Synthesis and Characteristics of Inorganic Polymer Materials Geopolymerized from Ash of Brickyard

Article Preview

Abstract:

Inorganic polymer materials known as geopolymer-based materials are always interesting topics for researchers. Geopolymer is environmentally friendly material which has been potential applications for many different fields such as technical materials, building materials, insolation or refractories, and others. This study used ash of brickyard (AB) as a raw material for geopolymerization process to develop novel materials with high porosity. AB is industrial waste of the brick factories that need to be managed to reduce their negative impact to the environment. AB contains high alumino-silicate resources were mixed with sodium hydroxide solution for 10 minutes to obtain the geopolymer pastes. Sodium hydroxide solution was used as an alkaline activator to form geopolymer paste. The geopolymer paste was filled into 5-cm cube molds according to ASTM C109/C109M 99, and then cured at room temperature for 28 days. These products were then tested for compressive strength, volumetric weight, and water absorption. Results indicated that the material can be considered lightweight with a compressive strength at 28 days that are in the range of 8.1 to 15.4 MPa, volumetric weight around 600kg/m3 and water absorption is under 210.65 kg/m3. The properties of geopolymer products were also determined by analytical techniques that included mineral composition by X Ray Diffraction (XRD) and microstructure by scanning electron microscope (SEM).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

45-50

Citation:

Online since:

July 2019

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Davidovits, Geopolymer chemistry and application, 3rd editon, Institute Geopolymer, France, (2011).

Google Scholar

[2] J.L. Provis and J.S.J. van Deventer, Alkali Activated Materials: State of the art report. RILEM-TC244 AAM, Springer Dordrecht Heidelberg New York London, (2014).

DOI: 10.1007/978-94-007-7672-2

Google Scholar

[3] M.A.B. Promentilla, H.T. Nguyen, T.K. Pham, H. Hinode, F.T. Bacani, S.M. Gallardo, Optimizing ternary-blended geopolymers with multi-response surface analysis, Waste biomass valorize 7 (2016) 929-939.

DOI: 10.1007/s12649-016-9490-8

Google Scholar

[4] H.T. Nguyen, T.K. Pham, and M.M.A.B. Abdullah, Lightweight Heat Resistant Geopolymer-based Materials Synthesized from Red Mud and Rice Husk Ash Using Sodium Silicate Solution as Alkaline Activator, MATEC Web Conferences 97, 011019 (2017).

DOI: 10.1051/matecconf/20179701119

Google Scholar

[5] V.Q. Le, M.Q. Do, M.D. Hoang, T.P. Dang, T.H. Bui, H.T. Nguyen, Evaluation on Roles of Activated Silicon and Aluminum Oxides for Formation of Geopolymer from Red Mud and Silica Fume, Key Engineering Materials, 777 (2018) 513-517.

DOI: 10.4028/www.scientific.net/kem.777.513

Google Scholar

[6] H.T. Nguyen, T.K Pham, M.A.B. Promentilla, Development of Geopolymer-Based Materials from Coal Bottom Ash and Rice Husk Ash with Sodium Silicate Solutions, Lecture Notes in Civil Engineering 8 (2018) 402-410.

DOI: 10.1007/978-981-10-6713-6_40

Google Scholar

[7] H.T. Nguyen, H.L.N. Nguyen, T.N.U. Vo, T.K. Pham, Novel materials synthesized from red mud, bagasse, and bentonite for gas treatment by CO2 absorption, MATEC Web of conferences 207, 03005 (2018). https://doi.org/10.1051/matecconf/201820703005.

DOI: 10.1051/matecconf/201820703005

Google Scholar

[8] M.E.L. Kalaw, A.B. Culaba, H.T. Nguyen, K. Nguyen, H. Hinode, W. Kurniawan, S.M. Gallardo, M.A.B. Promentilla, Mechanical and Thermal Properties of Geopolymers from Mixtures of Coal Ash and Rice Hull Ash using Water Glass Solution as Activator, ASEAN Journal of Chemical Engineering 15 (2015) 57-65.

DOI: 10.22146/ajche.49686

Google Scholar

[9] A.K.R. Sumabat, A.J. Manalac, H.T. Nguyen, M.E. Kalaw, R.R. Tan, M.A.B. Promentilla, Optimizing geopolymer-based material for industrial application with analytic hierarchy process and multi-response surface analysis, Chemical Engineering Transaction 45 (2015) 1147-1152.

