Structural, Morphological and Textural Features of EDTA-Citrate-Synthesized BaPrO3 Perovskite-Type Oxide

A.G. dos Santos; M.F. Lobato; A.B. Vital; Francisco Klebson Gomes dos Santos; Carlson P. de Souza

doi:10.4028/www.scientific.net/MSF.912.50

Paper Titles

Synthesis and Characterization of HMOR and Catalyst MoO₃/HMOR, NiO/HMOR and Co₂O₃/HMOR
p.33

Preparation of Molecular Sieve Al-SBA-15 with Two Ratios Si/Al Catalyst for Use in the Transesterification Reaction of Soybean Oil
p.39

Rice Husk Ash as a Raw Material to Produce Willemite Pigments
p.44

Structural, Morphological and Textural Features of EDTA-Citrate-Synthesized BaPrO₃ Perovskite-Type Oxide
p.50

Evaluation of Phyllite and Sand in the Heavy Clay Body Composition
p.55

Study of the Addition Effect of Fe₂O₃ and Al₂O₃ Originated from Pectin Citrus in the Glassy Phase on the Microestructural Development and in the Mechanical Characteristics of the Triaxial Ceramics
p.60

Evaluation of the Accelerated Degradation of Mortar in a Ceramic Coating Facade System
p.65

Characterisation of Refractory Ceramic Pressed Body Containing Industrial Waste
p.71

HomeMaterials Science ForumMaterials Science Forum Vol. 912Structural, Morphological and Textural Features of...

Structural, Morphological and Textural Features of EDTA-Citrate-Synthesized BaPrO₃ Perovskite-Type Oxide

Abstract:

BaCeO₃ has attracted great interest in research worldwide, whether doped with other elements on the site A and / or B of perovskite ABO₃ or not, thus enabling its use in different applications. However, the properties exhibited by perovskite depend on partial or total replacement at the site, as well as the applied synthesis method. In this work we studied crystal structure, crystallographic parameters, morphology and textural properties of BaPrO₃perovskite synthesized by EDTA-Citrate complexation process. The adopted methodology makes it possible to obtain powders with orthorhombic crystal structure ( a=6.07 Å; b=6.3 Å e c=8.7 Å) and crystallite size of approximately 100 nm. That perovskite has dense and irregular agglomerates with surface area and pore volume of about 2.37 m² g^-1 and 0.7x10^-8m³g^-1, respectively. Finally, the methodology has demonstrated effectiveness in achieving crystalline phase with similar characteristics and properties obtained by different methods.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Materials Science Forum (Volume 912)

Pages:

50-54

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.912.50

Citation:

Cite this paper

Online since:

January 2018

Authors:

A.G. dos Santos, M.F. Lobato, A.B. Vital, Francisco Klebson Gomes dos Santos, Carlson P. de Souza

Keywords:

BaPrO₃, Crystallographic Data, Morphology, Perovskite, Surface Area, Synthesis Method

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] L. G Tejuca, J. L. J. M. D. Tascon: Adv. Catal. Vol. 36 (1989), p.237.

Google Scholar

[2] P. J. Saines, B.J. Kennedy, R.I. Smith: Mater. Res. Bull. Vol. 44 (2009), p.874.

Google Scholar

[3] C.Y. Jones: J. Appl. Physics Vol. 97 (2005), pp.114908-01.

Google Scholar

[4] G. Cao, T. Yuen: J. Appl. Physics Vol. 70 (1991), p.6332.

Google Scholar

[5] C.S. Knee, A., Norby T. Magras, R.I. Smith: J. Materials Chem. Vol. 19 (2009), p.3238.

Google Scholar

[6] A.G. Santos, R.R. Silva, A. G. O. Dantas, M. F. Lobato, C. P. Souza: Revista Verde Vol. 9 (2014), p.149.

Google Scholar

[7] M.F. Lobato, C.P. Souza, R.H. Passos, A.G. Santos, I.R.B. Gomes: Cerâmica Vol. 60 (2014), p.532.

Google Scholar

[8] R.A. Young: The Rietveld Method. (International Union of Crystallography (IUCr) Oxford Science Publications 2002).

Google Scholar

[9] H. Patra, S.K. Rout, S.K. Pratihar, S. Bhattacharya: Powder Technol. Vol. 209 (2011), p.98.

Google Scholar

[10] S.J. Stokes, M.S. Islam: J. Materials Chem. (2010), p.6258.

Google Scholar

[11] D.J. Goossens, RA. Robinson, M. T.F. Telling: Physica B Vol. 352 (2004), p.105.

Google Scholar

[12] M.N. Popova, S.A. Klimin, B.Z. Malkin, L.A. Kasatkina, G. Cao, J. Crow: Physica Letter A Vol. 223 (1996), p.308.

Google Scholar

[13] A.J. Jacobsen, B.C. Tofield, B.E.F. Fender: Acta Crystallographica B Vol. 28 (1972), p.956.

Google Scholar

[14] A. Magraso, A. Calleja, X.G. Capdevila, F. Espiell: Solid State Ionics Vol. 166 (2004), p.359.

Google Scholar

[15] K.K. Sosetsu: The Chemical Society of Japan. (Japan Scientific Societies Press Tokyo, second ed. 32 1997).

Google Scholar

[16] W.J. Thomas, B. Crittenden: Adsorption Technology & Design. (Butterworth-Heinemann, 1998).

Google Scholar