Colloidal Crystal Templating of Two-Dimensional Ordered Macroporous SiCN Ceramics

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Abstract:

In this study, two-dimensional (2D) ordered macroporous SiCN ceramics were prepared by infiltrating sacrificial colloidal silica (SiO2) templates with the low molecular weight preceramic polymer, polysilazane. This was followed by a thermal curing step, pyrolysis at 1250°C in a N2 atmosphere, and finally the removal of the templates by etching with diluted HF. In particular, 100large-scale monolayer silica crystals were prepared on the cleaned Si substrates by spin coating. Two-dimensional SiCN ordered pore arrays were fabricated by a solution-dipping template strategy.

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Solid State Phenomena (Volume 135)

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27-30

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February 2008

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© 2008 Trans Tech Publications Ltd. All Rights Reserved

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