Google Scholar

[10] T.K. Pham, T.T.L. Tran, T.L.T. Pham, P.Q.N. Tran, H.T. Nguyen, M.M.A.B. Abdullah, A Novel Study on Using Vietnam Rice Hush Ash and Cullet as Environmental Materials, MATEC Web of Conferences 97, 011020 (2017).

DOI: 10.1051/matecconf/20179701118

Google Scholar

[11] H.T. Nguyen, T.N. Le, V.T.H.Q. Pham, T.P. Dang, T.K. Dao, V.P. Nguyen, Development of heat resistant geopolymer-based materials from red mud and rice husk ash, AIP Conference Proceedings, 1954, 040005 (2018). https://doi.org/10.1063/1.5033405.

DOI: 10.1063/1.5033414

Google Scholar

[12] H.T. Nguyen, N.H. Nguyen, V.T.H.Q. Pham, N.K.T. Nguyen, V.T.A. Tran, T.K. Pham, Engineering properties of lightweight geopolymer synthesized from coal bottom ash and rice husk ash, AIP Conference Proceedings, 1954, 040009 (2018). https://doi.org/10.1063/1.5033409.

DOI: 10.1063/1.5033414

Google Scholar

[13] H.T. Nguyen, V.T.H.Q. Pham, T.P. Dang, T.K. Dao, Leachability of heavy metals in geopolymer-based materials synthesized from red mud and rice husk ash, AIP Conference Proceedings, 1954, 040014 (2018). https://doi.org/10.1063/1.5033414.

DOI: 10.1063/1.5033414

Google Scholar

[14] M.A.B. Promentilla, M.E.L. Kalaw, H.T. Nguyen, K.B. Aviso, R.R. Tan, A Fuzzy Programming Approach to Multi-Objective Optimization for Geopolymer Product Design, Computer Aided Chemical Engineering 40 (2017) 1015-1020.

DOI: 10.1016/b978-0-444-63965-3.50171-9

Google Scholar

[15] ASTM C109/109M, Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2-in. or [50-mm] Cube Specimens), American Society for Testing and Materials. Philadelphia June 2000. Sec.4, Volume 04.01.

DOI: 10.1520/c0109_c0109m-13

Google Scholar

[16] ASTM C140 – 99b, Standard Test Methods for Sampling and Testing Concrete Masonry Units and Related Units, American Society for Testing and Materials. Philadelphia June 2000. Sec.4, Volume 04.05.

DOI: 10.1520/c0140-02a

Google Scholar

[17] ASTM C55 – 99, Standard specification for concrete brick. American Society for Testing and Materials. Philadelphia June 2000. Sec.4, Volume 04.05.

Google Scholar

[18] ASTM C90 – 99a, Standard specification for loadbearing concrete masonry units, American Society for Testing and Materials. Philadelphia June 2000. Sec.4, Volume 04.05.

Google Scholar

[19] V.Q. Le, M.Q. Do, M.D. Hoang, V.T.H.Q. Pham, T.H. Bui, H.T. Nguyen, Effect of Alkaline Activators to Engineering Properties of Geopolymer - Based Materials Synthesized from Red Mud Key Engineering Materials, 777 (2018) 508-512.

DOI: 10.4028/www.scientific.net/kem.777.508

Google Scholar

[20] H.T. Nguyen, T.H. Bui, V.T.H.Q. Pham, M.Q. Do, M.D. Hoang, V.Q. Le, Leaching Behavior and Immobilization of Heavy Metals in Geopolymer Synthesized from Red Mud and Fly Ash, Key Engineering Materials, 777 (2018) 518-522.

DOI: 10.4028/www.scientific.net/kem.777.518

Google Scholar

[21] H.T. Nguyen, V.T.H.Q. Pham T.N. Le, T.P. Dang, N.K.T. Nguyen, Utilization of red mud and bagasse for production of gas absorption materials, AIP Conference Proceedings 1954, 040010 (2018). https://doi.org/10.1063/1.5033410.

Google Scholar

[22] J.M. Simonson, R.E. Mesmer, P.S.Z. Rogers, The enthalpy of dilution and apparent molar heat capacity of NaOH (aq) to 523 K and 40 MPa, J. Chem. Thermodyn, 21 (1989) 561-584.

DOI: 10.1016/0021-9614(89)90172-9

Google Scholar