Corrosion Inhibition by a Caesalpinia Sappan L Modified Imidazoline for Carbon Steel API 5L Grade X60 in HCl 1M Environment

Abstract:

Acidizing is one of the stimulation technologies in the oil and gas industry by removing scale, rust, debris or other acid-soluble particulates on the pipe tubing internal surface. The most common acid used is HCl. To avoid problems such as pipe or casing tubing leak due to acidic corrosion, during the acidizing normally applied with inhibition treatment by inorganic corrosion inhibitor with various compositions including quaternary ammonium salts, solvent and often some surfactant to strip oil from acid reactive surfaces. However, most of these compounds are not only expensive but also toxic to the marine environment. It is an obvious remark to point out the importance of low cost, green corrosion inhibitors which is safe to the environment. The wood extract has become important as an environmentally acceptable, readily available and renewable resource for wide range of inhibitors. A Caesalpinia Sappan L modified imidazoline has been synthesized and used as a corrosion inhibitor for carbon steel in API 5L X60 in HCl 1M environment.The aim of the investigation is to find low dosage-high efficiency green corrosion inhibitor.The testing techniques include wheel test weight loss measurement, Tafel polarization and Electrochemical Impedance Spectroscopy (EIS), Fourier Transform Infra-red Spectroscopy (FTIR). The results of weight loss studies correlated well with those of polarization and Impedance Spectroscopy. Inhibition performance for both Caesalpinia Sappan L modified imidazoline ( CS IMI) and Imidazoline (IMI) increases with increasing inhibitor concentration. The formulated Caesalpinia Sappan L modified imidazoline ( CS IMI), and Imidazoline (IMI) inhibitors give a greater than 90% inhibition efficiency with dosage 25 ppm at a temperature of 90-140°F. Caesalpinia Sappan L modified imidazoline (CS IMI), and Imidazoline (IMI) show comparable inhibition performance. However, at temperature 140 ^oF, Imidazoline (IMI) seems to have a slightly better performance, indicating better thermal stability. Caesalpinia sappan bioactive agents are brazilein and chalcone, and its inhibition mechanism by physisorption obey Langmuir Isotherm, this mode will control charge transfer at surface metal and electrolyte.This result confirms that Caesalpinia sappan modified imidazoline is very promising for the development of green corrosion inhibitors for oil and gas application

• Periodical: Materials Science Forum (Volume 929)
• Pages: 158-170
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.929.158
• Online since: August 2018
• Authors: Norman Subekti, Adam Septiyono Arlan*, Johny Wahyuadi Soedarsono, Andi Rustandi
• Keywords: Acidizing, Caesalpinia Sappan, Electrochemical Impedance Spectroscopy, Green Corrosion Inhibitor, Imidazoline, Langmuir, Tafel Polarization

References

[1] M. A. Al-Ghazal, S. M. Al-Driweesh, A.-Z. Mustafa R, and F. A. Al-Ghurairi, Limited Entry, Multiple Injection Matrix Acidizing Technology Boosts Well Production in the World's Fourth Largest Gas Reserves,, Saudi Aramco J. Technol., vol. Spring, p.2–9, (2014).

DOI: 10.2118/167306-ms

[2] L. T. Popoola, A. S. Grema, G. K. Latinwo, and B. Gutti, Corrosion Problems During Oil and Gas Production and its Mitigation,, Int. J. Ind. Chem., vol. 4, no. 35, (2013).

DOI: 10.1186/2228-5547-4-35

[3] A. Singh and M. A. Quraishi, Acidizing Corrosion Inhibitors : A Review,, Journal. Mater. Environ. Sci., vol. 6, no. 1, p.224–235, (2015).

[4] A. Rustandi, J. W. Soedarsono, and B. Suharno, The Use of Mixture of Piper Betle and Green Tea as a Green Corrosion Inhibitor for API X-52 Steel in Aerated 3. 5 % NaCl ...,, Adv. Mater. Res., vol. 383–390, no. November, p.5418–5425, (2012).

