Explorative Synthesis of Magnetic Ca-Fe-O Compounds by Mixing Precipitated CaCO3 from Limestone and Iron Sand Extracted – Fe2O3.H2O

Mastuki Mastuki; Malik Anjelh Baqiya; Darminto Darminto

doi:10.4028/www.scientific.net/MSF.827.203

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HomeMaterials Science ForumMaterials Science Forum Vol. 827Explorative Synthesis of Magnetic Ca-Fe-O...

Explorative Synthesis of Magnetic Ca-Fe-O Compounds by Mixing Precipitated CaCO₃ from Limestone and Iron Sand Extracted – Fe₂O₃.H₂O

Abstract:

Synthesis of Ca-Fe-O using solution mixing method employing CaCO₃ and Fe₂O₃•H₂O has been conducted. Extraction of limestone as the raw material of precipitated calcium carbonate (PCC) and iron sands as that of Fe₂O₃•H₂O was prepared to explore various compound of C-Fe-O, where the CaFe₄O₇ phase is mainly expected. The PCC and Fe₂O₃•H₂O each are dissolved in 1 M HNO₃ and mixed to be most homogeneous. The results of the synthesis are characterized by DTA/GTA and then sintered at temperatures of 800°C, 900°C and 1000°C.The sintered samples were characterized by XRD, FTIR, and VSM. The sintering temperature at 800°C, 900°C and 1000°C gave result the phase content of CaFe₄O₇ being respectively 55.42%, 44.55% and 36.39%. Other major phases in the Ca-Fe-O samples consist of Ca₂Fe₉O₁₃ and Ca₄Fe₁₄O₂₅. The remanence value of the corresponding samples is 2.11, 1.28, and 1.74 emu/g respectively.

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Periodical:

Materials Science Forum (Volume 827)

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203-207

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.827.203

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Online since:

August 2015

Authors:

Mastuki Mastuki, Malik Anjelh Baqiya, Darminto Darminto

Keywords:

C-Fe-O, Fe₂O₃•H₂O, PCC, Solution Mixing

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References

[1] Hsing-I Hsiang, Ren-Qian Yao, Hexagonal ferrite powder synthesis using chemical coprecipitation, Materials Chemistry and Physics 104 (2007) 1–4.

DOI: 10.1016/j.matchemphys.2007.02.030

Google Scholar

[2] R. B. Jotania, R. B. Khomane, A. S. Desphande, C. C. Chauhan, and B. D. Kulkarni, Physical and Magnetic Properties of Barium Calcium Hexaferrite Nano- particles Synthesized by Water-in-oil Reverse Micelle and Co-precipitation Techniques, J. Sci. Res. 1 (1) (2009).

DOI: 10.3329/jsr.v1i1.1684

Google Scholar

[3] C. S. Prakash, V. M. Nanoti, D. K. Kulkarni, Magnetic Characterization of Substituted Calcium Hexaferrite, Materials Letters 24 (1995) 171-173.

DOI: 10.1016/0167-577x(95)00080-1

Google Scholar

[4] Emily Asenath-Smith, Indunil N. Lokuhewa, D. Edwards, p-Type thermoelectric properties of the oxygen-deﬁcient perovskite Ca2Fe2O5 in the brownmillerite structure, Journal of Solid State Chemistry 183 (2010) 1670-1677.

DOI: 10.1016/j.jssc.2010.05.016

Google Scholar

[5] Hesham I. Saleh, Synthesis and Formation Mechanism of Calcium Ferrite Compuonds, Journal Material Science and Technology 20 (2004) 530–534.

Google Scholar

[6] Darminto, M. N. Cholishoh, F. A. Perdana, M. A. Baqiya, Mashuri, Y. Cahyono, and Triwikantoro, Preparing Fe3O4 Nanoparticles from Fe2+ Ions Source by Coprecipitation Process in Various pH, AIP Conf. Proc. 1415 (2011) 234–237.

DOI: 10.1063/1.3667264

Google Scholar

[7] R. Ramesh, K. Ashok, G. M. Bhalero, S. Ponnusamy, and C. Muthamizhchelvan, Synthesis and properties of α-Fe2O3 nanorods, Cryst. Res. Technol. 45, (2010) 965 – 968.

DOI: 10.1002/crat.201000140

Google Scholar