Structural Refinement by the Rietveld Method on Clinkers Obtained from Waste from Pulp and Paper Mills

Article Preview

Abstract:

Pulp and paper mills have a process that generates waste with high levels of CaO and SiO2, which can be valued as an alternative mineral source in the cement industry. In this work the lime mud, biomass ashes and WWTP sludge are used in the production of clinker. Analysis of X-ray diffraction (XRD) confirmed the crystalline phases calcite and quartz. Chemical analysis by X-ray fluorescence (XRF) identified Al2O3, CaO and SiO2, providing support for the calculation of theoretical stages by applying the Bogue equations. Five formulations and three processing temperatures (1350, 1400, 1455 °C) were studied. The products obtained and an ordinary Portland cement (OPC) were characterized by XRD with quantification by the Rietveld method. The results showed that the processing conditions used produced belíticos (higher content of C2S) and Portland (C3S content greater) ecoclinker.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

175-179

Citation:

Online since:

January 2018

Keywords:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S. Bayr, J. Rintala: Water Research Vol. 46 (15) (2012), p.4713.

Google Scholar

[2] F. Gallardo et al.: Revista de la Ciencia del Suelo y Nutrición Vegetal Vol. 10 (1) (2010), p.48.

Google Scholar

[3] F. M. Martins et al.: Journal of Hazardous Materials Vol. 147 (1-2|) (2007), p.610.

Google Scholar

[4] R. Pérez-López et al.: Journal of Hazardous Materials Vol. 177 (1-3) (2010), p.762.

Google Scholar

[5] J. Zhang, Q. Wang, J. Jiang: International Journal of Hydrogen Energy Vol. 38 (6) (2013), p.2738.

Google Scholar

[6] L.H. Buruberri, M.P. Seabra, J.A. Labrincha: Journal of Hazardous Materials Vol. 286 (2015), p.252.

Google Scholar

[7] F. Castro et al.: International Journal of Materials Engineering Innovation Vol. 1 (1) (2009), p.74.

Google Scholar

[8] F. Raupp Pereira et al.: Cement and Concrete Research Vol. 38 (4) (2008), p.511.

Google Scholar

[9] P.K. Mehta, P. J. M. Monteiro: Concrete: Microstructure, Properties, and Materials. [s. l: s. n. ].

Google Scholar

[10] L.D.A. Gobbo: Aplicação da difração de raios-x e método de rietveld no estudo de cimento portland. [s. l. ] Universidade de São Paulo, (2009).

DOI: 10.11606/t.44.2009.tde-23072009-144653

Google Scholar

[11] L.B. Mccusker et al.: J. Appl. Crystallogr. Vol 32 (1999), p.36.

Google Scholar