DOI: 10.4028/www.scientific.net/amr.383-390.5418

[5] A. Ayende, A. Rustandi, J. W. Soedarsono, D. Priadi, D. N. Suprapta, and G. Priyotomo, Effects of Purple Sweet Potato Extract Addition in Ascorbic Acid Inhibitor to Corrosion Rate of API 5L Steel in 3. 5 % NaCl Environment,, Appl. Mech. Mater., vol. 709, p.384–389, (2015).

DOI: 10.4028/www.scientific.net/amm.709.384

[6] M. Acharya, J. S. Chouhan, A. Dixit, and D. K. Gupta, Green Inhibitors for Prevention of Metal and Alloys Corrosion : An Overview,, Chem. Mater. Res., vol. 3, no. 6, p.16–24, (2013).

[7] C. Kamal and M. G. Sethuraman, Spirulina platensis – A novel green inhibitor for acid corrosion of mild steel,, Arab. J. Chem., vol. 5, no. 2, p.155–161, (2012).

DOI: 10.1016/j.arabjc.2010.08.006

[8] G. Aziate, A. El Yadini, H. Saufi, A. Almaofari, A. Benhmama, H. Harhar, S. Gharby, and S. El Hajjaji, Study of jojoba vegetable oil as an inhibitor of carbon steel C38 corrosion in different acidic media,, vol. 6, no. 7, p.1877–1884, (2015).

[9] F. S. De Souza and A. Spinelli, Caffeic acid as a green corrosion inhibitor for mild steel,, Corros. Sci., vol. 51, no. 3, p.642–649, (2009).

DOI: 10.1016/j.corsci.2008.12.013

[10] S. C. Nwigbo, V. N. Okafor, and A. O. Okewale, Comparative Study of Elaeis Guiniensis Exudates ( Palm Wine ) as a Corrosion Inhibitor for Mild Steel in Acidic and Basic Solutions,, vol. 4, no. 9, p.1035–1039, (2012).

[11] M. Znini, L. Majidi, A. Bouyanzer, J. Paolini, and J. Desjobert, Essential oil of Salvia aucheri mesatlantica as a green inhibitor for the corrosion of steel in 0. 5 M H 2 SO 4,, Arab. J. Chem., (2010).

DOI: 10.1016/j.arabjc.2010.09.017

[12] M. Bello, N. Ochoa, V. Balsamo, F. López-carrasquero, S. Coll, A. Monsalve, and G. González, Modified cassava starches as corrosion inhibitors of carbon steel : An electrochemical and morphological approach,, Carbohydr. Polym., vol. 82, no. 3, p.561–568, (2010).

DOI: 10.1016/j.carbpol.2010.05.019

[13] N. O. Eddy, S. A. Odoemelam, and A. O. Odiongenyi, Inhibitive, adsorption and synergistic studies on ethanol extract of Gnetum Africana as a green corrosion inhibitor for mild steel in H2SO4,, Green Chem. Lett. Rev., vol. 2, no. 2009, p.111–119, (2009).

DOI: 10.1080/17518250903170868

[14] S. K. Sharma, A. Peter, and I. B. Obot, Potential of Azadirachta indica as a green corrosion inhibitor against mild steel, aluminum, and tin : a review,, J. Anal. Sci. Technol., (2015).

DOI: 10.1186/s40543-015-0067-0

[15] I. Radojcic, K. Berkovic, S. Kovac, and J. Vorkapic-Furac, Natural honey and black radish juice as tin corrosion inhibitors,, Corros. Sci., vol. 50, p.1498–1504, (2008).

DOI: 10.1016/j.corsci.2008.01.013

[16] S. Deng and X. Li, Inhibition by Ginkgo leaves extract of the corrosion of steel in HCl and H2SO4 solutions,, Corros. Sci., vol. 55, p.407–415, (2012).

DOI: 10.1016/j.corsci.2011.11.005

[17] M. Rashid, S. Sabir, A. a. Rahim, and U. Waware, Polyaniline/Palm Oil Blend for Anticorrosion of Mild Steel in Saline Environment,, J. Appl. Chem., vol. 2014, p.1–6, (2014).

DOI: 10.1155/2014/973653

[18] N. Lahhit, A. Bouyanzer, J. Desjobert, B. Hammouti, and R. Salghi, Fennel ( Foeniculum Vulgare ) Essential Oil as Green Corrosion Inhibitor of Carbon Steel in Hydrochloric Acid Solution,, vol. 29, no. 2, p.127–138, (2011).

