Thermal Stability and Kinetics of the Thermal Degradation of Thermal Conductive Silicone Rubber Filled with Al2O3 and ZnO

Qiu Hong Mu; Dan Peng; Feng Wang; Jin Hui Li; Shuo Zhang

doi:10.4028/www.scientific.net/MSF.926.45

Paper Titles

Mechanical Interlocking of an Aluminum Alloy and SS400 Structural Steel through Friction-Stir Spot Forming (FSSF)
p.17

A Study on Galvanic Current Variation of Zn Sacrificial Anode Made by Including of Additive in Solutions with Various Conductivities
p.25

Effect of Osmotic Pressure by Salt Concentration on Corrosion Resistance of Anti-Corrosive Paint
p.31

Synthesis and Properties of Phenyl Silicone Resin Reinforced Addition Type Liquid Phenyl Silicone Rubber
p.39

Thermal Stability and Kinetics of the Thermal Degradation of Thermal Conductive Silicone Rubber Filled with Al₂O₃ and ZnO
p.45

Investigation of the Influence of Heat Treatment on the Strength of Sandwich Structures
p.51

Study on Sandwich Core Modeling for Structural Analysis of Sandwich Composite Structure
p.57

Study on Precision Polishing of Alumina Ceramics
p.64

Parylene-Coated Cellulose Nanofiber Films with Improved Oxygen Barrier and Water Resistance
p.73

HomeMaterials Science ForumMaterials Science Forum Vol. 926Thermal Stability and Kinetics of the Thermal...

Thermal Stability and Kinetics of the Thermal Degradation of Thermal Conductive Silicone Rubber Filled with Al₂O₃ and ZnO

Abstract:

The kinetics of the thermal degradation and thermal stability of thermal conductive silicone rubber filled with Al₂O₃ and ZnO were investigated by thermogravimetric analysis in a flowing nitrogen atmosphere at a heating rate of 10°C/min. The rate parameters were evaluated by the method of Freeman–Carroll. The results show that the thermal degradation of silicone rubber begins at about 350°C and ends at about 600°C. The thermal degradation is multistage, in which zero-order reactions are principal. The kinetics of the thermal degradation of thermal conductive silicone rubber has relevance to its loading of thermal conductive filler. The activation energies are temperature-sensitive and their sensitivity to temperature becomes weak as temperature increases.

You might also be interested in these eBooks

International Symposium on Advanced Material Research II

View Preview

Info:

Periodical:

Materials Science Forum (Volume 926)

Pages:

45-50

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.926.45

Citation:

Cite this paper

Online since:

July 2018

Authors:

Qiu Hong Mu*, Dan Peng, Feng Wang, Jin Hui Li, Shuo Zhang

Keywords:

Degradation, Kinetics (Polym.), Silicones, Thermal Conductivity, Thermogravimetric Analysis (TGA)

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] S. C. Shit, P. Shah, A review on silicone rubber, Nat. Acad. Sci. Lett. 36(4) (2013) 355-365.

Google Scholar

[2] Y. Kim, J. Chung, J. Lee, Synergistic effect of spherical Al2O3 particles and BN nanoplates on the thermal transport properties of polymer composites, Comp. Part A: Appl. Sci. Manuf. 98 (2017) 184-191.

DOI: 10.1016/j.compositesa.2017.03.030

Google Scholar

[3] L. C. Sim, S. R. Ramanan, H/ Ismail, K. N. Seetharamu and T. J. Goh, Thermal characterization of Al2O3 and ZnO reinforced silicone rubber as thermal pads for heat dissipation purposes, Thermochimica Acta, 430(1-2) (2005) 155-165.

DOI: 10.1016/j.tca.2004.12.024

Google Scholar

[4] Q. Mu, S. Feng, Thermal conductivity of graphite/silicone rubber prepared by solution intercalation, Thermochimica Acta, 462(1-2) (2007) 70-75.

DOI: 10.1016/j.tca.2007.06.006

Google Scholar

[5] J. Zhang, S. Feng, Q. Ma, Kinetics of the thermal degradation and thermal stability of conductive silicone rubber filled with conductive carbon black, J. Appl. Polym. Sci. 89 (2003) 1548-1554.

DOI: 10.1002/app.12277

Google Scholar

[6] Y. Feng, J. Yuan, W. Zhou. Comparative study of various solving methods for solid thermal decomposition kinetics, Polym. Mater. Eng. 11(2) (1995) 66-70.

Google Scholar

[7] S. Fu, Z. Han, P. Wu, Progress in the Research of the Thermal Stability of Polysiloxanes, Polym. Bull. 2 (2001) 40-47.

Google Scholar