Study on the Corrosion Behavior In Vitro and Mechanical Properties of the FHA Coated Mg-Zn-Zr Alloy

Article Preview

Abstract:

The fluorine-doped hydroxyapatite (FHA) coating on the surface of Mg-3wt%Zn-0.8wt%Zr alloy was prepared using a chemical treatment method. The standard tensile samples of coated and uncoated Mg alloy were immersed in the SBF respectively for 1,3,5,10,20 and 30 days. The effect of the FHA coating on corrosion behavior in vitro and mechanical properties of the Mg-Zn-Zr alloy was investigated. Based on the losing weight and the max corrosion depth of the samples, the corrosion rate can be calculated. According to the weightlessness curve of samples, the average corrosion rate of the bare alloy, the alloy of MgF2 coating and the alloy of FHA coating were 4.13mm / y, 1.51mm / y and 0.86mm / y within 30 days in vitro, respectively. It can be seen that the significant difference of mechanical properties between the coated and uncoated samples with the increase of immersing time. This fully revealed that the FHA coating on the Mg-Zn-Zr alloy is beneficial to improve its corrosion resistance.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

647-653

Citation:

Online since:

March 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A. Colombo, E. Karvouni: Circulation. Vol. 102 (2000), p.371.

Google Scholar

[2] J.E. Gray, B. Luan: J. Alloys Compd. Vol. 336 (2002), p.88.

Google Scholar

[3] G.L. Song, Adv. Eng. Mater. 7 (2005) 563–586.

Google Scholar

[4] K.Y. Chiu, M.H. Wong, F.T. Wong, H.C. Wong, Surf. Coat. Technol. 202 (2007) 590–598.

Google Scholar

[5] L.C. Li, J.C. Li, Y. Li, Surf. Coat. Technol. 185 (2007) 92–98.

Google Scholar

[6] Jiao M J, Wang X X. Electrolytic deposition of magnesium-substituted hydroxyapatite crystals on titanium substrate [J]. Mater. Lett. 2009; 63: 2286–2289.

DOI: 10.1016/j.matlet.2009.07.048

Google Scholar

[7] K.J.L. Burg, S. Porter, J.F. Kellam, Biomaterials 21 (2000) 2347–2359.

Google Scholar

[8] R. Narayanan, S.K. Seshadri, T.Y. Kwon, K.H. Kim, Scripta Mater. 56 (2007) 229–232.

Google Scholar

[9] Li J, Song Y, and Zhang S. In vitro responses of human bone marrow stromal cells to a fluoridated hydroxyapatite coated biodegradable Mg-Zn alloy [J]. Biomaterials 2010; 31: 5782–5788.

DOI: 10.1016/j.biomaterials.2010.04.023

Google Scholar

[10] Kahrizsangi R E, Tabrizi B N, Chami A. Characterization of single-crystal fluorapatite nanoparticles synthesized via mechanochemical method Particuology, 2011; 9: 537–544.

DOI: 10.1016/j.partic.2011.07.001

Google Scholar

[11] Huang Y, Yan Y, Pang X. Electrolytic deposition of fluorine-doped hydroxyapatite/ZrO2 films on titanium for biomedical applications. Ceram. Int. 2013; 39: 245–253.

DOI: 10.1016/j.ceramint.2012.06.017

Google Scholar

[12] Yang Song, Shaoxiang Zhang. Electrodeposition of Ca–P coatings on biodegradable Mg alloy: In vitro biomineralization behavior Acta Biomaterialia 6 (2010) 1736–1742.

DOI: 10.1016/j.actbio.2009.12.020

Google Scholar

[13] TAN L L, WANG Q, GENG F, XI X S, QIU J H YANG K, Preparation and characterization of Ca-P coating on AZ31 magnesium alloy [J]. Trans. Nonferrous Met. Soc. China, 2010: 20: s648−s654.

DOI: 10.1016/s1003-6326(10)60555-9

Google Scholar

[14] ZHANG C Y, ZENG R C , CHEN R S, LIU C L, GAO J C, Preparation of calcium phosphate coatings on Mg-1. 0Ca alloy [J]. Trans. Nonferrous Met. Soc. China, 2010; 20: s655−s659.

DOI: 10.1016/s1003-6326(10)60556-0

Google Scholar

[15] Bakhsheshi-Rad H R, Idris M H, Abdul-Kadir M R, et al. Mechanical and bio-corrosion properties of quaternary Mg–Ca–Mn–Zn alloys compared with binary Mg–Ca alloys [J]. Mater Design 2014; 53: 283–292.

DOI: 10.1016/j.matdes.2013.06.055

Google Scholar

[16] XU L P, ZHANG E L, YANG K, Biocorrosion property and cytocompatibility of calcium phosphate coated Mg alloy [J]. Trans. Nonferrous Met. Soc. China, 2012; 22: 2014-(2020).

DOI: 10.1016/s1003-6326(11)61422-2

Google Scholar