Studies on Adsorption-Desorption of CO2 by Long Chain Fatty Amine Supported on SiO2

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The capture of carbon dioxide (CO2) molecules was achieved by utilizing impregnated long chain fatty amine solid sorbents. The long chain fatty amine impregnated on these solid substrates was octadecylamine (ODA) to improve CO2 adsorption-desorption capacity. The amine-loaded samples were characterized using nitrogen, N2 adsorption-desorption isotherm of Brunauer-Emmet-Teller (BET) and thermogravimetry analyzer (TGA). The prepared 25 wt % ODA/SiO2 exhibit acceptable CO2 capture capacities of 2.45 wt % CO2/adsorbent at 25 °C by using CO2 adsorption-desorption isotherm. TG profile shows that the solid sorbents able to adsorb and desorb CO2 in equivalent amount.

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343-347

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January 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Sema, A. Naami, Z. Liang, R. Idem, H. Ibrahim, P. Tontiwachwuthikul, 1D absorption kinetics modeling of CO2–DEAB–H2O system. Int. J. Greenh. Gas Control. 12 (2013) 390–398.

DOI: 10.1016/j.ijggc.2012.11.023

Google Scholar

[2] N. Hiyoshi, K. Yogo, T. Yashima, Adsorption characteristics of carbon dioxide on organically functionalized SBA-15., Microporous Mesoporous Mater. 84 (2005) 357–365.

DOI: 10.1016/j.micromeso.2005.06.010

Google Scholar

[3] A.S. Kovvali, H. Chen, K.K. Sirkar, Dendrimer membranes: a CO2-selective molecular gate., J. Am. Chem. Soc. 122 (2000) 7594–7595.

DOI: 10.1021/ja0013071

Google Scholar

[4] M.L. Gray, K.J. Champagne, D. Fauth, J.P. Baltrus, H. Pennline, Performance of immobilized tertiary amine solid sorbents for the capture of carbon dioxide, Int. J. Greenh. Gas Control. 2 (2008) 3–8.

DOI: 10.1016/s1750-5836(07)00088-6

Google Scholar

[5] J. Oviedo, M.A. San-miguel, J.A. Heredia-guerrero, J.J. Ben, Electrostatic Induced Molecular Tilting in Self-Assembled Monolayers of n -Octadecylamine on Mica, J. Phys. Chem. C. 116 (2012) 7099–7106.

DOI: 10.1021/jp300829g

Google Scholar

[6] M.N. Abu Tahari, M.A. Yarmo, Adsorption of CO2 on Silica Dioxide Catalyst Impregnated with Various Alkylamine, AIP Conf. Proc. 1614 (2014).

DOI: 10.1063/1.4895218

Google Scholar

[7] T. Sakpal, A. Kumar, S. Kamble, R. Kumar, Carbon dioxide capture using amine functionalized silica gel, Indian J. Chem. 51A (2012) 1214–1222.

Google Scholar