Mechanical Properties of Superconcentrates Based on Ethylene-Vinyl Acetate Copolymer and Microcrystalline Cellulose

Article Preview

Abstract:

In the study, highly filled superconcentrates based on various grades of ethylene-vinylacetate copolymer (EVA) and microcrystalline cellulose (MCC) were studied. It is assumed that adding superconcentrates to various polyolefins will make them biodegradable in the environment. The influence of EVA rheological characteristics and the content of vinyl acetate (VA) groups on the properties of the superconcentrates were studied. It was shown that increasing the concentration of VA groups in EVA leads to an increase in the elongation at break of the composites; increase in EVA melt flow index (MFI) greatly reduces the basic mechanical properties of the composite.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

306-310

Citation:

Online since:

May 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] P.V. Pantyukhov, T.V. Monakhova, N.N. Kolesnikova, A.A. Popov and S.G. Nikolaeva, Destruction of composite materials made of LDPE and lignocellulosic fillers, Journal of the Balkan Tribological Association. 19(3) (2013) 467-475.

Google Scholar

[2] N.A. Faris, N.Z. Noriman and S.T. Sam, Current Research in Biodegradable Plastics, Applied Mechanics and Materials. 679 (2014) 273-280.

DOI: 10.4028/www.scientific.net/amm.679.273

Google Scholar

[3] H. Abral, A.S. Anugrah, F. Hafizulhaq, D. Handayani, E. Sugiarti and A.N. Muslimin, Effect of nanofibers fraction on properties of the starch based biocomposite prepared in various ultrasonic powers, International Journal of Biological Macromolecules. 116 (2018) 1214-1221.

DOI: 10.1016/j.ijbiomac.2018.05.067

Google Scholar

[4] V. Sessini, M.P. Arrieta, J.-M. Raquez, P. Dubois, J.M. Kenny and L. Peponi, Thermal and composting degradation of EVA/Thermoplastic starch blends and their nanocomposites. Polymer Degradation and Stability. 159 (2019) 184-198.

DOI: 10.1016/j.polymdegradstab.2018.11.025

Google Scholar

[5] A.D. Cavdar, E.D. Tomak, and F. Mengeloglu, Long-term leaching effect on decay resistance of wood-plastic composites treated with boron compounds, Journal of Polymers and the Environment. 26(2) (2018) 756-764.

DOI: 10.1007/s10924-017-0992-7

Google Scholar

[6] A.K.M. Moshiul Alam, M.D.H. Beg, M.F. Mina, A.A. Mamun, and A.K. Bledzki, Degradation and stability of green composites fabricated from oil palm empty fruit bunch fiber and polylactic acid: Effect of fiber length, Journal of Composite Materials. 49(25) (2015) 3103-3114.

DOI: 10.1177/0021998314560219

Google Scholar

[7] A. Dufresne and M.N. Belgacem, Cellulose-reinforced composites: from micro-to nanoscale Polímeros. 23(3) (2013) 277-286.

DOI: 10.4322/polimeros.2010.01.001

Google Scholar

[8] K.G. Satyanarayana, G.G.C. Arizaga, F. Wypych. Biodegradable composites based on lignocellulosic fibers-An overview, Progress in Polymer Science. 34(9) (2009) 982-1021.

DOI: 10.1016/j.progpolymsci.2008.12.002

Google Scholar

[9] M. Laka, S. Chernyavskaya and M. Maskavs, Cellulose-containing fillers for polymer composites, Mechanics of Composite Materials. 39(2) (2003) 183–188.

Google Scholar

[10] E.M. Khar'kova, D.I. Mendeleev, M.A. Guseva, and V.A. Gerasin, Structure and properties of polymer–polymer composites based on biopolymers and ultra-high molecular weight polyethylene obtained via ethylene in situ polymerization, Journal of Polymers and the Environment. 27(1) (2019) 165-175.

DOI: 10.1007/s10924-018-1326-0

Google Scholar

[11] P. Pantyukhov, N. Kolesnikova and A. Popov. Preparation, structure, and properties of biocomposites based on low density polyethylene and lignocellulosic fillers, Polymer Composites. 37(5) (2016) 1461-1472.

DOI: 10.1002/pc.23315

Google Scholar

[12] J.W. Gooch, Encyclopedic Dictionary of Polymers, Springer, New York, 2011, 520 p.

Google Scholar

[13] D.C. Bugada and A. Rudin. Molecular structure and melting behaviour of ethylene-vinyl acetate copolymers, European Polymer Journal, 28(3) (1992) 219-227.

DOI: 10.1016/0014-3057(92)90179-6

Google Scholar

[14] T. Whelan and J. Goff. Ethylene vinyl acetate copolymers, Injection Molding of Thermoplastic Materials. 2 (1990) 49-59.

DOI: 10.1007/978-1-4757-5502-2_3

Google Scholar

[15] J.K. Fink, Handbook of engineering and speciality thermoplastics. Polyolejns and Styrenics, Scrivener Publishing LLC, 2010, 400 p.

Google Scholar

[16] T. Bremner, D.G. Cook and A. Rudin, Further comments on the relations between melt flow index values and molecular weight distributions of commercial plastics, Journal of Applied Polymer Science, 43(9) (1991) 1773-1773.

DOI: 10.1002/app.1991.070430920

Google Scholar

[17] P.G. Shelenkov, P.V. Pantyukhov and A.A. Popov, Highly filled biocomposites based on ethylene-vinyl acetate copolymer and wood flour, IOP Conference Series: Materials Science and Engineering. 369(1) (2018) 012043.

DOI: 10.1088/1757-899x/369/1/012043

Google Scholar

[18] A.Y. Anpilova, E.E. Mastalygina, I.A. Mikhaylov, A.A. Popov and Z.S. Kartasheva, Morphology and physical-chemical properties of celluloses obtained by different methods, AIP Conference Proceedings. 1909 (2017) 020008.

DOI: 10.1063/1.5013689

Google Scholar

[19] A. Zykova, P. Pantyukhov, and A. Popov, Ethylene–octene copolymer–wood flour/oil flax straw biocomposites: Effect of filler type and content on mechanical properties, Polymer Engineering and Science. 57(7) (2017) 756-763.

DOI: 10.1002/pen.24626

Google Scholar