The Influence of Current Density of Electrodeposition on the Electrochemical Properties of Ni-Mo Alloy Coatings

Magdalena Popczyk; B. Łosiewicz

doi:10.4028/www.scientific.net/SSP.228.269

Paper Titles

Effect of Sodium Hypophosphite Content in the Electroplating Bath on the Electrochemical Properties of Ni-P Alloy Coatings
p.246

The Hydrogen Evolution Reaction on Fe Electrode Material in 1 M NaOH Solution
p.252

Comparison of Electrochemical Properties of Ni+NiAl and Ni Coatings in an Alkaline Solution
p.258

The Influence of Temperature of Electrodeposition on the Electrochemical Properties of Ni+MoS₂+Mo Composite Coatings
p.263

The Influence of Current Density of Electrodeposition on the Electrochemical Properties of Ni-Mo Alloy Coatings
p.269

The Hydrogen Evolution Reaction on Ni Electrode Material Modified with Molybdenum(IV) Oxide and Chromium(III) Oxide Powders
p.273

Effect of Molybdenum(IV) Oxide on the Process of Hydrogen Evolution on Ni+Mo Electrolytic Composite Coatings
p.277

Electrochemical Characterization of Nickel-Based Composite Coatings Containing Molybdenum or Tungsten Nanopowders
p.283

Effect of Molybdenum Powder Granulation on Electrochemical Properties of Ni+Mo Composite Coatings
p.288

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The Influence of Current Density of Electrodeposition on the Electrochemical Properties of Ni-Mo Alloy Coatings

Abstract:

The Ni-Mo alloy coatings with a high content of Mo up to 44.5 at.%, were prepared by galvanostatic electrodeposition in the range of deposition current density, j_dep, from-30 to-240 mA cm^-2 from the nickel plating bath containing potassium pyrophosphate, nickel chloride, sodium molybdate, and sodium bicarbonate. Investigations of hydrogen evolution reaction (HER) were carried out in 5 M KOH solution at room temperature using steady-state polarization and electrochemical impedancy spectroscopy (EIS) measurements. It was found that for the Ni-Mo alloy coatings, the increase in their catalytic properties towards the HER with the increase in the value of j_dep of the coatings, was due to the intrinsic activity.

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Periodical:

Solid State Phenomena (Volume 228)

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269-272

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https://doi.org/10.4028/www.scientific.net/SSP.228.269

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Online since:

March 2015

Authors:

Magdalena Popczyk*, B. Łosiewicz

Keywords:

Current Density, Electrodeposition, Hydrogen Evolution Reaction, Ni-Mo Alloy Coatings

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References

[1] N.V. Krstajić, V.D. Jović, Lj. Gajić-Krstajić, B.M. Jović, A.L. Antozzi G.N. Martelli: Int. J. Hydrogen Energ. Vol. 33 (2008), p.3676.

DOI: 10.1016/j.ijhydene.2015.06.127

Google Scholar

[2] Q. Han, S. Cui, N. Pu, J. Chen, K. Liu, X. Wei: Int. J. Hydrogen Energ. Vol. 35 (2010) p.5194.

Google Scholar

[3] O. Aaboubi: Int. J. Hydrogen Energ. Vol. 36 (2011) p.4702.

Google Scholar

[4] N. Eliaz, E. Gileadi, Induced Codeposition of Alloys of Tungsten, Molybdenum and Rhenium with Transition Metals, in: Modern Aspects of Electrochemistry, Vol. 41, C.G. Vayenas, R.E. White (Eds. ), Springer, (2006).

DOI: 10.1007/978-0-387-49489-0_4

Google Scholar

[5] L. Valek, M. Metikoš-Huković, Z. Grubač: J. New Mat. Electrochem. Systems Vol. 9 (2006), p.145.

Google Scholar

[6] B.R. Hinderliter, S.G. Croll, D.E. Tallman, Q. Su, G.P. Bierwagen: Electrochim. Acta Vol. 51 (2006), p.4505.

Google Scholar