The Effect of Iron (III) Co-Insertion in Magnesium-Aluminum Hydrotalcites Obtained by Precipitation Method at pH 11

Abstract:

Hydrotalcite are anionic clay material presenting LDH arrangement and high porosity and specific areas, which make it a good adsorbent for pollutant species in water. Besides that, that material type can be used as catalyst or catalyst support in several industrial processes. The most common compositions is based on metallic mix hydroxide with high content of magnesium, but their adsorptive properties arise from aluminum replacement in layer structure. The present work presents the synthesis of carbonated magnesium-aluminum hydrotalcite through the precipitation method in order to investigate the co-insertion of iron (III) in aluminum site. It was found the iron (III) co-inserted samples obtained at 100 and 200 oC for 4 hours present no substantial harming in relation to the common magnesium-aluminum composition. All of the samples presented high porosity and specific area, becoming an alternative anionic adsorptive.

• Periodical: Materials Science Forum (Volume 930)
• Pages: 32-36
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.930.32
• Online since: September 2018
• Authors: Igor Silva de Sá, Creuza Kimito Caceres Kawahara, Graciele Vieira Barbosa, Eliane F. de Souza, Talita Cuenca Pina Moreira Ramos, Rafael Aparecido Ciola Amoresi, Margarete Soares da Silva, Alberto Adriano Cavalheiro
• Keywords: Hydrotalcite, Hydroxide Precipitation, Iron III, Phase Formation, Porosity

References

[1] K. Setshedi, J. Ren, O. Aoyi, M.S. Onyango: Int. J. Phys. Sci. Vol. 7 (1) (2012), p.63.

[2] W. Ma, N. Zhao, G. Yang, L. Tian, R. Wang: Desalination Vol. 2681 (3) (2011), p.20.

[3] Y. Yang, n. Gao, W. Chu, Y. Zhang, Y. Ma: J. Hazard. Mater. Vol. 9 (210) (2012), p.318.

[4] F. Cavani, F. Trifiró, A. Vaccari: Catal. Today Vol. 11 (1991), p.177.

[5] L. Conceição, S.B.C. Pergher: Quim. Nova Vol. 30 (5) (2007), p.1077.

[6] M. Kato, M.D. Azimi, S.H. Fayaz, M.D. Shah, M.Z. Hoque, N. Hamajima, S. Ohnuma, T. Ohtsuka, M. Maeda, M. Yoshinaga: Chemosphere Vol. 165 (2016), p.27.

DOI: 10.1016/j.chemosphere.2016.08.124

[7] M.N. Timofeeva, A.E. Kapustin, V.N. Panchenko, E.O. Butenko, V.V. Krupskaya, A. Gil, M.A. Vicente: J. Mol. Catal. A Chem. Vol. 423 (2016), p.22.

[8] L.I. Ardhayantia, S.J. Santosa: Procedia Chem. Vol. 148 (2016), p.1380.

[9] M. Bolognini, F. Cavani, D. Scagliarini, C. Flego, C. Perego, M. Saba: Catal. Today Vol. 75 (2002), p.103.

DOI: 10.1016/s0920-5861(02)00050-0

[10] B. Wiyantokoa, P. Kurniawatia, T.E. Purbaningtias, I. Fatimah: Procedia Chem. Vol. 17 (2015), p.21.

[11] T. Baskaran, J. Christopher, A. Sakthivel: RSC Adv. Vol. 5 (2015), p.98875.

[12] C.W. Beck: Am. Mineral Vol. 35 (1950), p.1006.

[13] F. Silvério: Springer Plus Vol. 2 (211) (2013), p.1.

[14] F.M Labajos, V. Rives: Inorg. Chem. Vol. 34 (1996), p.5313.

[15] A.S. Prakash, V. Kamath, M.S. Hegde: Mater. Res. Bull. Vol. 35 (2000), p.2189.

[16] D.M. Roy, R. Roy, E.F. Osborn: Am. J. Sci. Vol. 251 (1953), p.337.

[17] N.S. Puttaswamy, V. Kamath: J. Mater. Chem. Vol. 7 (9) (1997), p. (1941).

[18] M. Belloto, B. Rebours, O. Clause, J. Lynch, D. Bazin, E. Elkaïn: J. Phys. Chem. US Vol. 100 (20) (1996), p.8535.

[19] K. Ebitani, K. Motokura, K. Mori, T. Mizugaki, K. Kaneda: J. Org. Chem. Vol. 71 (2006), p.5440.

[20] JCPDS - Joint Committee on Powder Diffraction Standards/International Center for Diffraction Data, Pennsylvania, Powder Diffraction File (2003).

[21] G. Socrates: Infrared and Raman Characteristic Group Frequencies. (John Wiley & Sons 3ª ed. Chichester, 2004).

[22] H. Marsh, B. Rand: J. Colloid Interf. Sci. Vol. 33 (1970), p.478.

[23] J. Landers, G.Y. Gor, A.V. Neimark: Colloid Surface A Vol. 437 (2013), p.33.