The Study of Conditions for the Silicon Carbide Crystals Formation in the Complex Composition Metal Melt

Article Preview

Abstract:

The results of thermodynamic modeling and experimental studies are presented in this article. The aim of this work is to determine the conditions of silicon carbide crystals synthesis in the complex composition metal melts. The "FactSage" software was used for thermodynamic modeling. The phase diagrams, in the form of liquidus surfaces, allow determining the metal composition with minimum melting temperature and presenting the ranges of concentrations and temperatures for which the equilibrium product of the interaction between the components of the metal melt is silicon carbide. The results of experimental research confirmed the possibility of growing silicon carbide crystals in the complex metal melts at low temperatures. The results of the obtained sample of complex alloy examination (conducted with the scanning electron microscope JEOL JSM–6460LV with a energy dispersion spectrometer by "Oxford Instruments" used for performing qualitative and quantitative microprobe analysis) helped to reveal the crystals corresponding to SiC composition.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

167-172

Citation:

Online since:

February 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S. Kawanishi, T. Yoshikawa, T. Tanaka, Equilibrium Phase Relationship between SiC and a Liquid Phase in the Fe–Si–C System at 1523–1723 K, Materials Transactions. 50 (2009) 806-813.

DOI: 10.2320/matertrans.mra2008404

Google Scholar

[2] T. Yoshikawa, S. Kawanishi, T. Tanaka, Fundamental study for solvent growth of silicon carbide utilizing Fe–Si melt, Journal of Physics: Conference Series. 165 (2009) 012022.

DOI: 10.1088/1742-6596/165/1/012022

Google Scholar

[3] E.A. Trofimov, S.V. Rjaboshuk, Thermodynamic Analysis of the Conditions for the Formation of Silicon Carbide in the Molten Metal of Fe–Ni–Si–C, Modern Problems of Steel Electrometallurgy: Proceedings of the XV International Scientific Conference. 1 (2013).

Google Scholar

[4] E.A. Trofimov, A. Yu. Gabova, Thermodynamic analysis of the silicon carbide synthesis in complex metal melts, Bulletin of the South Ural State University, Series Metallurgical engineering,. 15(1) (2015) 1-5.

Google Scholar

[5] R.W. Olesinski, G.J. Abbaschian, C–Si (Carbon–Silicon), Binary Alloy Phase Diagrams: second ed., ASM International, Materials Park. 1 (1990) 882-883.

Google Scholar

[6] R.I. Scace, G.A. Slack, The Si–C and Ge–C phase diagrams, in: Silicon Carbide, High Temperature Semiconductor: Proceedings of the Conference. (1960) 24-28.

Google Scholar

[7] K. Ishida, T. Nishizawa, Co–Si (Cobalt–Silicon), Binary Alloy Phase Diagrams: second ed., ASM International, Materials Park. 2 (1990) 1235-1239.

Google Scholar

[8] R.H. Davies, A.T. Dinsdale, T.G. Chart, T.I. Barry, M.H. Rand, Application of MTDATA to the Modeling of Multicomponent Equilibria, High Temperature Science. 26 (1988) 251-262.

DOI: 10.1007/978-1-4612-0481-7_19

Google Scholar

[9] A.B. Gokhale, G.J. Abbaschian, Mn–Si (Manganese–Silicon), Binary Alloy Phase Diagrams: second ed., ASM International, Materials Park. 3 (1990) 2602-2604.

DOI: 10.1007/bf02898262

Google Scholar

[10] L. Kaufman, Coupled phase diagrams and thermochemical data for transition metal binary systems-III, Calphad: Computer Coupling of Phase Diagrams and Thermochemistry. 2 (1978) 117-146.

DOI: 10.1016/0364-5916(78)90031-7

Google Scholar

[11] N.A. Gokcen, Mn–Ni (Manganese–Nickel), Binary Alloy Phase Diagrams: second ed., ASM International, Materials Park. 3 (1990) 2580-2583.

Google Scholar