.

[14] D.K. Moon, K. Osakada, T. Maruyama, K. Kubota and T. Yamamoto: Macromolecules, Vol 26 (1993), p.6992.

[15] C.W. Kuo, T.C. Wen: European Polymer Journal, Vol 44 (2008), p.3393.

[16] S.M. Ashraf, S. Ahmad and U. Riaz: Polymer International, Vol 56 (2007), p.1173.

[17] N.R. Chiou, L.J. Lee and A.J. Epstein: Chemistry of Materials, Vol 19 (2007), p.3589.

[18] W. Yan, Z.X. Lu and S.J. Ding: Chemistry, Vol 1 (2004), p.57. (In Chinese).