Diffusion Carbide Layers Produced on Tool Steel in Chromium Chloride Atmosphere at Low Pressure

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Diffusion chromizing of tool steel has been investigated, using a powder method modified by the use of low pressure during the process for the avoidance of the oxidation of the batch. Innovative chromizing novel processes have been carried out in a hot-wall vacuum oven. The processes have been performed in a chromium chloride atmosphere at a low pressure range from 1 to 800 hPa, with treatment temperatures of 850 to 950°C. Studies of layer thickness, its phase composition, and Cr, Fe, and C depth profiles in the diffusion zone of chromized layer have been conducted. The effect of the process parameters, such as time and temperature, on the growth kinetics of diffusion layers has also been investigated. A comparison was made between the layer thickness produced on the tool steel surface using the novel chromizing method, under low pressure, and a traditional chromizing process, by the pack powder method. Chromizing conducted at low pressure was found to be more effective for maximizing the growth rate of diffusion layers than that for chromizing by the traditional pack cementation method.

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Solid State Phenomena (Volume 223)

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119-126

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November 2014

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] G.N. Dubinin, Diffusion Chromizing of Alloys, Edited by American Publishing Co., New Delhi, India, (1987).

Google Scholar

[2] J. W. Lee, J.G. Duh, Evaluation of microstructures and mechanical properties of chromized steels with different carbon contents. Surface and Coatings Technology. Vol. 177-178, (2004) 525-531.

DOI: 10.1016/j.surfcoat.2003.08.031

Google Scholar

[3] E. Kasprzycka, Chromizing in Wang, Q. Jane and Chung, Yip-Wah (Eds. ), Encyclopedia of Tribology. Springer-Verlag New York Inc, Vol. 1, 2013, 382–387.

DOI: 10.1007/978-0-387-92897-5_707

Google Scholar

[4] E. Kasprzycka, Corrosion resistant layers produced from metals vapors (Cr, Ti) under low pressure, Edited by Institute of Precision Mechanics, Warsaw, (2002).

Google Scholar

[5] E. Kasprzycka, Diffusion of chromium in low carbon steel during vacuum chromizing process. Solid State Phenomena, vol. 72 (2000), 85–90.

DOI: 10.4028/www.scientific.net/ssp.72.85

Google Scholar

[6] A. Mlynarczak, Modification of structure and properties of single- and multiphase diffusion chromium, vanadium, titanium carbide coatings formed on steels by pack cementation. Edited by Poznan Technical University, Poznan, (2005).

Google Scholar

[7] J.W. Lee, H.C. Wang, J.L. Li, C.C. Lin, Tribological properties evaluation of AISI 1095 steel chromized at different temperatures. Surface and Coatings Technology. Vol. 188-189 (2004) 550–555.

DOI: 10.1016/j.surfcoat.2004.07.011

Google Scholar

[8] E. Kasprzycka, J. Tacikowski, The layers structure composed of chromium carbides and titanium carbides. Materials Engineering (Poland) 5 (2005) 625-628.

DOI: 10.1520/mpc20150069

Google Scholar

[9] E. Kasprzycka, Diffusion carbide layers produced on tool steel surface in vacuum chromizing process. Problemy Mašinostroenija i Avtomatizacji, nr 1, vol. 5 (2006) 159–161.

Google Scholar

[10] E. Kasprzycka, J. Senatorski, B. Bogdański, Tribological Properties of Duplex Layers Produced in Vacuum Chromizing Process Together with Galvanic Treatment. 5th International Conference on Tribology, 20-22 September 2006, Parma, Italy.

DOI: 10.5604/01.3001.0010.6595

Google Scholar

[11] S. Schwarz, Y. Musayev, S. M. Rosiwal, Diffusionchromierung im Vakuum für die CVD-Diamantbeschichtung. Metalloberfläche, 9 (2001) 59–62.

Google Scholar

[12] E. Kasprzycka, Parameters of vacuum process as the factors changing the growth kinetics of chromized layers produced on low-carbon iron alloys by means of CVD. Journal de Physique IV, Colloque C5, supplement au Journ. II, 5 (1995) 175-181.

DOI: 10.1051/jphyscol:1995519

Google Scholar

[13] E. Kasprzycka, J. Tacikowski, K. Pietrzak, Factors determining growth of diffusion layers on low-carbon steel and iron during vacuum chromising. Surface Engineering 12 (3) (1996) 229-234.

DOI: 10.1179/sur.1996.12.3.229

Google Scholar

[14] E. Kasprzycka, J. Tacikowski and others, Polish Patent No 159 324, Warsaw (1993).

Google Scholar