DOI: 10.4152/pea.201102127

[19] A. S. Fouda, G. Y. Elewady, and S. Habouba, Anise Extract as Green Corrosion Inhibitor for Carbon Steel in Hydrochloric Acid Solutions,, vol. 3, no. 4, p.11210–11228, (2014).

[20] J. Porcayo-Calderon, M. Casales-Diaz, L. M. Rivera-Grau, D. M. Ortega-Toledo, J. A. Ascencio-Gutierrez, and L. Martinez-Gomez, Effect of the Diesel, Inhibitor, and CO 2 Additions on the Corrosion Performance of 1018 Carbon Steel in 3% NaCl Solution,, J. Chem., vol. 2014, no. 1, p.1–10, (2014).

DOI: 10.1155/2014/940579

[21] H. J. Chen, T. Hong, and W. Paul Jepson, High Temperature Corrosion Inhibition Performance Of Imidazoline and Amide,, NACE, no. 00035, (2000).

[22] L. M. Rivera-Grau, M. Casales, I. Regla, D. M. Ortega-Toledo, J. G. Gonzalez-Rodriguez, and L. Martinez Gomez, CO2 Corrosion inhibition by imidazoline derivatives based on coconut oil,, Int. J. Electrochem. Sci., vol. 7, p.13044–13057, (2012).

DOI: 10.1149/1.3660608

[23] H. M. A. El-Lateef, L. I. Aliyeva, V. Maharam, and T. A. Ismayilov, Development of New Eco-Friendly Corrosion Inhibitors Based on Vegetable Oils for Protection from CO 2 Corrosion,, Chem. J., vol. 02, no. 02, p.38–49, (2012).

[24] N. A. Negm, N. G. Kandile, I. A. Aiad, and M. A. Mohammad, New eco-friendly cationic surfactants : Synthesis , characterization and applicability as corrosion inhibitors for carbon steel in 1 N HCl,, Colloids Surfaces A Physicochem. Eng. Asp., vol. 391, no. 1–3, p.224–233, (2011).

DOI: 10.1016/j.colsurfa.2011.09.032

[25] N. P. Nirmal, M. S. Rajput, R. G. S. V Prasad, and M. Ahmad, Brazilin from Caesalpinia sappan heartwood and its pharmacological activities : A review,, Asian Pac. J. Trop. Med., vol. 8, no. 6, p.421–430, (2015).

DOI: 10.1016/j.apjtm.2015.05.014

[26] S. A. Umoren, Polymers as Corrosion Inhibitors for Metals in Different Media - A Review,, Open Corros. J., vol. 2, p.175–188, (2009).

DOI: 10.2174/1876503300902010175

[27] L. Rivera-Grau, M. Casales, I. Regla, D. Ortega-Toledo, D. Cuervo, J. Asencio, J. Gonzalez-Rodriguez, and L. Martine-Gomez, Corrosion Inhibition by a Coconut Oil Modified Imidazoline for Carbon Steel Under the Combined Effect of CO 2 and H 2 S,, Int. J. Electrochem. Sci., vol. 7, p.12610–12620, (2012).

DOI: 10.1149/1.3660608

[28] D. Daoud, T. Douadi, S. Issaadi, and S. Chafaa, Adsorption and corrosion inhibition of new synthesized thiophene Schiff base on mild steel X52 in HCl and H 2 SO 4 solutions,, Corros. Sci., vol. 79, p.50–58, (2014).

DOI: 10.1016/j.corsci.2013.10.025

[29] E. S. Meresht, T. S. Farahani, and J. Neshati, 2-Butyne-1 , 4-diol as a novel corrosion inhibitor for API X65 steel pipeline in carbonate / bicarbonate solution,, Corros. Sci., vol. 54, p.36–44, (2012).

DOI: 10.1016/j.corsci.2011.08.052

[30] A. S. Fouda, K. Shalabi, G. Y. Elewady, and H. F. Merayyed, Chalcone Derivatives as Corrosion Inhibitors for Carbon Steel in 1 M HCl Solutions,, Int. J. Electrochem. Sci., vol. 9, p.7038–7058, (2014).