Influence of Catalysts with Different Templates on Direct Decomposition of NO in Cement Kiln Exhaust

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The influence of catalysts with different templates on direct decomposition of NO in cement kiln exhaust was studied in this paper. The NO direct decomposition rate of porous catalyst materials with different templates was determined by infrared spectrometer. And pore structure and the microstructure of the catalysts were characterized by BET surface area, nitrogen adsorption-desorption. The results show that the catalytic performance of porous catalyst without any template is better than catalysts with other templates at low temperature. When the temperature reached 550 °C, NO decomposition rate of porous catalyst with CTAB could reach to more than 80%. And meanwhile, the catalysts with organic template reagent have higher BET surface area than those with inorganic template agent. With the increasing of the reaction time, the NO decomposition rate decreases. After reaction for 3 hours, the decomposition rate decreases from 80% to 40%.

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February 2018

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[1] Kunlong GAO. Study on the emission characteristics of atmospheric pollutants exhausted from NSP cement plants[D]. Hefei University of Technology, (2015).

Google Scholar

[2] Ling JIN, Chunlai JIANG, YANG Jintian. Economic Analysis of NOx Control Technologies for Cement Industry during The Twelfth Five-Year Planning[J]. Environment and sustainable development, 5 (2012) 19-23.

Google Scholar

[3] Wang H, Nakata T. Analysis of the market penetration of clean coal technologies and its impacts in China's electricity sector[J]. Energy Policy, 37(1) (2009) 338-351.

DOI: 10.1016/j.enpol.2008.09.045

Google Scholar

[4] Changming GAO. On the NOx emission reduction for domestic cement industry[J]. Senior Consultant of China Cement Association. 18(4) (2012) 5-7.

Google Scholar

[5] GB4915-2013, Emission Standard of Air Pollutants for Cement Industry.

Google Scholar

[6] Haifeng CUI, Junlin XIE, Fengxiang LI, Panpan DONG, Feng HE. Research and Application of SCR Flue Gas Denitrification Technology[J]. Bulletin of the Chinese Ceramic Society, 35(3) (2016) 805-809.

Google Scholar

[7] Glick HS, Klein JJ, Squire W. Single - Pulse Shock Tube Studies of the Kinetics of the Reaction N2+O2 ↔2NO between 2000–3000°K[J]. J Chem Phys, 27 (1957) 850-857.

DOI: 10.1063/1.1743864

Google Scholar

[8] Hailong LI, Ping XIAO, Tao WANG, et al. Recent progress on catalysts used for NO decomposition[J]. Scientia Sinica Chimica, 44(12) (2014) 1951-1965.

DOI: 10.1360/n032014-00049

Google Scholar

[9] Fritz A , Pitchon V . The current state of research on automotive lean NOx catalysis [J]. Appl Catal B: Envir, 13 (1997) 1-25.

DOI: 10.1016/s0926-3373(96)00102-6

Google Scholar

[10] Hamada H, Kintaichi Y, Sasaki M, Ito T. Silver-promoted cobal oxide catalysts for direct decomposition of nitrogen monoxide. Chem Lett. (1990) 1069-1070.

DOI: 10.1246/cl.1990.1069

Google Scholar

[11] Winter E R S. The catalytic decomposition of nitric oxide by metallic oxides[J]. J. Catal, 22 (1971) 158-170.

Google Scholar

[12] Haneda M, Kintaichi Y, Bion N, Hamada H. Alkali metal-doped cobalt oxide catalysts for NO decomposition. Appl Catal B, 46 (2003) 473-482.

DOI: 10.1016/s0926-3373(03)00287-x

Google Scholar

[13] Teraoka Yasutake, Tomohiro Harada, Shuichi Kagawa. Reaction mechanism of direct decomposition of nitric oxide over Co-and Mn-based perovskite-type oxides[J].Journal of the Chemical Society, Faraday Transactions, 94(13) (1998) 1887-1891.

DOI: 10.1039/a800872h

Google Scholar

[14] Bin Zhao, Rijie Wang, Xiaoxia Yang. Simultaneous catalytic removal of NOx and diesel soot particulates over La1–xCexNiO3 perovskite oxide catalysts[J].Catalysis Communications, 10(7) (2009) 1029-1033.

DOI: 10.1016/j.catcom.2008.10.024

Google Scholar

[15] Yokoi Yasuharu, Hiroshi Uchida. Catalytic activity of perovskite-type oxide catalysts for direct decomposition of NO:Correlation between cluster model calculations and temperature-programmed desor ption experiments[J].Catalysis Today, 42(12) (1998).

DOI: 10.1016/s0920-5861(98)00087-x

Google Scholar

[16] Iwamoto M, Yokoo S, Sakai K, Kagawa S. Catalytic decomposition of nitric oxide over copper (II)-exchanged, Y-type zeolites[J]. J Chem Soc, Faraday Trans, 77 (1981) 1629-1638.

DOI: 10.1039/f19817701629

Google Scholar

[17] Parvulescu V I , Grange P , Delmon B . NO decomposition over physical mixtures of Cu-ZSM-5 with zeolites or oxides [J]. Applied Catalysis B, 33(3) (2001) 137-223.

DOI: 10.1016/s0926-3373(01)00182-5

Google Scholar

[18] Yanping CHEN, Dang-guo CHENG, Fengqiu CHEN, etal. NO Decomposition and Selective Catalytic Reduction of NO over Cu-ZSM-5 Zeolite[J].Progress in chemistry. 26(2) (2014) 248-258.

Google Scholar