Magnetic Properties of Intercalated Zinc Hexacyanoferrate (II)

Tatiana A. Denisova; Lidia G. Maksimova; Dina G. Kellerman; M.A. Melkozerova; Elena V. Zabolotskaya; Valentin Yakovlevich Mitrofanov; G.A. Dorogina

doi:10.4028/www.scientific.net/SSP.168-169.169

Paper Titles

Relationship between the Spontaneous Magnetization, Spontaneous Magnetostriction and Heat Capacity in the Compound Mn₅Ge₃
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Determination of Texture Degree of NdFeB-Magnets by Means of Neutron Diffraction
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The Magnetocaloric Effect in Ni-Mn-X (X=Ga, in) Heusler Alloys and Manganites with Magnetic Transition close to Room Temperature
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Magnetic Properties of Intercalated Zinc Hexacyanoferrate (II)
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HomeSolid State PhenomenaSolid State Phenomena Vols. 168-169Magnetic Properties of Intercalated Zinc...

Magnetic Properties of Intercalated Zinc Hexacyanoferrate (II)

Abstract:

The results of magnetic behavior study of nickel ions, which were introduced into Zn2Fe(CN)6∙5.5H2O with channel structure, are presented. It was shown that nickel cations replace a part of Zn2+ ions or locate in the channels of lattice via the molecular mechanism sorption. It is shown that the magnetic moments μNi of the sorption products strongly depend on the content of Ni2+ ions. The values of μNi of the samples with Ni/Fe(CN)6=2.26 and 2.86 are great ~ 3.9 and 4.4 μB respectively and close to the value typical of free Ni2+ ions μ =4.47μB.

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Solid State Phenomena (Volumes 168-169)

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169-172

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.168-169.169

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Online since:

December 2010

Authors:

Tatiana A. Denisova, Lidia G. Maksimova, Dina G. Kellerman, M.A. Melkozerova, Elena V. Zabolotskaya, Valentin Yakovlevich Mitrofanov, G.A. Dorogina

Keywords:

Ethanol Solutions of NiCl₂, Magnetic Property, Sorption, Zinc Hexacyanoferrate (II)

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