Influence of the pH and Stirring Speed of the Electrodeposition Bath in the Performance of Zinc and Zinc-Nanocomposite Coatings

Abstract:

With the increase of environmental restrictions, chromium and cadmium-based coatings have been replaced by zinc layers. These coatings can be obtained through electrodeposition, whose industrially established pH range is from 5.0 to 5.8, and stirring speed is uncontrolled, which has led to part rejections. In addition, the corrosion resistance of zinc coatings is inferior to cadmium and chromium coatings, which has boosted the research of zinc composite coatings. The proposed work presents the performance of zinc-bentonite composite coatings in regards to corrosion relating to pH variation and stirring speed. The samples were degreased for 5 minutes in a commercial degreasing solution at a temperature of 55 °C, with magnetic stirring and, posteriorly, submitted to a pickling process with a duration of 1 to 2 minutes in a commercial bath, followed by a washing process with deionized water. The electrolyte used for electrodeposition was a zinc bath with a chemical composition of 85 g/l ZnCl₂, 210 g/l KCl and 25 g/l H₃BO₃. For the zinc-bentonite electrodepositions 20 g/l of bentonite nanoparticles was added to the bath. Zinc and zinc-bentonite coatings were characterized by scanning electron microscopy, open circuit potential and potentiodynamic polarization. This work shows that a 5.2 pH is the most recommended for the zinc electrodeposition process. Potentiodynamic polarization tests indicated that pure zinc coatings developed in the stirring speed of 380 rpm and zinc-bentonite produced in the stirring speed of 710 rpm showed the best results.

• Periodical: Materials Science Forum (Volume 899)
• Pages: 283-288
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.899.283
• Online since: July 2017
• Authors: Patrícia Marcolin*, Marielen Longhi, Lucas Pandolphi Zini, Bianca Proença, Célia de Fraga Malfatti, Lintha C. Battisti, Ester S. Rieder, Ademir José Zattera, Sandra Raquel Kunst, Cláudia Trindade Oliveira
• Keywords: Corrosion, Electrodeposition, Nanocomposites, pH, Stirring, Zinc

References

[1] K. Gang, L. Jintang, W. Haijiang: J. Rare Earths Vol. 27 (2009), p.164.

[2] C.M.A. Freire, R.G. Tannuri; Estudos do processo de eletrodeposição de zinco com partículas de terras raras. XVII Congresso interno de Iniciação Científica da Unicamp, Faculdade Mecânica – FEM-UNICAMP, São Paulo, setembro, (2009).

DOI: 10.19146/pibic-2017-77819

[3] T.L. Menezes: Elaboração e Caracterização de Revestimentos Compósitos de Zinco com Talco e Bentonita. Mestrado (Dissertação). Porto Alegre, 2008. Universidade Federal do Rio Grande do Sul (UFRGS). (RS).

DOI: 10.32467/issn.2175-3628v23n1a14

[4] F.R.V. Díaz; A.R. Morales; L.B. Paivai: Cerâmica Vol. 54 (2008).

[5] B. Kavitha; P. Santhosh; M. Renukadevi; A. Kalpana; P. Shakkthivel; T. Vasudevan: Surface & Coatings Technology Vol. 201 (2006), p.3438.

DOI: 10.1016/j.surfcoat.2006.07.235

[6] F.W. Eppensteiner M.R. Jenkins: Metal Finishing Vol. 99 (1) (2001), p.494.

[7] C. Mafaltti: Elaboração e caracterização de revestimentos nanocompósitos Ni-P-SiC eletrodepositados Doutorado (Tese). Porto Alegre, 2004. Universidade Federal do Rio Grande do Sul (UFRGS). (RS).

DOI: 10.32467/issn.2175-3628v23n1a14

[8] C.F. Malfatti; H.M. Veit; T.L. Menezes; J.Z. Ferreira; J.S. Rodrigues; J.P. Bonino: Surface & Coatings Technology Vol. 201 (2007), p.6318.

DOI: 10.1016/j.surfcoat.2006.11.040

[9] V. Barranco; S. Feliu Jr.; S. Feliu: Corrosion Science Vol. 46 (2004), p.2203.

[10] Y. Hamlaoui; F. Pedraza; L. Tifouti: Corrosion Science Vol. 50 (2008), p.1558.

[11] D. Sylla; C. Savall; M. Gadouleau; C. Rebere; J. Creus; P.H. Refait: Surface & Coatings Technology Vol. 200 (2005), p.2137.

DOI: 10.1016/j.surfcoat.2004.11.020

[12] C. Savall; C. Rebere; D. Sylla; M. Gadouleau; Ph. Refait; J. Creus: Materials Science and Engineering A Vol. 430 (2006), p.165.

DOI: 10.1016/j.msea.2006.05.025

[13] A. Hovestad; R.J.C.H.L. Heesen; L.J.J. Janssen: J. Applied Electrochemistry Vol. 29 (1999), p.331.