Effect of Blend Ratio on Morphology and Swelling Properties of PVA/Chitosan Nanofibers

Article Preview

Abstract:

PVA/chitosan nanofibers have been prepared by electrospinning method. A novel nanofibers mat was prepared in a various blend ratio of PVA to chitosan. The structure of PVA/chitosan nanofibers was examined by FTIR and SEM. The results showed that PVA/chitosan nanofibers were successfully formed. The result of FTIR indicates that PVA and chitosan exist in PVA/chitosan Nanofibers. SEM observation showed that the fiber has several hundred nanometers with a smooth surface. It also observed that fibers diameters decreased by increase percentage of chitosan, this occurs because of the conductivity of electrospun solution increase and the viscosity decrease. Reduction of fiber diameter followed by a decrease in pore size, this is a very important property of a membrane having a small pore size with high porosity. PVA/chitosan nanofibers have pH sensitive of swelling properties and better-swelling properties in acid conditions.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

79-84

Citation:

Online since:

July 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] N. Bhardwaj and S. C. Kundu, Electrospinning: A fascinating fiber fabrication technique, Biotechnol. Adv. 28 (2010) 325-347.

DOI: 10.1016/j.biotechadv.2010.01.004

Google Scholar

[2] K. Garg and G. L. Bowlin, Electrospinning jets and nanofibrous structures, Biomicrofluidics 5 (2011) 1–19.

DOI: 10.1063/1.3567097

Google Scholar

[3] M. Z. Elsabee, H. F. Naguib, and R. E. Morsi, Chitosan based nanofibers, review, Mater. Sci. Eng. C. 32 (2012) 1711–1726.

DOI: 10.1016/j.msec.2012.05.009

Google Scholar

[4] Y. Jia, J. Gong, X. Gu, H. Kim, and J. Dong, Fabrication and characterization of poly(vinyl alcohol)/chitosan blend nanofibers produced by electrospinning method, Carbohyd. Polym. 67 (2007) 403-409.

DOI: 10.1016/j.carbpol.2006.06.010

Google Scholar

[5] X. Mi, K. S. Vijayaragavan, and C. L. Heldt, Virus adsorption of water-stable quaternized chitosan nanofibers, Carbohydr. Res. 387 (2104) 24–29.

DOI: 10.1016/j.carres.2014.01.017

Google Scholar

[6] R. Liu, X. Xu, X. Zhuang, and B. Cheng, Solution blowing of chitosan/PVA hydrogel nanofiber mats, Carbohyd. Polym. 101 (2014) 1116–1121.

DOI: 10.1016/j.carbpol.2013.10.056

Google Scholar

[7] A. Esmaeili and A. A. Beni, A novel fixed-bed reactor design incorporating an electrospun PVA/chitosan nanofiber membrane, J. Hazard. Mater. 280 (2014) 788–796.

DOI: 10.1016/j.jhazmat.2014.08.048

Google Scholar

[8] A. Razzaz, S. Ghorban, L. Hosayni, M. Irani, and M. Aliabadi, Chitosan nanofibers functionalized by TiO2 nanoparticles for the removal of heavy metal ions, J. Taiwan Inst. Chem. Eng. 58 (2016) 333-3435.

DOI: 10.1016/j.jtice.2015.06.003

Google Scholar

[9] X. Qu, P. J. J. Alvarez, and Q. Li, Applications of nanotechnology in water and wastewater treatment, Water Res. 47 (2013) 3931–3946.

DOI: 10.1016/j.watres.2012.09.058

Google Scholar

[10] R. Rošic, J. Pelipenko, J. Kristl, P. Kocbek, M. Bešter-Rogač, and S. Baumgartner, Physical characteristics of poly (vinyl alcohol) solutions in relation to electrospun nanofiber formation, Eur. Polym. J. 49 (2013) 290–298.

DOI: 10.1016/j.eurpolymj.2012.11.013

Google Scholar

[11] S. N. Alhosseini, F. Moztarzadeh, M. Mozafari, S. Asgari, M. Dodel, A. Samadikuchaksaraei, S. Kargozar, and N. Jalali, Synthesis and characterization of electrospun polyvinyl alcohol nanofibrous scaffolds modified by blending with chitosan for neural tissue engineering, Int. J. Nanomedicine 7 (2012).

DOI: 10.2147/ijn.s25376

Google Scholar

[12] E. A. El-hefian, M. M. Nasef, and A. H. Yahaya, The Preparation and Characterization of Chitosan/Poly(Vinyl Alcohol) Blended Films, J. Chem. 7 (2010) 1212-1219.

DOI: 10.1155/2010/626235

Google Scholar